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65 Cards in this Set

  • Front
  • Back

What does the mass number tell you?


What does the atomic number tell you?


Mass: Total of protons and neutrons


Atomic: Number of protons

When are compounds formed?


When atoms of two or more elements are chemically combined together.


e.g carbon dioxide = chemical reaction between carbon and oxygen

What are isotopes?


Different atomic forms of the same element, which have the SAME number of PROTONS but a DIFFERENT number of NEUTRONS.

Name a popular pair of isotopes

Carbon-12 and carbon-14

What is ionic bonding?


Transferring electrons


Atoms lose or gain electrons to form charged particles (called ions) which are then strongly attracted to one another (because of the attraction of opposite charges)


What kind of structure does an ionic compound have? Describe it

A regular lattice structure


Ionic compounds always have giant ionic lattices


The ions form a closely packed regular lattice arrangement


There are very strong electrostatic forces of attraction between oppositely charged ions, in all directions




What are the similar properties of ionic compounds?


High melting points and high boiling points - due to strong attraction between ions. It takes a large amount of energy to overcome this attraction


When to ionic compounds melt, the ions are free to move and they'll carry electric current.


Dissolve easily in water & will carry electric current

Which groups are most likely to form ions?


1 & 2 (which are metals)


6 & 7 (which are non metals)

What electronic structure does an ion have?

Noble gas

What is the overall charge of any ionic compound?


0


(positive balance out negative)

What is covalent bonding?


Sharing electrons


Only share with outer shell (highest energy level)


Each atom involved has to make enough covalent bonds to fill up its outer shell

Describe the structure of simple molecular substances

The atoms form very strong covalent bonds to form small molecules of several atoms


By contrast, the forces of attraction between these molecules are very weak


Weak intermolecular forces results in low melting and boiling points as the molecules are easily parted from each other


Most are gases or liquids at room temp, but can be solids


Don't conduct electricity - no ions

Describe the structure of giant covalent substances


Macromolecules


Similar to giant ionic lattices but there are no charged ions


Bonded to each other by strong covalent bonds


Very high melting and boiling points


Don't conduct electricity


Main examples - diamond, graphite and silicon dioxide

Describe the structure of diamond


Each carbon atom forms four covalent bonds in a very rigid giant covalent structure


The structure makes diamond the hardest natural substance

Describe the structure of graphite


Each carbon atom forms three covalent bonds - this creates layers which are free to slide over each other


Layers are held loosely together meaning that they can be rubbed off onto paper - weak intermolecular forces


Only non metal which is a good conductor of heat and electricity - each carbon atom has 1 delocalised electron

Describe the structure of silicon dioxide

Sand ismade of this


Each grain of sand is one giant structure of silicon and oxygen



What are the properties of metal

All properties are due to the sea of free electrons


Giant structure


Metallic bonds involve delocalised electrons - come from outer shell of every atom in the structure


Good conductors of heat and electricity


Free electrons hold atoms together in a regular structure


Strong forces of electrostatic attraction between the positive metal ions and the negative electrons


Allow the layers of atoms to slide over each other



Why are alloys harder than pure metals?


Two or more metals are mixed together to create an alloy


Due to the different sized atoms, the layers are distorted meaning that they cannot slide over each other and therefore the alloy cannot be bent or shaped & are harder

What are the four structures of substances?

Giant ionic


Simple molecular


Giant covalent


Giant metallic

Give an example of a smart material and explain its properties

Nitinol - a "shape memory alloy" it's a metal alloy, but when cool you can bend it and twist it like rubber. When bent too far, it stays bent but if you heat it above a certain temperature, it goes back to a "remembered" shape.


Handy for glasses frames - if bent, but into bowl of hot water.


Used for dental braces too.

What is a nanoparticle?


1-100 nanometres across


Roughly a few hundred atoms per nanoparticle


Include fullerenes - molecules of carbon, shaped like hollow balls or closed tubes, arranged in hexagonal rings.



What are some uses of nanomaterials?


-Have a huge surface area to volume ratio, so they help make new industrial catalysts


-Can be used to make sensors to detect one type of molecule and nothing else. These sensors are already being used to test water purity


-Nanotubes can be used to make stronger, lighter building materials


-New cosmetics e.g sun tan cream, deodorant have been made using nanoparticles - don't leave white marks on skin


-Nanomedicine


-Lubricant coatings


-Tiny electric circuits

What determines the properties of plastics?

Forces between molecules
Strong covalent bonds hold the atoms together in long chains, but it's the bonds between the different molecule chains that determine the properties of the plastic



Thermosoftening polymers


Don't have cross linking between chains - weak intermolecular forces


Forces between chains are easy to overcome - easy to melt the plastic


When cools, it hardens into a new shape


Can melt these plastics and remould them as many times as you like

Thermosetting polymers


Have crosslinks - stronger intermolecular forces


These hold the chains together in a solid structure


Doesn't soften when heated


Strong, hard and rigid


What will affect the properties of a polymer?

How you make it - the starting materials and reaction conditions




What are the two types of polythene and what are their different conditions which they are made in?


Low density - made by heating ethane to about 200'c under high pressure. It's flexible and is used for bags and bottles


High density - made at a lower temperature and pressure (with a catalyst). It is far more rigid, and is used for water tanks and drain pipes.

What is the relative atomic mass?


How heavy different atoms are compared with the mass of an atom of carbon-12.


It is the same as the mass number of the element.

What is the relative formula mass?

In a compound


Adding up all the relative atomic masses


What is one mole equal to?

The relative formula mass of a substance in grams is known as one mole of that substance
How do you work out the number of moles?

Mass in g/Relative formula mass

How do you work out the percentage mass of an element in a compound?


RAM x no. of atoms in that element


/


RFM of whole compound


x 100

How do you work out the empirical formula?


List elements


Write percentages or experimental masses


Divide each mass by the RAM


Turn this into a ratio


Put the ratio into its simplest form

What is the calculation for the percentage yield?


Actual yield (grams)


/


predicted yield (grams)


x 100

Give three reasons as to why yields cannot be 100%


The reaction is reversible


Filtration


Unexpected reactions

How do you separate artificial colours using paper chromatography?


1 - extract the colour from a food sample by placing it in a small cup with a few drops of solvent


2 - put spots of the coloured solution on a pencil baseline on filter paper


3 - Roll up the sheet and put it in a beaker with some solvent


Why should you not use pen when doing paper chromatography?

It might dissolve in the solvent

What are the advantages of using machines to analyse unknown substances?


Very sensitive


Very fast


Very accurate

Give 3 examples of rate of reaction experiments

Hydrochloric acid and marble chips


Reaction of magnesium metal with dilute HCl


The decomposition of hydrogen peroxide

What does the decomposition of hydrogen peroxide show?


What is the ideal way to measure the rate of reaction in this experiment?


What gas is given off?


The effect of different catalysts


Gas syringe


Oxygen

What does the reaction of magnesium metal with dilute HCl show?


How can we measure the rate of reaction?


What gas is given off?

Effects of increased concentration


Change in mass


Hydrogen gas



What does the reaction of hydrochloric acid and marble chips show?


How can we measure the rate of reaction?




The effect of changing the surface area


Gas syringe

What are advantages of using catalysts?

Reduce costs -


Increase the rate of reaction, saves money - plant doesn't need to operate for as long to produce the same amount


Allow the reaction to work at a much lower temperature, reduces energy used up (energy cost), which is good for sustainable development & can save a lot of money



What are some disadvantages to using catalysts>

Can be expensive to buy, often need to be removed from the product and cleaned


Different reactions use different catalysts


They can be poisoned by impurities, so they stop working - have to keep reaction mixture very clean

What is an exothermic reaction?

A reaction which gives out heat energy to the surroundings, usually in the form of heat and usually shown through a rise in temperature
Give 3 examples of exothermic reactions


Burning fuels/COMBUSTION


Neutralisation reactions (acid + alkali)


Oxidation


What is an endothermic reaction?

A reaction which takes in energy from the surroundings, usually in the form of heat and is usually shown by a fall in temperature.


They are much less common

Give an example of an endothermic reaction

Thermal decompositions e.g. decomposing calcium carbonate to make quicklime.


Where are acids on the pH scale?


Where are alkalis?


Acids = 0 - 6


Alkali = 8 - 14


How can you test the pH of a substance?

Using an indicator


The dye changes colour depending on whether its above or below a certain pH


What is an acid, a base and an alkali?


Acid - a substance with a pH of less than 7. Acids form H+ ions in water


Base - a substance with a pH of greater than 7


Alkali - a base which dissolves in water. They form OH- ions in water.

What do the following state symbols show you?


(s), (l), (g), (aq)


(s) - solid


(l) - liquid


(g) - gas


(aq) - aqueous, dissolved in water


What do you get when metals react with acids?


Salts (+hydrogen)

How can you make a salt insoluble?


Precipitation reactions




What does electrolysis mean?


Splitting up with electricity


How does electrolysis occur?


-You pass an electric current through an ionic substance that's molten or in solution - it then breaks down into the elements its made of


-It requires a liquid to conduct the electricity, called the electrolyte


-Electrolytes contain free ions - usually the molten or dissolved ionic substance


-Electrons are taken away from ions at the positive electrode and given to other ions at the negative electrode.

Explain


OILRIG


Oxidation Is Loss, Reduction Is Loss


Reduction involves the los of oxygen, and the gain of electrons


Oxidation involves the gain of oxygen and loss of electrons


Electrolysis always involves this.


What is the electrolyte in electrolysis?


The liquid which conducts the electricity


What occurs at the positive electrode?


Electrons are taken away from ions


Lose

What occurs at the negative electrode?

Electrons are given to ions


Gain

What is produced where in the electrolysis of lead bromide?


Lead is produced at the -ve electrode


Bromine is produced at the +ve electrode


At the -ve electrode, one lead ion accepts two electrons to become one lead atom


At the +ve electrode, two bromide ions lose one electron each and become one bromine molecule

What is cryolite used for?
To lower the remperature and costs in electrolysis
How does electroplating use electrolysis?


To coat the surface of one metal with another metal


The negative electrode is the metal object you want to plate


The positive electrode is the pure metal you want it to be plated with

Give an example of when electroplating could be used


To electroplate silver onto a brass cup


The brass cup at the negative electrode


A lump of pure silver at the positive electrode



Give 2 positive uses of electroplating


Decorating - silver is attractive but very expensive


Conduction - metals like copper conduct electricity very well, often used to plate circuits and computers.