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28 Cards in this Set
- Front
- Back
bond energy
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energy required to break the bond
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ionic bonding
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formed when an atom that looses electrons easily reacts with an atom that has a high affinity for electrons
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coulumb's law
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energy of interaction between a pair of ions
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bond length
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distance where the energy is minimal
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covalent bonding
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electrons are shared by the nuclei
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polar covalent bond
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unequal sharing of electrons
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electronegativity
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the ability of an atom in a molecule to attract shared electrons to itself
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dipole moment
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molecule that has a center of positive charge and a center of negative charge
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isoelectronic ions
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ions containing the same number of electrons
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lattice energy
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the change in energy that takes place when separated gaseous ions are packed together to form an ionic solid
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localized electron model
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a molecule is composed of atoms that are bound together by sharing pairs of electrons using the atomic orbitals of the bound atoms
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lewis structure
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shows valence electron arranged among the atoms in the molecule
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resonance
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invoked when more than one valid lewis structure can be written for a particular molecule
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formal charge
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difference between the number of valence electrons on the free atom and the number of valence electrons assigned to the atom in the molecule
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molecular structure
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three dimensional arrangement of atoms in the molecule
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VSEPR model
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the structure around a given atom is determined principally by minimizing electron-pair replusions
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hybridization
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the mixing of native atomic orbitals to form special orbitals for bonding
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hybrid orbitals
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when a atom adopts a different set of atomic orbitals from those it has in the free state
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sigma bond
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covalent bond where the electron pair is shared in an area centered on a line running between the atoms
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pi bond
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parallel p orbitals can share an electron pair which occupies the space above and below a line joining the atoms
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molecular orbitals
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can hold tow electrons with opposite spins and the square of the molecule wave function indicates electron probability
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sigma molecular orbitals
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MO1 and MO2, bonding, and antibonding
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bonding molecular orbital
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lower in energy than the atomic orbitals of which it is composed
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antibonding molecular orbital
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higher in energy than the atomic orbitals of which it is composed
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bond order
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difference between the number of bonding electrons and the number of antibonding electrons divided by two
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pi molecular orbitals
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designated as pi2p for the bonding MO and pi2p* for the antibonding MO
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paramagnetism
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causes the substance to attracted into the inducing magnetic field
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diamagnetism
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causes the substance to be repelled from the inducing magnetic field
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