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12 Cards in this Set

  • Front
  • Back

multiple bond

Ifthere are not enough electrons for the central atom to attain an octet, a multiple bondis present

resonance hybrid

canbe depicted by more than one valid Lewis structure; havethe same relative placement of atomsbut different locations of bonding and lone electron pairs; the weighted average of the resonance structures is the correct one

fractional bond order

bond order by resonance hybrids


# electron pairs / # bonded-atom pairs

formal charge

the charge an atom would have if all its electrons were shared equally




= # valence electrons - (# of unshared valence electrons + 1/2 shared valence electrons)


must sum to the actual charge on the species for all resonance forms

free radical

molecule with an odd number of electrons

expanded valence shell

only possible for nonmetals period 3 or higher because these elements have available d orbitals

group of electrons

any number of electrons that occupies a localized region around the atom

molecular shape

three dimensional arrangement of nuclei joined by the bonding groups. classified using the designation


AXsubmEsubn where m and n are integers, X= surrounding atom, E= nonbonding valence-electron group, A= central atom

bond angle

the angle formed by the nuclei of two surrounding atoms with the nucleus of the central atom

molecular polarity

depends on both shape and bond polarity

dipole moment (u)

given the unit debye (d), it measures the polarity of a molecule

a molecule is polar if

it contains one or more polar bonds and the individual bond dipoles do not cancel