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53 Cards in this Set

  • Front
  • Back

Thermal Motions power...

Biological Interactions

What is the Brownian Motion

Vital Energy Source for Life


Movement of pollen or dust

Water and gas molecules collide at rates dependent of what?

Temperature

What is the optimal medium for "random" collisions and movement?

Water

What are weak interactions necessary for?

Cellular Function

What is another way Electrostatic Interaction is known as?

Salt Bridged or Ionic Bonds

like dissolves...

like

What is the law associated with Electrostatic Interaction?

Coulomb's Law

What causes an Electrostatic Interaction?

When substances electrostatically attracted to eachother go into polar solvent (H2O) force or interaction decreases


Competition

Where is Hydrogen Bonding highest?

In Electronegative Elements (N, O, F)

What does a Hydrogen Bonding interaction utilize?

a lone pair

What process is H-Bonds responsible for?

Transpiration

Other functions of H-Bonds..?

Important Biological Solvent


Keeps things out


Is polar hydrophobic or hydrophilic?

hydrophilic

Is nonpolar hydrophobic or hydrophilic?

hydrophobic

What are Van der Waals Interactions?

Electronegative charge around atom


Will result in partial positive and partial negative


Neighboring atom will interact electrostatically


Contact distance is optimal distance for attraction

What is an example of a hydophobic molecule in water?

drop of oil

What is Entropy?

Measure of randomness

What is the Gibb's Free Energy Formula?

Change in G=change in H-Tchange in S

Do you want change in G to be positive or negative?

Negative

Do you want the entropic term to be positive or negative?

Positive

Do you want to entropic term to be big or small?

Big

What is membrane formation driven by?

Hydrophobic Effect

Where does Acid Base Chemistry take place?

Water

Is there ionization in Acid Base Chemistry?

Small extent

What is ionization?

When a compound or molecule becomes an ion

What is the concentration of each ion in pure water?

1x10^7 M

What is KW?

[H+][OH-]

What is Keq?

The state of equilibrium, when reactions are stable


Doesn't change with time


[products]/[reactant]


stoichiometry becomes superscripts


K>1 eq favors product formation


K<1 eq favors reactant side

What is an acid?

a proton donor

What is a base?

Hydroxide donor/ proton acceptor

Are all acids and bases of equal strength?

No

A strong acid is...

100% dissociated

A weak acid is...

Less than 100% dissociated

What is Ka

The acid dissociation constant

What is the formula for Ka

[A-][H+]/[HA]

What is pH measured by?

Proton Concentration

What is the pH Range?

1-14


What is an acidic pH?

1-6

What is a neutral pH?

7

What is a basic pH?

8-14

What is the formula for pH?

-log[H+]


or


[H+]=10^-pH

What is POH?

OH Concentration

what is the formula for POH?

-log[OH-]


or


[OH-]=1x10^-POH


Ph+POH=14

What is neutralization?

When they fully react to eachother

In neutralization: what does a strong acid and a strong base go to?

Salt and Water

What is the ratio of the equivalence point?

1:1

When talking about the equivalence point which will dictate?

The strong will dictate

What is a titration?

When pH increases; a base must be going into an acidic solution

What is the PKa

The pH of an acid that is 1/2 dissociated

What is a buffer?

A type of solution resistant to changes in pH


Even when acids and bases are added

How do you make a buffer solution?

H+ and OH-


Must be composed of things that absorb protons and hydroxides


What is a buffer usually composed of?

weak acid and conj. base


weak base and conj. acid