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124 Cards in this Set

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Law of conservation of mass

The total mass of material present after a chemical reaction is the same as the total mass present before the reaction.

Law of multiple proportions. Dalton

If 2 elements A & B combine to form more than one compound, the masses of B that combine with a given mass of A are in the ratio of small whole numbers.

Dalton's atomic theory, 4 postulates

1 - small particles called atoms form each element


2 - atoms from each element are identical, and different from atoms of a different elements


3 - atoms of an element cannot be changed into atoms of a different element and atoms cannot be created or destroyed in chemical reactions.


4 - elements can combine atoms to form compounds. A given compound always have the same relative number and type of elements.

What did the Cathode Ray experiment help discover? When was the paper published?

Electrons and their charge to mass ratios. 1897.

What is electric charge of an electron? To its mass?

-1.602x10^-19, 1.76 x 10^8 coulombs per gram

How was the electric charge of an electron measured?

Using Cathode rays and calculating the strength of magnets and electric forces needed to deflect the electrons.

Approximate diameter of the nucleus

100-500 picometers. Or 1-5 angstroms.

The elements that normally occur as diatomic molecules.

H2,O2,N2,F2,Cl2,Br2, &I2.

Molecules are composed of:

Two types or more types of atoms from different elements, generally composed of non-metals only.

Methane formula

CH4

Methane formula

CH4

Ionic compounds are generally formed from which types of elements? What about molecular compounds?

Combinations of metals and nonmetals.



Molecular compounds are composed of Nonmetals only. Like H2O.

How to figure empirical formula for ionic compounds.

Take the charges number and make it the subscript for the other element.

How to name ionic compounds?

Cations formed from metal atoms have the same name as the metal. If the metal can have two charges then the positive charge is indicated by a Roman numberal in parentheses following the name of the metal.


Anions: the names of monatomic anions are formed by replacing the ending of the name of the element with -ide. EX: H^-Hydride ion. O^2- oxide ion. N^3- nitride ion.

Cations, anions, metals with two charges, and monatomic examples.

Which elements can have more than one charge?

Most metals that can form two different charges are transitional metals from the middle of the periodic table (group 3B to 2B).

Which metals can only form one charge?

Group 1A and 2A, as well as Al^3+ and two transitional metals: Ag^+ and Zn^2+. Charges are not expressed when writing these ions. When in doubt, write the charges in Roman numberal since it is never considered wrong to do so.

The older method of distinguishing different transitional ionic charges.

The lesser charge: add -ous to element name. EX: ferrous ion (Fe^2+). The higher charge: -ic. EX: cupric ion (Cu^2+)

Cations formed from nonmetal atoms have names that end in?

-ium. Ex: NH4^+ = ammonium ion. H3O^+ = hydronium ion.

Cations with 1+ charges

H^+, Li^+, Na^+, K^+, Cs^+, & Ag^+.

Ions with 2+ charges.

Mg^2+, Ca^2+, Sr^2+, Ba^2+, Zn^2+, Cd^2+


Co^2+ cobalt (II) ion


Cu^2+ copper (II) ion


Fe^2+ iron (II) ion


Mn^2+ manganese (II) ion


Hg2^2+ mercury (II) ion


Ni^2+ nickle (II) ion


Pb^2+ lead (II) ion


Sn^2+ tin (II) ion

Ions with 3+ charges.

Al^3+ aluminum ion


Cr^3+ chromium (III) ion


Fe^3+ iron (III) ion

Ammonium ion

NH4^+

NH4^+

Ammonium ion

Cu^+

Cooper (I) or cuprous ion

Cr^3+

Chromium (III) or chromic ion

Mass of 1 amu

1.66054x10^-22 g

Mass of a proton, neutron, and electron, respectively in amu.

1.0073amu, 1.0087amu, 5.486x10^-4amu

How many amu are in one gram?

6.02214x10^23 amu

Group 1A name and elements

Alkaline metals: Li, Na, K, Rb, Cs, Fr

2A group name and elements

Alkaline earth metals: Be,Mg,Ca,Sr,Ba,Ra

6A group name or elements

Chalcogens: O,S,Se,Te,Po

7A group name and elements

Halogens: F,Cl,Br,I,At

8A group name and elements

Nobel gases: He, Ne, Ar, Kr, Xe, Rn

OH^-

Hydroxide ion

CN^-

Cyanide ion

O2^2-

Peroxide ion

Oxyanions, difference between the -ate and -ite endings

Polyatomic anions containing oxygen have names ending in either -ate or -ite.


-ate: used for the most common or representative oxyanion of an element, and -ite is used for an oxyanion

Mercury (I) ion

Hg2^2+

Hg2^2+

Mercury (I) ion

NO3^-

Nitrate ion

Nitrate ion

NO3^-

NO2^-

Nitrite ion

Nitrite ion

NO2^-

SO4^2-

Sulfate ion

Sulfate ion

SO4^2-

Sulfite ion

SO3^2-

SO3^2-

Sulfite ion

ClO4^-

Perchlorate ion (1 more O atom than chlorate)

Perchlorate

ClO4^-

ClO3^-

Chlorate ion

Chlorite ion

ClO2^-

ClO2^-

Chlorite ion (1 O atom fewer than chlorate)

Hypochlorite ion

ClO^-

ClO^-

Hypochlorite ion (1 fewer O atom than chlorite)

Maximum number of O atoms on polyatomic ions in period 2

3

Carbonate ion

CO3^2-

CO3^2-

Carbonate ion

Phosphate ion

PO4^3-

PO4^3-

Phosphate ion

Perchlorate ion

ClO4^-

Oxyions charge and number of oxygen relation on period table.

CO3^2-

Carbonate ion

CO3^2-

Carbonate ion

HCO3^-

Hydrogen carbonate ion (or bicarbonate ion)

Hydrogen carbonate ion

HCO3^-

Phosphate ion

PO4^3-

PO4^3-

Phosphate ion

H2PO4^-

Dihydrogen phosphate ion

H2PO4^-

Dihydrogen phosphate ion

Acetate ion

CH3COO^- or C2H3O2

CH3COO^-

acetate ion

Permanganate ion

MnO4^-

MnO4^-

Permanganate ion

CrO4^2-

Chromate ion

Chromate ion

CrO4^2-

Dichromate ion

Cr2O7^2-

Nitride ion

N^3-

Nitride ion

N^3-

Define an acid for chemical purposes

Is a substance whose molecules yield hydrogen ions when dissolved in water.

Naming acids whose anions end in -ide

Add hydro- to beginning and -ic acid to the end.


Chloride (Cl^-) becomes hydrochloric acid(HCl)


Sulfide (S^-) becomes hydrosulfuric acid (H2S)


Naming acids whose anions end in -ate

Change -ate to -ic then add the word acid.


Perchlorate (ClO4^-) becomes perchloric acid (HClO4)


Chlorate (ClO3^-) becomes chloric acid (HClO3)

Naming acids whose anions name end in -ite

Change -ite to -ous and add the word acid.


Chlorite(ClO2^-) to chlorous acid(HClO2)


Hypochlorite (ClO^-) to hypochlorous acid (HClO)

Prefixes for naming binary compounds formed between two nonmetals.

Mono- 1


Di- 2


Tri- 3


Tetra- 4


Penta- 5


Hexa- 6


Hepta- 7


Octa- 8


Nona- 9


Deca- 10

Procedure for naming binary molecular compounds.

1. The name of the element farther to the left in the periodic table is usually written first. Except when the compound contains oxygen and chlorine, bromine, or iodine then oxygen is written last.


2. If both elements are in the same group, the one closer to the bottom of the table is written first.


3. The name of the second element is given an -ide ending.


4. Greek prefixes indicate the number of atoms of each element. When the prefix ends in a or o and the name of the second element begins with a vowel, the a or o of the prefix is dropped.

Hydrocarbons

Compounds that only contain carbon and hydrogen.

Alkanes

Simplest hydrocarbons. Each carbon is bonded to four other atoms. The smallest alkane is methane then ethane, and propane.

Methane

CH4

Ethane

C2H6

C3H8

Propane

An alcohol

An alkane with a -OH group instead of a H

Be (chemical name)

Beryllium

Beryllium chemical symbol

Be

Rb element name and group

Rubidium, alkaline metal

Rubidium chemical symbol

Rb^1+

Cs element name and group

Caesium, alkaline metal

Br element name and group

Bromine, halogen

Rn element name and group

Radon (noble gas)

At element name and group

Astatine, halogen

Se element name and group

Selenium, nonmetal

Se element name and group

Selenium, nonmetal

B element name and group

Boron, metalloid

Te element name and designation

Tellurium, metalloid

Sb element name and designation

Antimony, metalloid

Ge element name and designation

Germanium, metalloid

Ge element name and designation

Germanium, metalloid

Sr element name and designation

Strontium, alkaline earth metal

Sr element name and designation

Strontium, alkaline earth metal

Ba element name and designation

Barium, alkaline earth metal

Ra element name and designation

Radium, alkaline earth metal

How many decimal points do you round the answer when finding the atomic mass of an element based on the abundance and weight of the isotopes?

2 decimal points because last function is addition.

How many decimal points do you round the answer when finding the atomic mass of an element based on the abundance and weight of the isotopes?

2 decimal points because last function is addition.

What do you call the rows and columns in the periodic table?

Rows are periods, columns are groups.

Which elements are the metalloids?

Ge, Sb, Po.

Which elements are the metalloids?

Ge, Sb, Po.

What kind of bond holds molecules?

Covalent bond (shared electron)/ molecular bond between non-metals and or metalloids.

What is an ionic bond?

Attraction between two atoms of opposite charge, like Na+ and Cl-.

Hypophosphite ion

PO2^3-

Phosphite ion

PO3^2-

PO3^2-

Phosphite ion

PO2^3-

Hypophosphite ion

IO3^-

Iodate

Iodate

IO3^-

Iodite ion

IO2^-

What did the metal foil scattering alpha particles lead to the discovery of? And replaced what?

The nuclear model. The currant pudding model.