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38 Cards in this Set
- Front
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Relative Formula Mass
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Mass of a compound molecule, calculated by adding all of the Ar's (relative atomic masses) for the component atoms (Mr/RFM/RMM)
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what is the relative atomic mass of H2O?
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H2O= (2x1)+16=18
H=1 O=16 |
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Mr of Al2 (so4)3
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(so4)3= (2x27)+(32x3)+(16x4x3)=342
Al=27 S=32 0=16 |
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Mr of citric acid C6H8O7
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C6H8O7= (12x6)+(1x8)+(16x7)=192
C=12 H=1 O=16 |
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Moles& Avogadro's number
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Atoms are too small to count/weigh individually, so chemists group them together. 6.02x1023 is the number of atoms called the mole.
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Moles equation
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Moles= Mass/Molar mass
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how many moles in 73g of HCl
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Moles=Mass/Molar Mass
73/(1+35.5) = 2 moles |
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196g of H2So4
moles=? |
Moles=Mass/Molar mass
196/(2+32.1+64) =2 moles |
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2 moles of iron
what is the mass? |
Mass=Moles x Molar mass
2 x 55.8 Mass= 111.6 g |
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0.1 moles of S8
Mass=? |
Mass=moles x molar mass
0.1 x (32.1 x 8) =25.6 g |
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molar volume of gases
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when working with gases, chemists calculate how many moles of gas are present from the volume of the gas. therefore 1 mole of gas at RTP (Room Temperature Pressure) has a volume of 24dm3.
Room temperature= 25 degrees Room pressure= 1 atm |
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Moles in gases equation
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Moles = volume of gas in dm3/24dm3
1dm3= 1000cm3 cm3/1000=dm |
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24,000cm3 of Cl
Moles=? |
2.4/24
0.1 moles |
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Mg +H2So4 = MgSo4+ H2
How many moles of Mg? |
Mg=24.3
H2=2 S=32.1 O4= 64 Moles of Mg= mass/molar mass =2.4/24.3 =0.1 moles of Mg |
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Hydrated
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Forms a complex with water
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Empirical formula or EF
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shows the simplist whole number molar ratio of atoms in a molecule
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EF of Fe2O3
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Fe:O
2:3 EF = Fe2O3 |
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EF of Al2O6
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Al:O
2:6 =1:3 AlO3 |
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An experiment shows that 64g of conmpound contains 48g of C and 16g of H. Calculate the empirical formula.
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C H
Mass= 48 16 Molar mass= 12 1 Moles= 4 16 Ratio= 1:4 EF= CH4 |
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Molecular Formula
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Shopws the actual number of atoms in a compound and is a simple multiple of the Empirical formula
for example: EF= CH3 MF= CH3 x 2 MF= C2H6 |
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Find the MF of a compound whose EF is CH2 and has a mass of 84g
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Mass of EF=
(12 x 1)+(1 x 2) = 14g N= the amount to multiply the EF by N= molar mass/empirical mass = 84/14 =6 6 x CH2 C6H12 |
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N= the amount to multiply by
what is the equation? |
N= molar mass/empirical mass
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Find the MF of CH2
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Mass of EF= 912 x 1) + (1 x 2) =14g
N= molar mass/empirical formula =28/14 =2 MF+ |
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% yield equation
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% yield = obtained yield/ theoretical yield X 100
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The theoretical yield of X is 12.5g
Actual yield= 8.25g |
8.25/12.5 x 100
= 66% |
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Reversible reactions
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Some reactions can move in both directions. They are known as reversible reactions.
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Example of an irreversible reaction
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C+ O2 = CO2
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Example of a reversible reaction
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CuSo4.5H20 = CuSo4 + 5H2O
hydrated copper sulfate complex (blue crystals) = Anhydrous copper sulfate (white) It goes white because the water has been removed. |
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Dynamic equilibrium
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In a reversible reaction, the forward and back reactions are happening at the same time. The forward reaction always goes first, but as soon as products are formed, the back reaction begins. Eventually, a steady state will be reached and the forward and backwards reaction are happening at he same time. This is Dynamic Equilibrium.
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How does the position of the equilibrium point tell us the proportion of the products and reactants.
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EQM point to the right = more products
EQM point to the left = more reactants |
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Kinetic theory of matter
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all particles above absolute zero have kinetic energy
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Collision theory
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In order for a reaction to happen, particles must collide.
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4 ways to change the equilibrium point
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1. a higher temperature
2. particle size (smaller particles= greater surface area) 3. Change the concentration 4. A catalyst will make the reaction meet its equilibrium much faster, with less energy |
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The Haber Process
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Air is liquefied under pressure
Nitrogen is separated out by fractional distillation Hydrogen is extracted from Methane Nitrogen and hydrogen are combined to make Ammonia High temperature, pressure and catalyst is needed. Used for explosives, dye making, medicines and fertilisers. |
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Why is an iron catalyst used in the Haber process?
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The iron catalyst is used in the Haber process because it increases the rate of reaction and speeds up both the forward and backwards reaction up.
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If the temperature increases what will happen to the yield?
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The yield would decrease because a low temperature favours the exothermic reaction
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why is a high pressure not used?
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A high pressure is not used because it is too expensive and dangerous.
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Le Chatalier's Principle
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If a dynamic equilibrium is disturbed by the conditions, the reaction will move to counteract the change.
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