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73 Cards in this Set
- Front
- Back
allows for 4 hydrogen bonds
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tetrahedral
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with 2 lone e-pairs allows for polarity
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bent
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gives the solid phase less density than the liquid phase
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hexagonal
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Effects of hydrogen bonding: ___ surface tension, ___ boiling and melting point, ___ specific heat capacity, ___ heat of vaporation
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high; high; high; high
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the amount of heat needed to raise the temperature of 1g of water to 1C
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Specific Heat Capacity
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The specific heat capacity of water:
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4.18 Joules
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the amount of energy needed to convert 1g of a substance from a liquid to a gas at the boiling point
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heat of vaporization
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Something is considered soluble when ___g can dissolve in ___ml of solvent.
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.1 ; 100
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Intermolecular bonding is described as:
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"like dissolves like"
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H2O, Sugar, Salt, NaNO3, and alcohol are examples molecules of ___ and ___ intermolecular forces.
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polar; ionic
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Oils, grease, gasoline, benzene, and CCl4 are all:
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nonpolar
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C6H12 is:
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Hexane
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when a solute particle is surrounded by the solvent
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solvation
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C6H12O6:
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glucose
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C12H22O11
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sucrose
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A solid in a liquid is an _________ force.
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induced dipople-induced dipole
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incapable of being mixed
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immiscible
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What is the chemical formula for methanol?
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CH3OH
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What is the chemical formula for ethanol?
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C2H5OH
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What is the chemical formula for propanol?
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C3H7OH
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What determines solubility?
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The length of the hydrocarbon chain.
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Why is Ammonia extremely soluble in water?
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because of hydrogen bonding
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Solubility is ___ dependent.
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Pressure
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S1/P1= ?
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S2/P2
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___ will always float on water.
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Hydrocarbon
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The hydrocarbon layer is the ___.
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organic layer
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For a separate solute, the heat is ___.
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+
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For a separate solvent, the heat is ___.
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+
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For the solute and solvent combined, the heat is ___.
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-
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What is enthalphy?
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heat
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The heat of a solution may be + or - depending on _____ energy.
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bonding
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The heat of a solution =
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[/\H1+ /\H2] - [/\H3]
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What causes 95% of all ionic compounds to be soluble in water even though their enthalpy is +?
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entropy
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What does stirring do?
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increase collisions
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What does unsaturated mean?
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The maximum amount has been dissolved.
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+/\Hsoln =
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heat + ionic solute + h2O --><-- soln
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-/\Hsoln=
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gas solute + H2O --><-- solv + heat
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How is something supersaturated?
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By heating; You can increase the solute so theres more room for the solvent
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What is the rate of dissolving?
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change in concentration
----------------------------------- change in temperature |
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Ions conduct ____.
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electricity
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What indicates the degree of ionization?
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the amount of current
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Strong electrolytes are ___% ions.
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100
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Ionic salts in H2O and strong acids in H2O and strong bases in H2O are ____ electrolytes.
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strong
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Weak electrolytes are <__% ions.
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100
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What are the strong bases in H2O?
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Elements in group IA and IIA (hydroxides)
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Weak acids and weak bases are ____ electrolytes.
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weak
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Hc2, H3O2, H2CO3, and HF are:
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weak acids
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H C2 H3 O2:
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Acetic Acid
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NH3 (gas) is a _____.
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nonelectrolyte
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Cl, Br, I, NO3, CLO4, SO4 are strong ___ in H2O.
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acids
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What are some molecular substances that are nonelectrolytes?
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sugars, gasoline, sulfur, benzene, naphthalene, glucose, sucrose
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Why aren't colloids and suspensions true solutions?
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They are 2 phases, particles are larger and they show the Tyndall effect
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0.1-1 nm is a:
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solution
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1-100 nm is a:
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colloid
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100-1000 nm is a:
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suspension
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For a solution: tyndall? settles? stays n filter? Uniformity:
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no ; no; no; homogenous
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For a colloid: tyndall? settles? stays n filter? Uniformity:
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yes; no; no; borderline
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For a suspension: tyndall? settles? stays n filter? Uniformity:
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yes; yes; yes; heterogeneous
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What is emulsion?
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when a liquid is dispersed in a liquid
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__ is a solid disp. in liquid
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gel
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___ is a gas disp in liquid
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foam
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___ is a liquid disp in gas (fog)
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aerosol
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Water is most dense at ___C.
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4
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Salt water is/is not a colloid
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is not
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A substance that will lose its water of hydration due to its high vapor pressure is said to be:
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efflorescent
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solvent:
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what the solute is dissolved in
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solute:
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what is dissolved
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Sugar is/is not an electrolyte.
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is not
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What is the heat of vaporization of water?
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2.26 kJ/g
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An inward force that tends to minimize the surface area of a liquid is its
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surface tension
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The particles of a colloid are kept in suspension by numerous collisions known as:
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brownian motion
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A type of colloid where both dispersed phase and dispersion medium are liquids is known as __
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emulsion
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The fact that polar solvents dissolve polar solutes and nonpolar solutes dissolve in nonpolar solvents is summarized as _____.
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like dissolves like
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