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71 Cards in this Set

  • Front
  • Back
Ionic bonding uses what types of elements?
Metal to nonmetal
Covalent bonding uses what type of elements?
nonmetal to nonmetal
Metallic bonding uses what type of elements?
metal to metal
Metals __ valence e- making them a ___
lose.
cation.
nonmetals___ valence e- making them an ___
gain.
anion.
Electronnegativity is
the abiltiy of an element to attract e- to itself within a covalent bond
Pure covalent bonds (nonpolar bonds) have no ____ moment.
dipole
Mass % =
Mass Solute
______________ x 100
Mass Solution
Mole fraction =
Mole solute/ mole soulte + mole slovent
Molality =
Moles of solute/ kg of slovent
Molarity =
Moles of soute/ L of solution
Mass solution =
mass solute + mass solvent
Molarity containing density =
mass solution= d solution x v solution
metals lose ______ e- and become ______.
valence, cations
nonmetals gain ______ e- and become _______.
valence, anions
Ionic bonding
metal to nonmetal
covalent bonding
metal to metal
Nonpolar covalent bonds
Bonds between two nonmetal atoms with equal EN.
The _______ the EN, the closer bonding e- pair to itself
greater
polar molecules dissolve ________ molecules.
polar
nonpolar molecules dissolve __________ molecules.
nonpolar
intramolecular forces
forces between atoms/ ions (within molecules)
ion-dipole forces
forces between ions and charge centers from polar molecules.
dipole-dipole forces
attraction of opposite charge poles of two molecules
The more _____ the molecule the more attraction between molecules, the _____ the forces.
Polar, stronger
The more electrons, the more ________.
polarizability
The greater the ______ the more polarizability.
size
Down a group, polarizability
increases
Cross a period (L to R)
polarizability
decreases
less polarizable
cations
more polarizable
anion
The greater ________, the more space and easier for charge to
build up, the greater ________ _______ moment
polarizability, instaneous, dipole
The more ________ in a
molecule, the ______ size
of a molecule, the _______
polarizability, the greater
_________
electrons, bigger, greater, induced dipole
London forces (Dispersion forces)
Instantaneous dipole – induced dipole forces
Exist in ALL covalent molecules
London forces (Dispersion forces)
Instantaneous dipole – induced dipole forces
The more electrons within a molecule, the stronger _______.
london forces
The larger the molecule, the stronger ________
london (dispersion) forces
Occur in all polar molecules
dipole-dipole forces
The more polarity, the stronger the
dipole forces
London < dipole if molecules are less
polarizable
London > dipole if molecules are more
polarizable
The greater the intermolecular forces, the higher
boiling point
The greater intermolecular forces, the
more ________ molecules to move around
difficult
The higher the IM forces, the _______ ΔHvap, the _____ Pvap
higher, lower
The _______ the T, the ______ Pvap
higher, higher
A liquid “boils” when its vapor pressure is _______ to an
externally applied pressure
equal
Line where liquid and solid
phases exist in equilibrium
fusion curve
Line where liquid and gas
phases exist in equilibrium
Vaporization curve
Line where solid and gas
phases exist in equilibrium
sublimation curve
________ occurs when
substance has a triple point higher than 1 atm
Sublimation
A combination of lowest T, P
where liquid and gas phases
are no longer distinct
critical point
The temperature on the
vaporization curve where
Pressure is 1 atm
normal boiling point
The temperature on the fusion curve where Pressure is 1 atm
normal melting point
the slope of a positive fusion curve m.p. increases as P _______, solid occupies _______ space and has a ______ density.
increases, less, greater
P increases⇒ V ________, when the slope of fusion curve is positive.
decreases
m.p. ______ as P increase when the slope of the fusion curve is negative
decreases
When the slope of the fusion curve is negative, solid occupies _____ space and has _____ density.
more, less
different molecular forms of the same element
allotropes
2 C.C
0 lone pairs
Linear
3 C.C
0 lone pairs
Trigonal planar
3 C.C
1 lone pair
Bent shape
4 C.C
0 lone pairs
Tetrahedral
4 C.C.
1 lone pair
Trigonal pyramidal
4 C.C.
2 lone pairs
Bent
5 C.C.
0 lone pairs
trigonal bipyramidal
5 C.C.
1 lone pair
seesaw
5 C.C
2 lone pairs
T-shape
5 C.C
3 lone pairs
linear
6 C.C
0 lone pairs
octahedral
6 C.C
1 lone pair
Square pyramidal
6 C.C
2 lone pairs
Square planar