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28 Cards in this Set

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Solution

Homogenous mix of solvent and one or more solute.

Unsaturated Solution

Solution that contains less solute than the solvent. Has the capacity to dissolve at a specific temperature.

Saturated Solution

One that contains the max amount of solute that will dissolve in solvent at a specific temperature.

Super Saturated Solution

Contain more dissolved solute than is present in a saturated Solution and are generally unstable.

Solvation

Occurs when solute molecules are separated from one another and surrounded by solvent molecules.

Depends on 3 type of reactions.


1.) Solute-solute interactions


2.) Solvent-Solvent interactions


3.) Solute-solvent interactions


Ion-Dipole

The charge of an ion is attracted to the partial charge on a polar molecule. (NaCl or Ki in water)

Intermolecular interaction

Dipole-Induced Dipole

The partial charge on a polar molecule induces a temporary partial charge on a neighboring Nonpolar molecule or atom. (He or CO2 in water)

Intermolecular Force

Ion-Induced Dipole

The charge of an ion induces a temporary partial charge on a neighboring Nonpolar molecule or atom. (Fe II and O2.)

Intermolecular Force

Entropy

A measure of how the dispersed or spread out its energy is.

There is a natural tendency for the energy of the system to become dispersed.

Miscible

When 2 liquids are completely soluble in each other in all proportions.

Molarity

The amount of solute relative to the volume of a solution or to the amount of solvent in a solution. (called concentration).


Molarity= Moles of solute/Liters of solution.

Mole Fraction

Moles of A/Sum of moles of all components.

Concentration unit.

Molality

Moles of Solute/Kg of solvent

Concentration Unit

Percent by Mass

Independent of temperature.

Solubility

Temperature affects solubility of most substances.

Henry's Law

States that the solubility of a gas in a liquid is proportional to the pressure of the gas over the solution.

Colligative Properties

Properties that depend on the number of solute particles in solution. Do not depend on the nature of the solute particles.

Raoults Law

states that the partial pressure of a solvent over solution is given by the vapor pressure of the pure solvent X the mole fraction of the solvent in the solution.

Ideal solutions obey Raoults Law

Volatile

The vapor pressure of the solution is the sum of the individual partial pressures.

Boiling Point Elevation

Solution boils At a higher temperature than the pure solvent.

Colligative Property

Freezing Point Depression

Solution freezes at a lower temperature than the pure solvent.

Colligative Property

Osmosis

Selective passage of solvent molecules through a porous membrane from a more dilute solution to a more concentrated one.

Osmotic Pressure

The pressure required to stop osmosis.

P=MRT

Van's Hoff Factor (i)

Ion particles dissolved in a solution.


1 is for nonelectrolytes.


2 is for strong electrolytes


3 is for strong electrolytes.

Usually smaller than predicted due to formation of ion pairs.

Ion pair

made up of one or more cations and one or more anions held together by electrostatic forces.

Percent Dissasociation

The percentage of dissolved molecules that separate into ions in a solution and this can be found using colligative properties.

Strong Electrolytes should have complete 100% dissociation. But experimentally determined is not the case. More complete at lower concentration.

Colloid

A Dispersion of particles of one substance throughout another substance. Colloid particles are much larger than the normal solute molecules.

Emulsification

The process of stabilizing a colloid that would otherwise not stay dispersed.