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51 Cards in this Set

  • Front
  • Back

Solution

A homogeneous mixture of two or more substances with each substance retaining its own chemical identity.




solids, liquids, gas

Solute

Component of a solution that is present in a lesser amount relative to that of the solvent




substance being dissolved

Solvent

Component of a solution that is present in the greatest amount


ex. liquid water

General properties of a solution

Contains two or more components




has variable composition




properties change as the ratio of solute to solvent is changed




dissolved solutes are present as individual particles




solutes remain uniformly distributed and will not settle out with time




solute can be separated from solvent by physical means such as evaporation

Solubility

the max number/amount of solute that will dissolve in a given amount of solvent under a given set of conditions

effect of TEMPERATURE on solubility

most solids become more soluble in water with INCREASING Temperature




Gas solubilities in water decrease with increasing temperature

effect of PRESSURE on solubility

Solids and Liquids- no effect


Gas- major impact/effect




pressure has little to no effect on solubility of solids and liquids in water




pressure has major impact on solubility of gases in water

Henrys Law

the amount of gas that will dissolve in a liquid at a given temperature is directly proportional to the partial pressure of the gas above the liquid




as the pressure of a gas above the liquid increases, the solubility of the gas increases

Saturated Solution



a solution that contains the MAXIMUM amount of solute that can be dissolved under the conditions at which the solution exists

Super Saturated solution

an UNSTABLE solution that temporarily contains more dissolved solute than that present in a saturated solution




will produce crystals rapidly, often in a dynamic manner. if it is slightly disturbed or "seeded" with a tiny crystal of a solute

Unsaturated solution

contains LESS THAN the max amount of solute that can be dissolved under the conditions at which the solution exists


most solutions we encounter fall under this

Concentrated Solution

contains a LARGE amount of solute relative to the amount that could dissolve

Dilute Solution

Contains a SMALL amount of solute relative to the amount that could dissolve

Aqueous Solution

water is the solvent

Non-Aqueous Solution

A substance other than water is the solvent

What has to happen in order for a Solute to Dissolve in a Solvent?

Two types of inter particle attractions must be overcome


solute-solute attractions


solvent-solvent attractions

what are the two types o inter particle attractions?

Solute-solute attractions


solvent-solvent attractions




attractions between solute particles


attractions between solvent particles

A new type of interaction forms. what is it?

Attraction between solute and solvent particles


(solute-solvent attractions)




dissolving is a dynamic process







how does temperature effect the dissolving rate?

as temperature increases, the dissolving rate increases


higher temperature=faster dissolving rate

the _____ solute you have, the ____ solvent you have

more


less

the ____ the particles, the ____ the attraction

smaller


smaller

the greater the surface area, the ____ it dissolves

faster

Solubility Rules

the greater the difference in the solute-solvent polarity, the less soluble is the solute




substances of like polarity tend to be more soluble in each other than substances that differ in polarity

Soluble Ionic Compounds (always soluble)

Sodium (Na+)


Potassium (K+)


Ammonium (NH4+)


Nitrate (NO3-)


Acetate (CH3COO-)


(Ba(OH)2)

Mostly Soluble With Exceptions

Chloride (Cl-)


Sulfate (SO4^2-)


Bromide (Br-)


Iodide (I-)




Exceptions- Lead, Silver, Mercury


I


Pb2+


Ag+


Hg2^2+

Not Soluble with exceptions

Carbonate (CO3^2-)


Sulfide (S2-)


Phosphate (PO4^3-)


Hydroxide (OH-)



Exceptions- Li+, Na+, K+, NH4+

Concentration (two methods)

the amount of solute present in a specified amount of solution


1. Percent concentration


2. Molarity

Percent Concentration (3 kinds)

1. % by mass


2. % by volume


3. mass-volume %



percent by mass=

mass of solute/mass of solution X 100




mass of solution= mass of solute + mass of solvent

Percent by Volume=

volume of solute/volume of solution X 100


mass- volume %=

mass of solute (g) / volume of solution (mL) X 100


Molarity (M) =

the number of moles of solute in 1 liter of solution




moles of solute/liters of solution




convert ml to L unless told otherwise

Dilution

the process in which more solvent is added to a solution in order to lower its concentration




Dilution with water does not alter the numbers of moles of solute present




Moles of solute before dilution=moles of solute after dilution

Dilution Formula

Cs X Vs = Cd X Vd




s=stock solution


d=diluted solution


c= concentration-% of mass/molarity


v=amount of solution-volume/mass

Moles of solute before dilution _____ moles of solute after dilution

equal

Colloidal Dispersion

a HOMOGENEOUS mixture that contains dispersed particles that are intermediate in size between those of a true solution and those of an ordinary heterogenous mixture

dispersed Phase like the (solute or solvent)?

solute

dispersing medium like the ( solute or solvent)?

solvent

what is the normal particle size of a Colloidal dispersion?

10^-7 - 10^-5 cm

Tyndall Effect

the light scattering phenomenon that causes the path of a beam of visible light through a colloidal dispersion to be observable




when we shine a beam of light through a true solution, we cannot see the track of the light




A beam of light passing through a colloidal dispersion can be observed bc the light is catered by the dispersed phase

Suspension

a HETEROGENEOUS mixture that contains dispersed part ices that are heavy enough that they settle our under the influence of gravity




when the size of the dispersed particles is greater than 10^-5 cm

Colligative property

a physical property of a solution that depends only on the number (concentration) of solute particles present in a given quantity of solvent and not their chemical reaction

what are the 4 kinds of Colligative properties?

vapor-pressure lowering




boiling pt elevation




freezing pt depression




osmotic pressure

Osmolarity (osmol)

osmolarity=molarity X i




i = the number of particles produced from the dissociation of the formula units of solute

osmosis

the passage of a solvent through a semi-permeable membrane separating a dilute solution (or pure solvent) from a more concentrated solution

Semi-Permeable membrane

a membrane that ALLOWS ONLY CERTAIN TYPES of molecules to pass through it, but prohibits the passage of other types of molecules




ONLY ALLOWS PASSAGE OF SOLVENT





Osmotic Pressure

pressure required to prevent osmosis from happening

Chemical Reaction

process in which at least one new substance is produced as a result of chemical change

Combination

two or more reactants


1 product




x+y ----> xy




2H2 + O2 ---> 2H20

Decomposition

1 reactant


two or more products




xy---> x+y

Single-Replacement

an atom or a group of atoms is replaced by another atom or group of atoms




X+YZ---> Y +XZ