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40 Cards in this Set

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  • Back
What are the three states of mater?
solid liquid gas

Solid


Particles are _____ and tightly packed together.


particles.


particles are ____ to each other


solids maintain their ___


they have a ____


they are___



well ordered


very attracted


shape and volume


high density


non compressible

Liquids


particles are still close together, but can ___


particles are ___ to each other


liquids take the ___, but ___


they have a slightly ___


they are ___



flow past one another


less attracted


shape of their container, maintain their volume


lower density


slightly compressible

Gas


particles are __, in a very chaotic arrangement


particles are ___ to each other


gases take ___


they have a ___.


they are ___.

far apart


barley attracted


shape and volume of their container


very low density


very compressible

kinetic molecular


Gas particles are ___.


they move in ___.


they are very____.


they collide with ___.


they ___ as the temp ___.

constantly in motion


straight lines


very far apart


elastic collisions (no energy lost)


speed up, increases ( kinetic energy increases.)





Gas laws


Boyles law


Pressure (P) and Volume(V) vary indirectly

volume increases pressure decreases


volume decreases pressure increases

Boyles law


Inspiration


Diaphragm lowers, chest wall expands, __


If volume gets __, pressure gets __


outside pressure is ___ than inside pressure


air rushes __ lungs to equalize pressure.

increasing volume of lungs


larger, small


greater


into

Boyles law continued


expiration (exhaling)


Diaphragm raises, chest wall collapses, ___.


If volume gets __, pressure gets larger __


inside pressure is ___ than outside pressure.


air rushes___ lungs to equalize pressure.



increasing volume of lungs


small, larger


greater


out of

Charles Law


Volume (V) and temp (T) vary directly



temp increases volume increases


temp decreases volume decreases

changes in state



endothermic heat goes into the object >


Melting evaporation or vaporization


solid >>>> liquid >>>>> gas


<<< <<<


freezing condensation


< exothermic heat comes out of the object

Boiling point


transition temp between ___ and ___.


Particles overcome ___ to escape as gas



liquid, gas states


water (I) > water (g)


<


I-----l---------l---------l---------l


20c 99c 100c 101c 120c


transition temp both states are present

Melting point


transition temp. between ___ and ___


particles must overcome attraction to each other and break up _____.

solid, liquid


the solids rigid structure


water (S) > water (I)


<


l-------l--------l-----l---------l


-20c -1c 0c 10c 15c

Decomposition



occurs when atomic bonds break before state change occurs


charring and burning occurs

Special properties of water


Solid water is ___ than liquid water


solid water has a ___ than liquid water


water has a larger capacity for ___


water has a high ___

less dense


larger volume


absorbing heat


surface tension


(resistance of a liquids surface to disruption)

The mole


avogadros number


a mole (mol) is a ___ of a substance.


avogadros number of items together make up 1 mole


avogadros number is ___ when written with 4 significant figures.

counted quantity


6.022x10^23

For elements


1 mole C= ?


For compounds


1 mole = ?


allows conversion


mole of an element <---> atoms of element


moles of a compound <---> molecules of compound

6.022x10^23 atoms of C


6.022x10^23 molecules

2.3x10^24 atoms of He makes up how many moles?



initial value (old unit): 2.3x 10^24 atoms


desired new unit: moles


Conversion factor: 1 mole He= 6.022x10^23 atoms He


2.3x10^24atomes He X 1 mole He/6.022x10^23 atoms He


= 3.8 mol He



How many molecules are in 3.00 moles of PH3?

initial value(old): 3.00 moles of PH3


desired new unit: molecules


conversion factor: 1 mole PH3= 6.022X10^23 molecules PH3


3.00 mole PH3 X 6.022X10^23/1 mol PH3=


1.81 X 10^24

Molar mass of an element


the molar mass of an element is the ___.


what are the molar masses of H, C, and S?



number of grams in 1 mol of any element


1 mole H= 6.022X10^23 molecules weights 1.01g


1 mole H= 1.01 g H (atomic/molar mass)


1 mole C= 12.01 g C


1 mole S= 32.06 g S

molar mass of a compound


for a compound simply ___ the molar masses of ___ in the compound multiplied by ___.


NH3?

add, each element, its subscript


N= 14.01 can also just multiply H 3xs


H= 1.01


H= 1.01


h= 1.01


------------


17.04 g NH3= 1 mole NH3

Calculations using molar mass


what is the mass in grams of 4.00 moles of Pb?

given value(old unit):


desired new unit: mass (grams)


conversion factor: 207.2 g Pb= 1 mol Pb


4.00 mol Pb X 207.2 g/ 1 mol Pb= 829 g Pb

how many moles are in 32.00 grams of H20?


given value (old): 32.00 g H2O

desired new unit: moles


conversion factor: 18.02 h H2O= 1 mol H2O


add H mass and O mass togehter


32.00 g H2O * 1 mole H2O/ 32.00 g H2O= 1.776 mol H2O

what is the mass of 10.33 moles of NiC2?



given value(old): 10.33 moles NiCl2desired new unit: mass(g)conversion factor: 1 mol NiCl2=129059 g NiCl2

10.33 mol NiCl2 * 129.59 g NiCl2/ 1 mol NiCl2= 1339 g NiCl2

Chemical reactions


yield


Reactants ---> products


H2(g) + O2(g) ---> H2O(l)


law of conservation of matter: all equations must be balanced with coefficients which have the ______ possible.


nothing will just disappear, balance equation multiply coefficients


then add to see if they are equal.

smallest whole number ratio

Balance


__ H2(g) + __ O2(g) ----> __ H2O(l)

2 H2


2H2O

Balance


__ P4O10(s) + __ H2O(l) --> H4P2O7(aq)

4 h2o


2 H4P2O7

__ Al + __ H2SO4 --> __ Al2(SO4)3 + __ H2

2 Al


3


3 H2

Moles and equations


The coefficients of a balanced equation tells you the ___ ratio for each compound in the equation.


2 H2(g) + O2(g) --> 2 H20


they serve as a ___.


this allows us to convert ___ in a balanced equation into __ in that same equation.

mole-to-mole


2 mol 1 mol 2 mol


free-form conversion factor


moles of one substance


moles of any other substance.



2 H2(g) + O2(g) --> 2 H20(l)

2 mol 1 mol 2 mol


how many moles of H2O are formed when 2.00 moles of O2 react?



2.00 mol O2 * 2 mol H2O/ 1 mol O2 = 4.00 mol H2O

N2(g) + 3H2(g) --> 2 NH3(g)


1 mol 3 mol 2 mol


how many moles of H2 reacted to form 0.22 mol NH3?



0.22 mol NH3 * 3 mol H2/ 2 mol NH3= 0.33 mol H2

For any reaction involving 2 species (A and B) we can convert:


moles of a <--> moles of B


l l


v v


grams of A grams of B

no back

B A


N2(g) + 3H2(g) --> 2 NH3(g)


mole of A ---------------- moles of H2


l l


grams NH3 7.04 g NH3 grams of H2 (2.02gH2)=1

2.4 g NH3 * 1 mol NH3/ 17.04 g NH3 * 3 mol H2/ 2 mol NH3 * 2.02 g H2/ 1 mol H2 = 0.43 g H2

heat and reactions


endothermic reactions


energy (heat) must be ___ by the reactants.


the energy will appear on the ___ of the chemical equation


CO2 + H2O + heat --> C6H12O6(s) + O2


endothermic reactions feel ___ to the touch

absorbed


reactant side


cold

ecothermic reactions


energy (heat) must be ____ when products form.


the energy will appear on the ____ of the chemical equation.


CH4 + 2O2 --> CO2 + 2H2O + heat4


exothermic reactions feel ___ to the touch

released


product side


warm

Rates of reactions


Conditions required for a reaction to occur


reactant molecules must __.


the molecules must have the correct orientation to each other.


they must have appropriate __ during the collision (activation energy)

collide


energy

Factors which affect the rate (speed) of a reaction.


concentrations of reactants: a large # of molecules in a small area will collide more often


temperature of reactants: a high temp makes molecule move faster, causing them to collide more often.


adding a catalyst: the catalyst lowers the activation energy of a reaction allowing it to proceed faster.

no back

reversible reaction and equilibrium


reversible reaction


aA + bB ----. cC dD


reactants <--- products


at equilibrium the rate of the forward reaction is equal to the rate of the ___.


reactants are forming products __ as products are forming reactants.


there is ___ in the amount of reactants or products present.

reverse reaction


exactly as fast


no net change



Lechateliers principle states that the position of an equilibrium ___ in response to stress applied to that system.


equilibrium shifts away from whats being added.


equilibrium shifts toward whats being removed



shifts

lechatieliers principle example


H2 + I2 <---> 2 HI


if I2 Removed: eq. will shift towards I2 (reactants)


if H2 is added: eq will shift away from H2 (products)


if HI is added: eq will shift away from HI (reactants)

what the f is this shi

N2 + 3H2<---> 2NH3 + heat(exo)


if heat is added: eq will shift away from heat (reactants)


if heat is removed: eq will shift towards heat (products)

no back