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53 Cards in this Set

  • Front
  • Back

Two types of chemical bonds

Ionic and covalent

Definition: Ionic bond

Bond between a metal and one or more nonmetals. Forms cations and anions. Complete transfer of electrons. Oppositely charged ions are attracted.

Definition: Cation

A positively charged ion

Definition: Anion

A negatively charged ion

Definition: Covalent bond

Bond between nonmetals. Sharing of electrons. Form molecules.

Definition: Molecular compounds

Covalently bonded compounds, usually between nonmetals.

Order of elements in a chemical formula for a compound

More metallic (positively charged) first, less metallic second.

Types of chemical formulas

Empirical, molecular, and structural

Definition: Empirical formula

Gives the relative number of atoms in a compound

Definition: Molecular formula

Gives the actual number of atoms in a compound

Definition: Structural formula

Uses lines to represent covalent bonds, and may show the compound's geometry

Types of pure substances

Elements and compounds

Types of elements

Atomic and molecular

Types of compounds

Molecular and ionic

Definition: Atomic elements

Exist with single atoms as their basic units.


Ex: Ne

Definition: Molecular elements

An element that normally exists as a molecule.
Ex: 02

List of diatomic elements

H, N, O, F, Cl, Br, I

List of polyatomic elements

P (4), S (8), Se

Definition: Formula unit

The smallest, electrically neutral collection of ions in an ionic compound. Same as the empirical formula

Definition: Polyatomic ion

An ion composed of two or more atoms.


Ex: Hypochlorite, ClO -

Rule: Writing formulas for ionic compounds

1. Write the cation first and anion second with superscripts for charge. (use P-table)


2. Adjust the subscripts to balance the charges.


Ex: Al 3+ and O 2- gives Al2O3

Two branches for naming ionic compounds

1. Metal forms ions with only one charge (no numeral)


2. Metal forms variably charged ions (use numeral)

Rule: Naming ionic compounds with metals that form only one charge of ion

Name of cation, base name of anion +ide.

Which metals have invariably charged ions?

Main group metals with the exception of Tin (Sn) and Lead (Pb). Charge determined by the group number.


Definition: Binary compound

Contains only two different elements.

Rule: Naming binary ionic compounds with metals that form variably charged ions

Name of cation (roman numeral for cation charge), base name of anion +ide.


Ex: CrBr3 chromium (III) bromide

Which metals form ions with variable charges?

The transition metals. Charge determined by what they are bonded to. Exceptions are zinc (Zn) 2+, silver (Ag) +, cadmium (Cd) 2+, and scandium (Sc) 3+

Rule: Naming ionic compounds containing polyatomic ions

Name the metal with roman numeral if needed, then name the polyatomic ion.


Ex: NaNO2 sodium nitrite, FeSO4 iron (II) sulfate

Prefixes and endings for oxyanions, from least to most O's

hypo___ite


___ite


___ate


per___ate

Definition: Hydrates

Ionic compounds that contain a specific number of water molecules associated with each formula unit.


Ex: MgSO4⋅7H2O

Definition: Anhydrates

A salt with no water trapped inside the crystal lattice.

Definition: Waters of hydration

The water molecules trapped within the crystal lattice of a salt.

To determine the number of waters of hydration in an ionic hydrate divide ______ by ______.

The moles H20


The moles of the metal

Rule: Naming hydrates

Name the ionic compound according to ionic compound rules then prefixhydrate.
Ex: BaCl2⋅6H2O barium chloride hexahydrate

List of prefixes

Hemi 1/2, Mono 1, Di 2, Tri 3, Tetra 4, Penta 5, Hexa 6, Hepta 7, Octa 8, Nona 9, Deca 10

Rule: Naming molecular compounds

Prefix, 1st element name + prefix, 2nd element name. (more metallic element is first) (if the prefix of the first is mono it can be dropped)


Ex: NO2 nitrogen dioxide

Definition: Acids

Molecular compounds that release hydrogen ions when dissolved in water. Formula starts with H

Two types of acids when naming

Binary (contains two elements) and oxyacids (contain oxygen)

Rule: Naming binary acids

Hydro, base name of nonmetal +ic, acid


Ex: HCl(aq) hydrochloric acid

Rule: Naming oxyacids

1. Oxyanion ends in -ate. Take base name of oxyanoion +ic acid


2. Oxyanion ends in -ite. Take base name of oxyanion +ous acid


Ex: HNO3(aq) nitric acid, H2SO3(aq) sulfurous acid

Definition: formula mass / molecular mass / molecular weight

The average mass of a molecule or formula unit of a compound.

Finding formula mass

# of 1st atom x atomic mass of 1st atom + # of 2nd atom x atomic mass of 2nd atom + ...

Definition: Molar mass of a compound

The mass in grams of one mole of a compound. Same number as the formula mass, but in g.
Ex: CO2 molar mass= 44.01 g/mol
Definition: Mass percent

The percent of an element's mass of the compound's total mass.

Finding mass percent

(mass of element in 1 mol of compound)/(mass of 1 mol of the compound) all x 100%


If the element has a subscript, multiply it in the numerator.

Conceptual plan for masses in compound

Mass A -> Moles A -> Moles B -> Mass B

Finding empirical formula using mass percent composition

1. Convert masses to moles


2. Write moles as subscripts


3. Divide all by the smallest number


4. Convert decimals to smallest whole number ratios

Finding molecular formula from empirical formula

1. Divide molar mass by empirical formula molar mass


2. Multiply the subscripts of the empirical formula by that number

Definition: Combustion reaction

A chemical reaction in which a substance combines with oxygen and gives off heat.

Two sides of a chemical equation

Reactants/reagents and products

Definition: Hydrocarbons

Organic compounds that contain only one C and H

Definition: Functional Group

A characteristic atom or group of atoms that are incorporated into a hydrocarbon, changing its properties

Definition: Family (in regards to organic compounds)

A group of organic compounds with the same functional group.