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10 Cards in this Set

  • Front
  • Back
What the equation when a halide ion reacts with sulphuric acid acting as an acid?
e.g. NaCl + H2SO4 -> HCl + NaHSO4 (same with all halides)
What would you see when sulphuric acid acts as an oxidising agent with chloride or fluoride ions?
Steamy fumes
What would you see when sulphuric acid acts as an oxidising agent with Bromide ions?

What is the ionic equation for this reaction?
1. Steamy fumes
2. Brown vapour (bromine)
3. Suplphur dioxide (colourless gas)

4H(+) + SO4(2-) + 2Br(-) -> SO2 + 2H2O + BR2
What would you see when sulphuric acid acting as an oxidising agent reacts with iodide ions?

What is the ionic equation for this reaction?
1. Steamy fumes ( hydrogen iodide)
2. Purple vapour or grey solid (iodine)
3. Yellow solid suplur
4. Rotten egg smell (Hydrogen Sulphide)
5. Colourless gas (sulphur dioxide)

10H(+) + SO4(2-) + 8I(-) -> H2S + 4I2 + 4H2O
What happens to the reducing ability of the halides as you go down the group?
Increases
What factors increase rate of reaction?
1. Concentration
2. Temperature
3. Surface Area
4. Catalyst
5. Pressure (gases only)
What happens to electronegativity of halogens as you go down the group?

Why?
Decreases

Shielding increases meaning that outer rlectrons are less attracted to the nucleus
What is the trend in boiling points of the halogens as you go down the group?

Why?
Increases

The size of the van der waal forces increase as atomic radius increases
What happens to oxidising ability of halogens as you go down the group?
Decreases (F2 - STRONG BUT I2 WEAK)
An oxidising agent is.......?

A reducing agent is.........?
Reduced

Oxidised