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23 Cards in this Set

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ORGANIC COMPOUNDS

-made from carbon & hydrogen atoms


-may also contain other nonmetals~ oxygen, sulfur, nitrogen, phosphorus, or a halogen


-often found in gasoline, medicines, shampoos, plastics & perfumes

PROPERTIES OF ORGANIC COMPOUNDS

-covalent bonds


-low melting & boiling points


-flammable & undergo com ustion


-sent stable in water

INORGANIC COMPOUNDS

-high melting & melting points


-ionic, stable in water & don't burn in air

HYDROCARBONS

-organic compounds, only contain carbon & hydrogen


-every carbon has 4 hydrogen bonds


SATURATED HYDROCARBONS


-contain only single bonds

PICTURE

CONFIRMATIONS OF ALKANES

carbon atoms in a chain connected by single C-C bonds


-can rotate, so groups attached to each carbon move frely


-can have different arrangements

ALKANE REPRESENTATION

helax molecule can be represented in several ways


-molecular formula


-ball and stick model


-expanded structural formula


-condensed structural formula


-skeletal formula

CYCLOALKANES

-cyclic alkanes


-two fewer hydrogen atoms than the open chain form


-named by using prefix cyclo before the name of the alkane chain with the same number of carbon atoms

Picture

ALKANES WITH SUBSTITUTENTS

Substituent- atoms or groups of atoms attached to the carbon chain & include alkyl & halo groups


Alkyl Groups- groups of carbons atoms attached to carbon chains


Halo Substituent- halogen atoms attached to carbon chain

STRUCTURAL ISOMERS

-same molecular formula with different arrangement of atoms


-same number of atoms bonded in a different order

SOLUBILITY & DENSITY OF ALKANES

-nonpolar


-insoluble in water


-less dense than water


-flammable in air


-found in crude oil

COMBUSTION OF ALKANES

with strong C-C bonds


-react with oxygen gas to make carbon dioxide & water in combustion reactions


-release energy when C-C bonds are broken in combustion reactions

Picture

ALKENES & ALKYNES

Families of hydrocarbons


-contain double & triple bonds, respectively


-called unsaturated hydrocarbons because they don't contain the maximum number of hydrogen atoms


-react with hydrogen gas to increase number of hydrogen atoms & become alkanes

IDENTIFYING ALKENES

contain one or more carbon-carbon double bonds


-each carbon atom in the double bond is attached to two hydrogen atoms & have a trigonal planar arrangement with bond angles of 120°

IDENTIFYING ALKYNES

contain one or more carbon-carbon triple bonds


-each carbon atom in the triple bond has a linear arrangement with angles of 180°

CYCLOALKENES

have a double bond within a ring structure


-named by assigning the double bond to be between carbon 1 & 2 when a substitutent is on the ring

CIS-TRANS ISOMERS

the atoms or groups of atoms attached to the carbon atoms on the double bond may form two different structures, also called geometric


-have different physical & chemical properties

CIS & TEAND ISOMERS

In an alkene, the double bond


-rigid & doesn't rotate


-holds attached groups in fixed positions


-makes cis-trans possible when two different groups are attached to the carbon atoms on each side of double bond

CIS-TRANS ISOMERS OF BUTENE

CIS ISOMERS- alkyl groups are attached on the same side of double bond & H atoms are on the other side


TRANS ISOMERS- groups & H atoms are attached on opposite side of double bond

PHEROMONES

-warn an insect of danger


-mark a trail


-atract the opposite sex


Effectiveness depends on the cis or trans configuration on double bond in molecule

ADDITION REACTIONS

In alkenes & alkynes, double & triple bonds are


-very reactive, adding H-H or H-OH to the carbons in the double or triple bonds


-easily broken, providing to form new bonds

HYDROGENATION OF OILS

-hydrogenation is used to convert the double bond in vegetable oils to saturated fats


Adding H2 to double bonds in vegetable oils produces


-compounds with higher melting points


-solids at room temperature

HYDRATION REACTIONS

An alkene reacts with water, H-OH to form alcohol


-Markovnikov's Rule: a hydrogen atom from wager forms a bond with carbon atom in double bond with more hydrogen atoms


-the -OH from water forms a bond with second carbon atom in double bond with fewer hydrogen atoms

AROMATIC COMPOUND

-ring of six C atoms, each bonded to one H atom


-flat ring structure drawn with three alternating double bonds


-represented by two structures because the electrons are shared equally among all the C atoms