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31 Cards in this Set

  • Front
  • Back

VSEPR

Valence Shell electron pair repulsion model

hybridization

the process of orbital mixing

Hybrid Orbitals

the new atomic orbitals formed from two or three different types of orbitals (s,p,d)




# of hybrid orbitals = # of atomic orbitals mixed

Valence Bond Theory

covalent bonds form when orbitals of two atoms overlap




overlap region must contain a pair of electrons

Pauli Exclusion Principle (Opposing spins of the bonding electrons - )

2 electrons with opposite spins

Maximum Overlap of Orbitals

The greater the orbital overlap, the more stable and stronger the bond.

Hybridization of Atomic Orbitals

different atomic orbitals used to account for bond angles and shapes of molecules.

Mode

orientation of how the hybrid orbitals overlap with each other or orbitals of bonded atoms

sigma bond

end-to-end overlap


highest electron density located along the bond axis




free rotation

pi bond

bond formed by the overlap of two regions above and below the plane of molecule (p orbitals) side to side overlap




orbital overlap will be disturbed if molecule is rotated, breaking bond

Cis

similar atoms on the same side

Trans

similar atoms are on opposite sides

isomers

two different arrangements of the same molecule

Stoichiometric Amounts

Exact Proportions indicated by the balanced chemical equation

Limiting Reagant

Reactant used up first in the reaction

Theoretical Yield

amount of product that would result if all the limiting reagant reacted MAX obtainable result

Actual Yield

amount of product actually obtained from a reaction

solution

homogenous mixture of 2 or more substances

solute

substance present in the smaller amount

solvent

substance present in the larger amount

Equilibrium

state in which there are no observable changes as time goes by

Chemical equilibrium

rates of forward and reverse reactions are equal




concentrations of the reactants and products remain constant

electrolyte

substance that when dissolved in water results in a solution that can conduct electricity

nonelectrolyte

substance that when dissolved results in a solution that does not conduct electricity

strong electrolyte

100% dissociation

weak electrolyte

not completely dissociated

NON ELECTROLYTES

most carbon compounds, fats sugars, alcohols
(NH2)2CO


CH3OH


C2H5OH


C6H12O6


C12H22O11



Dilution

procedure of preparing a less concentrated solution from a more concentrated solution




MV = MV

titration

a solution of accurately known concentration is added gradually to another solution of unknown concentration until the chemical reaction between the two solutions is complete

Equivalence Point

the point at which the reaction is complete

Indicator

substance that changes color at or near the equivalence point