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29 Cards in this Set

  • Front
  • Back

Law of Conservation

Energy can neither be created nor destroyed. It can only be transferred between the system and surroundings.

First Law of Thermodynamics

In any process, the cabbage in energy of a system is equal to the heat another by the system and the work done on it.

Endothermic

System absorbs hear

Exothermic

System releases heat

Heat

Is a form of energy transfer between two objects as a result of different temperature.

Calorimeter

An insulator apparatus that contains water or liquids of any heat capacity.

Calorimeter

Used to determine heat capacity of a substance

Calorimetry

Measures flow of energy between system and surroundings.

Thermochemistry

Branch of thermodynamics which deals with the interconversion of energy: heat and work

Thermochemical equation

Chemical equation that shows the value is heat involved in reaction

Ethalpy

Amount of heat absorbed or released by a chemical reaction at constant atmospheric pressure

Ethalpy

Form of chemical energy

Chemical Kinetics

Study of the rate of chemical reactions

Rate of a reaction

The change in the concentration of a reactant or product per change in time

Rate Law

Mathematical expression that shows how the rate of reaction depends on the concentration of the reactants.

Reaction order

Dictates how the rate responds to variations in the concentration of the reactants

Method of Initial Rates

Determines how the rate is affected by concentration by comparing the initial rates of reaction at different initial concentrations of reactants.

Integrated Rate Law

Is an equation that expresses the concentrations of reactants or products as a function of time.

Reaction Mechanism

A sequence of reaction steps that show how the reactants are converted into products.

Rate-determining step

Dictates rate law of the reaction in reaction mechanism

Molecularity of the Reaction

Indicates the number of molecules that are involved in the rate-determining step

The Collision Theory

Contact between the reactants

Activation energy

Must have sufficient energy during collision

Activation energy

Energy barrier

Catalysis

The process of speeding up a chemical reaction

Catalysts

It speeds up a chemical reaction

Homogenous

It is a catalyst in the same place of the reaction

Heterogenous

It is a catalyst in a different phase of the reaction

Arrhenius Equation

Effect of temperature on reaction rate