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39 Cards in this Set

  • Front
  • Back

Ionic Crystals

Ionic Bonding


Properties: Hard, brittle, high MP, poor conductor of electricity and heat

Covalent Crystals

Covalent Bonding


Properties: hard, high MP, poor conductor of heat and electricity

Molecular Crystals

IMF bonding


Properties: soft, low mp, poor conductor of heat and electricity

Metallic Crystals

Metallic bonding


Properties: soft, low to high mp, excellent conductor of heat and electricity

Intermolecular Forces

attractive forces between different molecules

Intramolecular Forces

attractive forces between different atoms in a molecule

Van Der Waals forces

Intermolecular forces


London Dispersion, Dipole-Dipole, Hydrogen Bonding

Dipole-Dipole forces

When there is polarity and a dipole-dipole movement.

Ion-Dipole Forces

attract an ion and a polar molecule to each other

induced dipole

separation of positive and negative changes in the atom is due to the proximity of an ion or a polar molecule

dispersion forces

attractive forces that arise as a result of temporary dipoles

hydrogen bond

special bond between H and N,O, or F. Type of IMF

Surface tension

amount of energy to stretch or increase surface area of a liquid by a unit area

cohension

intermolecular attraction between like-molecules that brings about capillary action

adhesion

attraction between unlike molecules, like water and sides of a glass tube

Viscosity

measure of resistance for fluid to flow. Goes down with increasing temperature

unit cell

basic repeating structural unit of a crystalline solid

crystalline solid

possess rigid and long range order in its atoms, molecules, or ions

coordination number

defined as the number of atoms surrounding an atom in a crystal lattice

Closest packing

most efficient arrangement of spheres

X ray diffraction

scattering of x rays by the units of a crystalline solid




X rays are used because their wavelength is distance between lattice points

amorphous solids

solids that lack regular 3D arrangement of atoms, like glass

glass

optically transparent fusion product of inorganic materials that has cooled to a rigid state without crystallizing

phase changes

transformations from one phase to another, solid to liquid

sublimation

solid directly to gas

deposition

gas directly to solid

Vaporization

liquid to gas

equilibrium vapor pressure

vapor pressure measured when a dynamic equilibrium exists between condensation and evaporation

dynamic equilibrium

rate of forward process is balanced by the rate of the reverse process

Condensation

change from gas to liquid

molar heat of vaporization

amount of heat required to vaporize one mole of liquid

boiling point

temperature at which vapor pressure of liquid is equal to the external pressure

critical temp

point where above it gas cannot liquefy. highest point where substance can exist as liquid

critical pressure

minimum pressure that must be applied to create liquefaction at critical temperature

melting point and freezing point

temperature where solid and liquid coexist

molar heat of fusion

amount of heat required to melt one mole of a solid

supercooling

liquid can be temporality be cooled to below freezing point

molar heat of sublimation

amount of heat required to sublimate one mole of a solid

triple point

only point where a substance can exist in all 3 phases