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23 Cards in this Set

  • Front
  • Back
Thermodynamics
study ofheat and work
energy
capacity to do work
kinetic
energy associated with motion
potential energy
energy that results from an object's position
law of conservation of energy or the First law of thermodynamics
energy can neither be created or destroyed, the total energy of the universe is constant
system
the object, or collection of objects being studied
surroundings
everything outside the system that can exchange energy with the system
thermal equilibrium
when two objects reach the same temperature. the temperature through the system is the same
exothermic
heat is transferred from a system to the surroundings
endothermic
heat is transferred from surroundings to the system
q
heat transferred
sys
system
joule
SI unit of thermal energy
1 calorie =
4.184 joules
specific heat cappacity
quantity of heat required to raise the temp of 1 g of a substance by one kelvin
q =
mCAT Joules
increase +
heat transferred from surrounds to system (endothermic)
decrease -
heat transferred from system to surroundings (exothermic)
heat of fusion
heat required to convert a substance from a solid at its melting point to a liquid
heat of vaporization
heat required to convert a substance from a liquid to a gas
sublimation
property when it absorbs heat from its surroundings changes directly from solid to gas
internal energy E
in a chemical system: the sum of the potential and kinetic energies of the atoms, molecules, or ions in the system
enthalpy (H)
the heat content of a substance at a constant pressure