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44 Cards in this Set

  • Front
  • Back
Chemical equilibrium
A type of dynamic equilibrium that occurs when a reaction and its reverse reaction proceed at the same rates
Approaches equilibrium
Both the forward and reverse reactions are occurring but at different rates
Equilibrium achieved
Both the forward and reverse reactions are occurring at the same rate
keq
equilibrium constant
Equilibrium expression
kc = C^c x D^d / A^a x B^b
kp
Particle pressure
Relationship between KC and KP
Kp = Kc (RT)^ ∆n
∆n
Moles of gases product - moles of gases reactants
products, reactants
K>1 favor

K<1 favor
Homogenious equilibrium
When all substances and chemical equilibrium are in the same phase
Heterogeneous equilibrium
When all substances in a chemical reaction are not in the same phase
Pure solid or liquid
These concentrations do not matter in an equation
For a system that is not yet at equilibrium
Q is used when
Too much product left
Too much reactants right
Q > K too much _____ shifts _____
Q< K too much ______ shifts ______
Le Chateliers Principle
1. Adding or removing a reactant or product
2. Change in pressure or volume
3. Change in temperature
expert a lower pressure
Fewer gas molecules
a change in volume or pressure will not shift in either direction
If the number of gas molecules is the same on both side...
Pressure and volume
Inverse of each other
Endothermic
Increasing temperature a reactant results in more product so K is larger
Exothermic
Increasing temperature a product results and more reactant so K is smaller
Catalyst
Increase the rate of those for it and reverse reaction by same amount. The cooler brand is it cheaper faster but does not change the position of the equilibrium picture.
Arrhenius
Acid substance that dissolves in water increases concentration of protons.

Base of substance same
Bronsted - Lowry
Acid proton donor. base proton acceptor
amphiprotic amphoteric
Chemical species that can either donate or accept protons
Hydronium
H3O+
The weaker its conjugate is
The stronger an acid or a base...
Moving the proton from the stronger acid to the stronger base
Equilibrium will favor which type of reaction for acids and bases
Autoionization
In pure water a few molecules act as bases and if you act as acid to form hydroxide and hydronium ions
KW
1.0 x 10^-14
- log of
PH
10^-ph
H3O+
14
PH + Poh
Basic
Red paper blue
acidic
Blue paper red
- log of M, if base subtract from 14
For strong acids and bases if it gives you the molarity then...
Ka
Acid dissociation constant
Percent ionization
H+ equilibrium/ Ha initial x 100
Ka Kb
[H+]^2 / ACID
[OH-]^2 / BASE
Presentaion ionization is less than 5%
In an acid and base calculation for pH you do not need an ice table if
Neutral
Nacl
Na -> base Na(OH-) strong
Cl -> acid HCl strong
Oxy acids
Acid in which an OH- group is bonded to another atom Y
Lewis base
Electron pair donators
Lewis acid
Electron pair acceptor
enzymes
catalyst of biological systems