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9 Cards in this Set

  • Front
  • Back

Pressure

STP


1 atm = 101.3 kPa = 760 mmHg


-Is the amount of force exerted on an area


-Pressure at sealevel is 1 atm

Kinetic Theory

-Base of all gas laws. Very essential


-According to kinetic theory:g Gas composed of particles, considered small hard spheres with significant volume. no attractive/repulsive forces


-In constant motion & gas fill container, unconstrained gas will diffuse


-Average KE of collection of gas particles is directly proportional to kelvin temp of gas.

Variables that describe gas

-Amount: pressure caused by collisions of particles within walls of container. Adding a gas increases number of particles, increases pressure. Directly proportional.


-Volume: Pressure increased by reducing size of a container. Inversely proportional.


-Temp: raising temp increases pressure. doubling kelvin, doubles pressure.

Boyles law

-Constant temp, volume varies inversely with pressure:


P1V1=P2V2

Charles' law

-Volume is directly proportional to kelvin temp. Pressure remains constant.


- V1/T1=V2/T2

Gay-Lussac's Law

-Pressure is directly proportional to kelvin temp if volume is constant.


- P1/T1=P2/T2

Combined gas law



Three gas laws above can be combined into a single gas law


P1V1/T1=P2V2/T2


*Note temp must be kelvin and pressure and volume must be same units on both sides

Ideal gas law

-Includes three variables (temp, pressure and volume). Adds another one- amount of gas in a system (expressed in moles)


PV=nRT


-Where R is a constant whose units change depending on the value used for pressure:


-If you use kPa, R=8.315 kPa.L/mol


-If you use atm, R= 0.0821 atm.L/mol


-It you use mmHhg, R= 62.4 mmHg.l/mol

Ideal gas law + kinetic theory

-KE assumes particles have no volume, therefore they don't exist


-Ideal gas obeys all the gas laws at all conditions


-Real gasses can be liquefied, ideal cannot.


-Ideal can be compressed at 0k to be 0 volume (theoretically), real gasses cant- they have volume. They become liquids at low temp and high pressure