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29 Cards in this Set

  • Front
  • Back

The force exerted per unit of surface area.

pressure (P)



(201)

A device used to measure atmospheric pressure. Most commonly, a tube open at one end, which is filled with mercury and inverted into a dish of mercury.

barometer



(202)

A device used to measure the pressure of a gas in a laboratory experiment.

manometer



(202)

The SI unit of pressure;

1Pa - 1 N/m^2pascal (Pa)



(202)

The average atmospheric pressure measured at sea level and 0°C, defined as 1.01325 x 10^5 Pa.

standard atmosphere (atm)



(203)

A unit of pressure based on the difference in the heights of mercury in a barometer or manometer. Renamed the torr in honor of Torricelli.

millimeter of mercury (mmHg)



(203)

A unit of pressure identical to 1 mmHg

torr



(203)

A hypothetical gas that exhibits linear relationships among volume, pressure, temperature and amount (mol) at all conditions; approximated by simple gases at ordinary conditions.

ideal gas



(204)

The gas law stating that a constant temperature and amount of gas, the volume occupied by a gas is inversely proportional to the applied (external) pressure: V∝1/P


Boyle's law



P₁V₁ = P₂V₂



(205)

The gas law stating that at constant pressure, the volume occupied by a fixed amount of gas is directly proportional to its absolute temperature: V ∝ T


Charles's law



V₁ / T₁ = V₂ / T₂



(207)

The gas law stating that, at fixed temperature and pressure, equal volumes of any ideal gas contain equal numbers of particles, and, therefore, the volume of a gas is directly proportional to its amount (mol): V ∝ n

Avogadro's law



V₁ / n₁ = V₂ / n₂



(208)

The reference conditions for a gas: 0°C (273.15 K) and 1 atm (760 torr)

standard temperature and pressure (STP)



(209)

The volume of 1 mol of an ideal gas at standard temperature and pressure:

standard molar volume



22.4141 L.



(209)

An equation that expresses the relationships among volume, pressure, temperature, and amount (mol) of an ideal gas:

ideal gas law



PV = nRT



(209)

A proportionality constant that relates the energy, amount of substance, and temperature of a system;

universal gas constant (R)



R = 8.31451 J/mol K



(209)

The portion of the total pressure contributed by a gas in a mixture of gases.

partial pressure



(219)

A gas law stating that, in a mixture of unreacting gases, the total pressure in the sum of the partial pressures of the individual gases:

Dalton's law of partial pressures



P(total) = P₁ + P₁ + ... + P(n)



(219)

A concentration term expressed as the ratio of moles of one component of a mixture to the total moles present.

mole fraction (x)



(219)

The model that explains gas behavior in terms of particles in random motion whose volumes and interactions are negligible.

kinetic molecular theory



(224)

The speed of a molecule having the average kinetic energy; very close to the most probable speed.

rms speed



(229)

The process by which a gas escapes from its container through a tiny hole into an evacuated space.

effusion



(229)

A gas law stating that the rate of effusion of a gas is inversely proportional to the square root of its density (or molar mass):

Graham's law of effusion



rate ∝ 1/sqrt(M)



(229)

The movement of one fluid through another.

diffusion



(231)

The average distance a molecule travels between collisions at a given temperature of pressure.

mean free path



(232)

The average number of collisions per second that a particle undergoes.

collision frequency



(232)

The mixture of gases that extends from a planet's surface and eventually merges with outer space

atmosphere



(233)

An equation that accounts for the behavior of real gases.

van der Waals equation



(237)

Experimentally determined positive numbers used in the van der Waals equation to account for the intermolecular attractions and molecular volume of real gases.

van der Waals constants



(237)

Common units of pressure - 203

Unit = Normal Atmospheric Pressure at Seal Level and 0°C:



pascal (Pa) = 1.01325 x 10^5 Pa


kilopascal (kPa) = 101.325 kPa


atmosphere (atm) = 1 atm


millimeters of mercury (mmHg) = 760 mmHg


torr = 760 torr