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12 Cards in this Set
- Front
- Back
multiple bond |
Ifthere are not enough electrons for the central atom to attain an octet, a multiple bondis present |
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resonance hybrid |
canbe depicted by more than one valid Lewis structure; havethe same relative placement of atomsbut different locations of bonding and lone electron pairs; the weighted average of the resonance structures is the correct one |
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fractional bond order |
bond order by resonance hybrids # electron pairs / # bonded-atom pairs |
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formal charge |
the charge an atom would have if all its electrons were shared equally = # valence electrons - (# of unshared valence electrons + 1/2 shared valence electrons) must sum to the actual charge on the species for all resonance forms |
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free radical |
molecule with an odd number of electrons |
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expanded valence shell |
only possible for nonmetals period 3 or higher because these elements have available d orbitals |
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group of electrons |
any number of electrons that occupies a localized region around the atom |
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molecular shape |
three dimensional arrangement of nuclei joined by the bonding groups. classified using the designation AXsubmEsubn where m and n are integers, X= surrounding atom, E= nonbonding valence-electron group, A= central atom |
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bond angle |
the angle formed by the nuclei of two surrounding atoms with the nucleus of the central atom |
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molecular polarity |
depends on both shape and bond polarity |
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dipole moment (u) |
given the unit debye (d), it measures the polarity of a molecule |
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a molecule is polar if |
it contains one or more polar bonds and the individual bond dipoles do not cancel |