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44 Cards in this Set
- Front
- Back
Chemical equilibrium
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A type of dynamic equilibrium that occurs when a reaction and its reverse reaction proceed at the same rates
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Approaches equilibrium
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Both the forward and reverse reactions are occurring but at different rates
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Equilibrium achieved
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Both the forward and reverse reactions are occurring at the same rate
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keq
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equilibrium constant
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Equilibrium expression
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kc = C^c x D^d / A^a x B^b
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kp
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Particle pressure
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Relationship between KC and KP
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Kp = Kc (RT)^ ∆n
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∆n
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Moles of gases product - moles of gases reactants
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products, reactants
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K>1 favor
K<1 favor |
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Homogenious equilibrium
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When all substances and chemical equilibrium are in the same phase
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Heterogeneous equilibrium
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When all substances in a chemical reaction are not in the same phase
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Pure solid or liquid
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These concentrations do not matter in an equation
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For a system that is not yet at equilibrium
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Q is used when
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Too much product left
Too much reactants right |
Q > K too much _____ shifts _____
Q< K too much ______ shifts ______ |
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Le Chateliers Principle
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1. Adding or removing a reactant or product
2. Change in pressure or volume 3. Change in temperature |
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expert a lower pressure
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Fewer gas molecules
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a change in volume or pressure will not shift in either direction
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If the number of gas molecules is the same on both side...
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Pressure and volume
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Inverse of each other
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Endothermic
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Increasing temperature a reactant results in more product so K is larger
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Exothermic
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Increasing temperature a product results and more reactant so K is smaller
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Catalyst
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Increase the rate of those for it and reverse reaction by same amount. The cooler brand is it cheaper faster but does not change the position of the equilibrium picture.
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Arrhenius
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Acid substance that dissolves in water increases concentration of protons.
Base of substance same |
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Bronsted - Lowry
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Acid proton donor. base proton acceptor
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amphiprotic amphoteric
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Chemical species that can either donate or accept protons
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Hydronium
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H3O+
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The weaker its conjugate is
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The stronger an acid or a base...
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Moving the proton from the stronger acid to the stronger base
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Equilibrium will favor which type of reaction for acids and bases
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Autoionization
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In pure water a few molecules act as bases and if you act as acid to form hydroxide and hydronium ions
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KW
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1.0 x 10^-14
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- log of
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PH
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10^-ph
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H3O+
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14
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PH + Poh
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Basic
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Red paper blue
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acidic
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Blue paper red
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- log of M, if base subtract from 14
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For strong acids and bases if it gives you the molarity then...
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Ka
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Acid dissociation constant
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Percent ionization
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H+ equilibrium/ Ha initial x 100
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Ka Kb
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[H+]^2 / ACID
[OH-]^2 / BASE |
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Presentaion ionization is less than 5%
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In an acid and base calculation for pH you do not need an ice table if
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Neutral
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Nacl
Na -> base Na(OH-) strong Cl -> acid HCl strong |
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Oxy acids
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Acid in which an OH- group is bonded to another atom Y
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Lewis base
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Electron pair donators
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Lewis acid
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Electron pair acceptor
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enzymes
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catalyst of biological systems
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