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38 Cards in this Set

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Relative Formula Mass
Mass of a compound molecule, calculated by adding all of the Ar's (relative atomic masses) for the component atoms (Mr/RFM/RMM)
what is the relative atomic mass of H2O?
H2O= (2x1)+16=18
H=1
O=16
Mr of Al2 (so4)3
(so4)3= (2x27)+(32x3)+(16x4x3)=342
Al=27
S=32
0=16
Mr of citric acid C6H8O7
C6H8O7= (12x6)+(1x8)+(16x7)=192
C=12
H=1
O=16
Moles& Avogadro's number
Atoms are too small to count/weigh individually, so chemists group them together. 6.02x1023 is the number of atoms called the mole.
Moles equation
Moles= Mass/Molar mass
how many moles in 73g of HCl
Moles=Mass/Molar Mass
73/(1+35.5)
= 2 moles
196g of H2So4
moles=?
Moles=Mass/Molar mass
196/(2+32.1+64)
=2 moles
2 moles of iron
what is the mass?
Mass=Moles x Molar mass
2 x 55.8
Mass= 111.6 g
0.1 moles of S8
Mass=?
Mass=moles x molar mass
0.1 x (32.1 x 8)
=25.6 g
molar volume of gases
when working with gases, chemists calculate how many moles of gas are present from the volume of the gas. therefore 1 mole of gas at RTP (Room Temperature Pressure) has a volume of 24dm3.
Room temperature= 25 degrees
Room pressure= 1 atm
Moles in gases equation
Moles = volume of gas in dm3/24dm3

1dm3= 1000cm3

cm3/1000=dm
24,000cm3 of Cl
Moles=?
2.4/24
0.1 moles
Mg +H2So4 = MgSo4+ H2
How many moles of Mg?
Mg=24.3
H2=2
S=32.1
O4= 64
Moles of Mg= mass/molar mass
=2.4/24.3
=0.1 moles of Mg
Hydrated
Forms a complex with water
Empirical formula or EF
shows the simplist whole number molar ratio of atoms in a molecule
EF of Fe2O3
Fe:O
2:3
EF = Fe2O3
EF of Al2O6
Al:O
2:6
=1:3
AlO3
An experiment shows that 64g of conmpound contains 48g of C and 16g of H. Calculate the empirical formula.
C H
Mass= 48 16
Molar mass= 12 1
Moles= 4 16
Ratio= 1:4
EF= CH4
Molecular Formula
Shopws the actual number of atoms in a compound and is a simple multiple of the Empirical formula
for example:

EF= CH3
MF= CH3 x 2
MF= C2H6
Find the MF of a compound whose EF is CH2 and has a mass of 84g
Mass of EF=
(12 x 1)+(1 x 2) = 14g
N= the amount to multiply the EF by
N= molar mass/empirical mass
= 84/14
=6
6 x CH2
C6H12
N= the amount to multiply by
what is the equation?
N= molar mass/empirical mass
Find the MF of CH2
Mass of EF= 912 x 1) + (1 x 2) =14g
N= molar mass/empirical formula
=28/14
=2
MF+
% yield equation
% yield = obtained yield/ theoretical yield X 100
The theoretical yield of X is 12.5g
Actual yield= 8.25g
8.25/12.5 x 100
= 66%
Reversible reactions
Some reactions can move in both directions. They are known as reversible reactions.
Example of an irreversible reaction
C+ O2 = CO2
Example of a reversible reaction
CuSo4.5H20 = CuSo4 + 5H2O
hydrated copper sulfate complex (blue crystals) = Anhydrous copper sulfate (white)
It goes white because the water has been removed.
Dynamic equilibrium
In a reversible reaction, the forward and back reactions are happening at the same time. The forward reaction always goes first, but as soon as products are formed, the back reaction begins. Eventually, a steady state will be reached and the forward and backwards reaction are happening at he same time. This is Dynamic Equilibrium.
How does the position of the equilibrium point tell us the proportion of the products and reactants.
EQM point to the right = more products
EQM point to the left = more reactants
Kinetic theory of matter
all particles above absolute zero have kinetic energy
Collision theory
In order for a reaction to happen, particles must collide.
4 ways to change the equilibrium point
1. a higher temperature
2. particle size (smaller particles= greater surface area)
3. Change the concentration
4. A catalyst will make the reaction meet its equilibrium much faster, with less energy
The Haber Process
Air is liquefied under pressure
Nitrogen is separated out by fractional distillation
Hydrogen is extracted from Methane
Nitrogen and hydrogen are combined to make Ammonia
High temperature, pressure and catalyst is needed.
Used for explosives, dye making, medicines and fertilisers.
Why is an iron catalyst used in the Haber process?
The iron catalyst is used in the Haber process because it increases the rate of reaction and speeds up both the forward and backwards reaction up.
If the temperature increases what will happen to the yield?
The yield would decrease because a low temperature favours the exothermic reaction
why is a high pressure not used?
A high pressure is not used because it is too expensive and dangerous.
Le Chatalier's Principle
If a dynamic equilibrium is disturbed by the conditions, the reaction will move to counteract the change.