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50 Cards in this Set

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What is a formula unit?

The fundamental particle held together by an ionic bond


- could you just call it an ionic compound?????

What is a molecule?

The fundamental particle held together by a covalent bond.

True or False?


Diatomic Molecule are always Polar.

False,


Diatomic Molecules are always non-polar because the two atoms have the same electronegativity

What is a Polar Bond?

A polar bond is one in which one atom in the bond has a stronger attraction than the other atom for the electron pair (and essentially holds them closer)

Non-Polar Bond

When two atoms in a bond have the same attraction for the electron pair (same electronegaivity)

When is Delta Notation used, what does it look like and what does the notation refer to?

It is used to show which atom, in a polar bond, has the greater electronegativity.


- It looks like this S(-), S(+) denoted above the formula


- The S refers to slightly. = Slightly more negative OR slightly more positive

What atoms form covalent bonds?

2 or more non-metals

What is a double bond

When 2 atoms form a covalent bond by sharing 2 pairs of loose electrons

What is a triple bond?

When 2 molecules form a covalent bond by sharing three pairs of loose electrons

True or False?


A chemical bond containing a metal is always an ionic bond



True

What is Electronegativity?

The measure of the ability of an atom to attract electrons in a chemical bond.

What are the elements that naturally form diatomic covalent bond?

H, O, F, N, I, Cl, Br

H-appy


O-n


F-riday


N-ight


I-ce


Cl-Cold


Br-Beer

Can two atoms be isoelectronic with each other?



NO, however an ion of an element can be isoelectronic with another atom or ion.


i.e. Rb(+) is Isoelectronic with Kr.

What does Isoelectronic refer to?

It refers to two ions or atoms having the same # of electrons.

Can an ion have the same electron configuration as an atom of a different element?

Yes,


because the electron configuration shows how many electrons are present in an ion or atom. And just as an ion can be isoelectronic with an atom of a different element, so can its electron configuration be the same.

What 3 transition elements are exceptions to the Roman numeral Rule?

Zinc, Cadmium, Silver

What Non-transition metals are an exception to the Roman numeral rule?

Tin & Lead

*Remember: these ones have weird prefixes (they use the latin prefix instead of the English ones, they are not hard to miss)

What is the difference between Monoatomic and Polyatomic Ions?

Monoatomic ions are single atoms with a charge, whereas polyatomic ions are a group of atoms with an overall charge

True or False?


When expressing a formula-unit in writing, you should write the metal before the non-metal, followed by the word "ion":


i.e. 'Calcium phosphate ion'

False,


it is incorrect to express a formula unit as an ion. Once two ions combine to form a formula-unit, they have full valence shells, and are no longer considered ions.

True or False?


All atoms with the suffix '-ide' are monoatomic ions, and should be written with this suffix when expressed in a molecular formula.

True with exceptions;


The exceptions are hydroxide and cyanide, which are polyatomic ions.

What suffix is used to express polyatomic ions?

"-ate" & "-ite"

True or False


If asked to write the name of a formula with a charge, you should always write "ion" following the name.


i.e. Cu(2+)

True


= Copper (II) ion

True or False?


Diatomic molecules always have the suffix "-ide"

True

What is the charge of a zinc (Zn) ion?

2+

What is the charge of a Nickel (Ni) ion?

It varies

What is the charge of an Aluminum (Al) ion?

3+

What is the charge of a Lead (pb) ion?

it varies

What is the charge of a silver (Ag) ion?

1+

What is the charge of a Cadmium (Cd) ion?

2+

What are the rules of nomenclature for Covalent Bonds?

- add suffix "-ide" to ONLY the second element in the equation


- add prefix that correlates with the # of elements in the equation.


- the prefix "-mono" should NOT be used with 2 exceptions (Carbon monoxide, Nitrogen monoxide)



What is the name for this compound?


Br3O7

tribromine heptaoxide

true or false?


In ionic bonds, the charge ratio of ions always has to be 1:1, but the # of ions in the equation does not have to be 1:1

True

true or false?


In ionic bonds, the number of ions in the equation has to be 1:1, but the charge ratio of the ions does not have to be 1:1

False

What is the name of the theory that explains the shapes of molecules?

Valence Shell Electron Pair Repulsion Theory


(VSEPR)

What are the two types of electrons involved in the VSEPR theory?

1 - Non bonding electron pairs (Lone pairs)


2 - Bonding electron pairs

According to the VSEPR theory, what determines the shape of molecules?

The electron pairs will arrange themselves in space the farthest apart from one another because they are negatively charged

What is the general idea of the VSEPR theory?

That outer energy level electrons determine the shape of a molecule.

What is the shape and bond angle of a methane molecule CH(4)?

- tetrahedral (109.5 deg)

What is the shape and bond angle of an ammonia molecule NH(3)?

- trigonal pyramidal (107 deg)

What is the shape and bond angle of a water molecule H(2)O?

- Bent (104.5 deg)

What is a general rule of thumb for determining if the valence electrons will be spaced at equal distances in a covalent bond?

- If the atoms involved in the bond are polar, and if there is a lone pair in the bond, there will be an unequal spacing due to the inconsistency in electron strength.

What is the molecular shape and bond angle of CO(2)?

- linear (180 deg.)

Elctronegativity ________________ from left to right within a period and ______________ from top to bottom within a group.

> Increases


> Decreases

why is it a good idea to double check the numbers on bonds before naming them?

1- they could have been reduced


2- it can be easy to confuse # of atoms in bond with charge, leading to naming the wrong transition element (i.e. Iron II instead of Iron III)


3 - it is a method to double check if a bond is covalent...in case you miss it.

name this compound:


Si(2)Br(6)

disilicon hexabromide

name this compound:


Pb(SO4)2

Lead (IV) Sulfate

This is an example of why it's important to check the charges on the formula.


- In this example the formula has been reduced. So you wouldn't know that it refers to Lead (IV) unless you check the charge

Define Polar Covalent Bond:

> A bond between two or more non or semi-metals


> in which the atoms share one or more pairs of electrons.


> The bond is unequal due to difference in electronegativity, which results in various molecular shapes.

what is the covalent prefix for 10?

deca

what is the covalent prefix for 6?

hexa



what is the covalent prefix for 9?

nona