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8 Cards in this Set

  • Front
  • Back

-Define the term relative atomic mass


-In a mass spectrometer, the relative abundance of each isotope is proportional to thecurrent generated by that isotope at the detector. Explain how this current is generated.

-Mean average mass of atoms of an element compared to carbon-12


-Electron(s) transferred / flow (at the detector)(From detector / plate) to the (+) ion

State the meaning of the term first ionisation energy

Energy/enthalpy (needed) to remove one mole of electrons fromone mole of atoms/compounds/molecules/elementsOREnergy to form one mole of positive ions from one mole of atomsOREnergy/enthalpy to remove one electron from one atomIn the gaseous state (to form 1 mol of gaseous ions)

State and explain the general trend in the first ionisation energies of the Period 3elements sodium to chlorine

Increase


Bigger nuclear charge (from Na to Cl)/more protons


electron (taken) from same (sub)shell/ similar or same shielding/electron closer to the nucleus/smaller atomic radius

State the element in Period 3 that has the highest melting point.Explain your answer.

Silicon / Si


covalent (bonds)


Strong or many of the (covalent) bonds need to be broken / needs a lot ofenergy to break the (covalent) bonds

State the element in Period 3 that has the highest first ionisation energy.Explain your answer.

Argon / Ar


Large(st) number of protons / large(st) nuclear charge


Same amount of shielding / same number of shells / same number of energylevels

Predict whether the atomic radius of 124Te is larger than, smaller than or the same as theatomic radius of 130TeExplain your answer.

Same


(Each isotope has the) same number of protons/same nuclear charge andsame number of electrons / electronic configuration

Explain, in terms of electronegativity, why the boiling point of H2S2 is lower than H2O2

Electronegativity of S lower than O or electronegativity difference between Hand S is lowerNo hydrogen bonding between H2S2 moleculesOr only van der Waals / only dipole-dipole forces between H2S2 molecules

A TOF mass spectrometer can be used to determine the relative molecular mass ofmolecular substances.Explain why it is necessary to ionise molecules when measuring their mass in a TOFmass spectrometer

Ions, not molecules, will interact with and be accelerated by anelectric fieldOnly ions will create a current when hitting the detector