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6 Cards in this Set

  • Front
  • Back
The purpose of GC
To test the purity of a substance and separate the components of a mixture. The relative amounts of the components in a mixture may be determined.
How does it work?
It separates a moving gas phase and stationary liquid phase. GC separates the components of a mixture based on their vapor pressures (or boiling points)
How does gas chromatograph work?
1. Sample is injected
2. It immediately vaporized in a heated injection chamber and introduced into the carrier gas
3. Vaporized sample is then swept into a column filled with particles coated with a liquid absorbent (contained in a temperature-controlled oven.
4. Sample passes through the column they undergo gas-liquid partitioning processes and the components are separated
How does column work?
It is packed with a liquid or low-melting solid as the stationary phase. The stationary phase has a high boiling point.
Separation process
As mixture reaches the column, which is heated in a controlled oven, it begins to equilibrate between liquid and gas phases. It is affected by vapor pressure and volatility (boiling point)
***Vapor pressure and boiling points are INVERSELY Proportional***
Factors determine the rate of a given compound travel
1. Boiling point
2. Rate of flow of the carrier gas
3. Choice of liquid phase used in the column
4. Length of the column