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84 Cards in this Set

  • Front
  • Back
Chemistry
the science that seeks to understand the behavior of matter by studying the behavior of atoms and molecules
1. Matter

2. 3 states of matter
1. anything that hass mass and occupies space.

2. solid, liquid, gas
Solids
fixed shape, fixed volume, non compress, non flow
Liquids
indef shape, fixed volume, non compress, yes flow
Gases
indef shape, indef volume, yes compress, yes flow
Classifications of Matter

1. Pure Substance

2. Mixture
1. made of one type of particle, all samples show same intensive properties.

2. made of multiple types of particles, may show different intensive properties.
Classification of Pure Substances

1. Element

2. Compound
1. substance that cannot be broken down into simpler substances.

2. substance that can be decomposed, chemical combination of elements, all samples of compounds behave the same way.
Classifications of Mixtures

1. Heterogeneous

2. Homogeneous
1. Made of multiple substances whose presence can be seen, portions of samples have different composition and properties.

2. made of multiple substances but appear as one, all portions of a sample have same composition and properties.
Changes in Matter

1. Physical Change

2. Chemical change
1. alter the state or appearance of matter without altering the composition

2. alter the chemical composition of the matter
Properties of matter

1. Physical Properties

2. Chemical properties
1. can be changed without changing the composition

2. are the characteristics that determine how the composition of matter changes as a result of contact with other matter or the influence of energy
Examples

1. Physical changes

2. Chemical changes
1. boiling, condensing, melting, freezing, subliming, dissolving

2. rusting, burning, processes that release lots of energy
1. Energy

2. Work

3. Force
1. The capacity to do work.

2. action of a force applied across a distance

3. a push or a pull on an object, electrostatic force is the push or pull on objects that have an electric charge
Energy of Matter

1. Kinetic energy

2. Potential energy
1. energy of motion. Motion of the atoms, molecules and subatomic particles. Thermal energy is a form of kinetic energy.

2. Energy stored in matter due to the composition of matter and its position of the universe. Chemical potential energy arises from the electrostatic forces between atoms, molecules and subatomic particles.
When reading a measurement
use the bottom of the miniscus and don't forget to estimate the last digit
Density =
mass/volume
0 degrees C =
1. fahrenheit
2. kelvin
1. 32

2. 273
100 degrees C =
1. fahrenheit
2. kelvin
1. 212

2. 373
Fahrenheit to Celsius conversion
C = (F-32)
-----------
1.8
Celsius to Kelvin conversion
K = C+273.15
Significant Figures
1. all non-zero figures are sig.
2. interior zeroes are sig.
3. leading zeroes are not sig.
4. trailing zeroes are only sig. if they are after a decimal point.
5. exact numbers and conversion factors have an infinite number of sig figs.
Significant Figures
1. multiplication/division
2. addition/subtraction
1. use the same as the measurement with the least number of sig figs
2. use the same number of decimal places as the measurement with the fewest number of decimal places
1. Precision

2. Accuracy
1. an indication of how reproducible a measurement is

2. an indication of how close a measurement comes to the actual value of the quantity
Dalton's Atomic Theory
1. each element is composed of tiny, indestructable particles called atoms
2. all atoms of a given element have the same mass and other properties that distinguish them from atoms of other elements
3. atoms combine in simple whole-number ratios to form molecules of compounds
4. in a chemical reaction, atoms of one element cannot change into atoms of another element
Structure of the atom
1. the atom contains a tiny dense center called the nucleus
2. nucleus has essentially the entire mass of the atom
3. nucleus is positively charged
4. electrons are dispersed in the empty space of the atom surrounding the nucleus
Isotopes
the same element can have atoms with different masses called isotopes, weights depend on the number of neutrons, identified by their mass numbers: protons + neutrons
1. atomic number

2. mass number
1. number of protons

2. protons + neutrons
Number of
1. protons
2. neutrons

52
Cr
24
1. 24

2. 28
1. cation

2. anion
1. when atoms lose electrons they become positively charged ions

2. when atoms gain electrons they become negatively charged ions
anions are named by:

F-
changing the end of the name to -ide

Flouride
cations are named by:

Na+
same as the metal they are composed of

sodium ion
Periodic table is broken up into:
metals, non-metals, metalloids, main group, transition metals.
Avogadro"s number
6.0221421 x 10^23
Ionic charge and the periodic table:
1. metals
2. non-metals
1. always positively charged, main group metals charge = group number
2. always negatively charged, charge = group number -8
molar mass
mass of one mole of atoms or molecules of a particular element or compound
Chemical Bonds
1. ionic bonds
2. covalent bonds
1. electrons have been transferred between atoms
2. atoms share some of their electrons
Chemical Formula
1. Empirical Formula
2. Molecular Formula
1. describe the kinds of elements found in the compound and the ratio of their atoms
2. describe the kinds of elements found in the compound and the number of their atoms
Atomic elements
elements whose particles are single atoms
molecular elements
elements whose particles are multi-atom molecules
molecular compounds
compounds whose particles are molecules made of only non-metals
ionic compounds
metals + non-metals, compounds whose particles are cations and anions
writing formulas for ionic compounds
1. write the symbol for the metal cation and its charge
2. write symbol for non-metal anion and its charge
3. charge becomes subscript for other ion
4. reduce subscripts to smallest whole number ratio
5. check that the sum of the charges of the cation cancels the sum of the anions
Ionic Bonds: Metal and Non-metal

Type I: Metal forms 1 type of Ion only
Name of cation +-ide

Ex: CaI2, calcium iodide
Ionic Bonds: Metal and Non-metal

Type II: Metal forms more than 1 type of ion
Name of cation, charge of cation in roman numerals, + -ide

Ex: FeCl3, iron (III) chloride
Covalent Bonds: Molecular bonds between non-metals only
prefix+name of first element, then prefix+name of second element+-ide

Ex: P2O5, diphosphorus pentoxide
Acids: H and one or more non-metals

Binary: Two-element
Hydro+base name non-metal + -ic acid

Ex: HCl, hydrochloric acid
Acids: H and one or more non-metals

Oxyacids: Contain oxygen and ends in -ate
Base name of oxyanion + -ic

Ex: H3PO4, phosphoric acid
Acids: H and one or more non-metals

Oxyacids: Contain oxygen and ends in -ite
Base name of oxyanion + -ous

Ex: H2SO3, sulfurous acid
HClO4
Perchloric Acid
HI
Hydroiodic Acid
Ca SO4
Calcium Sulfate
KH2PO4
Potassium Dihydrogen Phosphate
Sr(OH)2
Strontium Hydroxide
FeCl3
Iron (III) Chloride
Cu2SO4
Copper (I) Sulfate
Co(NO3)2
Cobalt (II) Nitrate
MnO
Magnese (II) Oxide
HCl
Hydrochloric Acid
HNO3
Nitric Acid
H2SO4
Sulfuric Acid
HBr
Hydrobromic Acid
Polyatomic Ions

C2H3O2
acetate
Polyatomic Ions

CO3
carbonate
Polyatomic Ions

HCO3
hydrogen carbonate
Polyatomic Ions

OH
hydroxide
Polyatomic Ions

NO3
nitrate
Polyatomic Ions

NO2
nitrite
Polyatomic Ions

CrO4
chromate
Polyatomic Ions

Cr2O7
dichromate
Polyatomic Ions

NH4
ammonium
Polyatomic Ions

ClO
hypochlorite
Polyatomic Ions

ClO2
chlorite
Polyatomic Ions

ClO3
chlorate
Polyatomic Ions

ClO4
perchlorate
Polyatomic Ions

SO4
sulfate
Polyatomic Ions

SO3
sulfite
Polyatomic Ions

HSO4
hydrogen sulfate
Polyatomic Ions

HSO3
hydrogen sulfite
1. hydrate

2. anhydrate
1. ionic compounds containing a specific number of H2O molecules for each formula unit, 6H2O = hexahydrate, 1/2 H2O = hemihydrate
2. ionic compounds not containing a number of H2O molecules per formula unit
writing names of molecular compounds of 2 non-metals
1. write name of first element
2. name of second element + -ide suffix
3. use a prefix in front of each name to indicate the number of atoms
Formula Mass
Mass of one individual molecule or formula unit.

H2O = 2(1.008)+16.00 = 18.02amu
Molar Mass
identical to formula mass just in units of g/mole
Percent Composition:

CaCl2 percent of Ca?
molar mass Ca
---------------------------- x 100
molar mass CaCl2
Given 2.4g Na, NaCl is 39% Na. Find mass of NaCl containing 2.4g of Na
1. 100g NaCl contains 39g Na and 61g Cl so...

100g NaCl
2. 2.4g Na x ------------------ =
39g Na
Finding Empirical Formula
1. convert percentages to grams
2. convert grams to moles
3. write a pseudoformula using moles as subscripts
4. divide by smallest number of moles
5. multiply all mole ratios by number to make all whole numbers.