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101 Cards in this Set
- Front
- Back
micro
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ten negative six
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NANO
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ten negative nine
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pico
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ten negative 12
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femto
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ten negative 15
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attractive and repulsive forces that act between either electrically charged or magnetic objects
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electromagnetic forces
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same number of protons but different number of neutrons
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isotope
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atomic weight = ??
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abundance of isotope x mass + abundance of isotope2 x mass2
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intrument used to measure precise masses and relative amounts of atomic and molecular ions
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mass spectrometer
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group 1a
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alkali metals
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group 2a
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alkaline earth metals
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group 6a
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chalcogens
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group 7a
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halogens
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group 8a
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noble gases(rare gases)
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rutherford experiment
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shot particles at gold foil, discovered the nucleus
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unit of frequency
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hertz, or cycles per second
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light or dark: wave crests arrive together
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light
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light or dark: wave crest and trough arrive together
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dark
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atoms emit or absorb energy in quanta; energy of light is quantized as photons
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quantum theory
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energy of a photon is what number?
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planck's constant 6.606e-34 j s
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Electrons are emitted by metal only if light has freq greater than certain min. value, not matter how intense the light
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photoelectric effect
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light emitted by excited atoms
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line spectra
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distance between two adjacent peaks
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wavelength
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distance of wave from center line to crest or trough
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amplitude
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smallest wavelength
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gamma rays
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largest wavelength
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radio
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electromagnetic spectrum from smallest to greatest wavelength
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gamma x uv visible infrared microwaves radio
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visible light range
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400 to 700
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visible light order from smallest to largest wavelength
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vibgyor
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emission of light from hot objects
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black body effect
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emission of electrons from metal surfaces on which light shines
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photoelectric effect
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emission of light from electronically excited gas atoms
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emission spectra
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a fixed amount
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quantum
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quantum??
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a fixed amount
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said energy can only be released or absorbed by atoms only in discrete chunks of some minimum size
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planck
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radiation composed of a single wavelenght
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monochromatic
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when radiation from a source is seperated into its different wavelength components
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spectrum
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spectrum containing radiation of only specific wavelengths
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line spectrum
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when n is infinity, energy is
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zero
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limitation of the bohr model
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can only explain line spectrum for H atom
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describes the wave characteristics of material particles
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matter waves
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it is inherently impossible for us to know simultaneously both the exact momentum of the e and its exact location in space
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uncertainty principle
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no two e in an atom can have the same set of four quantum numbers
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pauli exclusion principle
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all orbitals filled unpaired first
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Hund's rule
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quantum number, measures size
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n
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quantum number, measures shape
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l
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quantum number, measures orientation
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ml
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quantum number, measures spin
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ms
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L values correspond to these subshells
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0 s 1 p 2 d 3 f
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region of space with size, shape, characteristic energy
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orbitals
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shape of s orbital number 1
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spherical
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shape of p orbital number 3
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dumbbell
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shape of d orbital number 5
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5 shapes
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principal quantum number
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n
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asimuthal quantum number
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L
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magnetic quantum number
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mL
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these control the chemistry of the elements
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valence electrons
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organization of periodic table determined by
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electron configurations
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elemental properties determined by
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size and shape of orbitals and atomic number
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atomic size across a group, atomic size down a period
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decreases and increases
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effective nuclear charge across a group, effective nuclear charge down a period
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increases and increases
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net positive charge experienced by an electron in a many-electron atom
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effective nuclear charge
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charge equal to the charge minus the shielding
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effective nuclear charge
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is cation or anion smaller?
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cation because has same charge but less e, so each e pulled closer
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ionic size across a period, ionic size down a group
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decreases and increases
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same number of electrons
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isoelectronic series
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energy needed to remove an electron
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ionization energy
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these electrons are more easily removed, outer or inner
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outer
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ionization energy across a period, ionization energy down a group
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increases and decreases
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it takes extra energy to remove an electron when?
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when subshell filled or half filled
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energy needed to add an electron to an atom or ion in gas phase
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electron affinity
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when you add an e to an element
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electron affinity
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electron affinity across a period, down a group
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becomes more negative, very little change
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electronegativity across a period and down a group
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increases across, decreases down
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metallic character across and down
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metallic character decreases across, increases down
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measures the ease with which an atom gains an electron
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electron affinity
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force holding atom or ions together
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chemical bond
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electrostatic force between ions of opposite charge
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ionic bond
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sharing of electrons between two bonded atoms
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covalent bond
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bond found in metals
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metallic bond
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NH4
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1+
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OH
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-1
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CN
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-1
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NO3
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-1
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MnO4
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-1
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CO3
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-2
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CrO4
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-2
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SO4
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-2
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PO4
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-3
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the change in energy when an ionic solid is seperated into isolated ions in the gas phase
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lattice energy
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melting point depends on
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smaller radius means larger lattice means higher meltingg point
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simplest compounds, contain only H and C
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hydrocarbons
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class of hydrocarbons, contains all single bonds
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alkanes
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class of hydrocarbons, contains double bond
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alkenes
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class of hydrocarbons with a triple bond
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alkynes
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equal sharing of electrons
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nonpolar bond
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unequal sharing of electrons
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polar bond
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tendency of an atom to attract electrons to itself in a bond
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electronegativity
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this is the purest covalent bond
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between two identical atoms
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formal charge is equal to
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number of valence minus (num lone pairs + 1/2 num bonding Es)
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more than one lewis structure for fixed nuclear arrangement
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resonance
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1 and a half bonds
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aromatic bonds
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