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32 Cards in this Set

  • Front
  • Back

c=c HX and ether

add halogen and hydrogen to c-c bond

c=c X2 and CH2Cl2

add X and X anti stereochemistry to c-c bond

c=c X2 and H2O

add X and OH to c-c bond, HX is left over

c=c H3O+

markovnikov, addition of H and OH to c-c bond

c=c Hg(OAc)2, H2O/THF


NaBH3

markovnikov, addition of H and OH to c-c bond 2 steps

c=c BH3 THF


H2O2, OH-

anti markovnikov, addition of H and OH to c-c bond 2 steps

c=c H2 and metal catalyst

c-c

c=c RC=OOOH

epoxide

epoxide acid

diol trans

c=c OsO4


NaHSO3, H2O

diol cis

c=c + CHCl3 KOH

cyclopropane + dichloro

c=c O3


Zn H3O

c=o o=c

diol HIO4


H2O

c=o o=c

conjugated diene HBR

two possibilities depending on carbocation

alkyne + H2 and metal catalyst

c-c

alkyne + H2 and lindler catalyst

c=c

alkyne + H3O


HgSO4

acetate

alkyne + NaNH2

acetylide anion

Benzene + Br2 FeBr3

Br addition HBr

Benzene + Cl2 FeCl3

Cl addition and HCl

Benzene +I2 CuCl2

iodine addition and HI

Benzene + HNO3


H2SO4

NO2 addition + H2O

Benzene +SO3


H2SO4

SO3H addition

Benzene + CH3Cl


AlCl3

CH3 addition + HCl

Benzene with nitro group


Fe H3O+


OH-

NH2 substitution

Benzene with a methyl group


KMnO4


H2O

carboxylic acid substitution

Benzene with aryl (ketone) group

ketone loses O and is relaced with 2 hydrogens

1 or 2 alcohol HX and ether

substitution of X



1 or 2 alcohol SOCl2 and pyrimidine

substitution of chlorine

1/2 alcohol PBr3 in ether

substitution of Br

phenol HF and pyrimidine

substitution of F

R-X 2 Li/pentane

R-Li Li-X