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17 Cards in this Set

  • Front
  • Back
Addn of Br2 (2 moles)
Addn of Br2 (2 moles)
Nomenclature
A. Change the ending of the parent name to –yne
B. Locate the position of the double bond using the lowest possible number
C. The simplest alkyne is called acetylene.
Addition of HX(halides)
Addition of HX(halides)
Addn HX-- 2 moles
Addn HX-- 2 moles
Addition of X2
Addition of X2
Addition of H2O
Addition of H2O
Hydration
Hydration
1.	 The reagent is H+/H2O with a Hg2+ catalyst present
2.	Markovnikov addition of H and OH
3.	A ketone is formed
1. The reagent is H+/H2O with a Hg2+ catalyst present
2. Markovnikov addition of H and OH
3. A ketone is formed
Hydration
Hydration
1.	 The reagent is H+/H2O with a Hg2+ catalyst present
2.	Markovnikov addition of H and OH
3.	A ketone is formed
1. The reagent is H+/H2O with a Hg2+ catalyst present
2. Markovnikov addition of H and OH
3. A ketone is formed
Rules, trends?
Rules, trends?
Addition of BH3 followed by H2O2/KOH

1.	Anti-Markovnikov addition of H and OH
2.	Produces an aldehyde
Addition of BH3 followed by H2O2/KOH

1. Anti-Markovnikov addition of H and OH
2. Produces an aldehyde
Reduction
Reduction
Get alkane
Get alkane
Reduction
Structure?
Reduction
Structure?
Cis
Cis
Reduction
Reduction
Trans
Trans
Ozonalysis Terminal
Ozonalysis Terminal
Ozonalysis Internal
Ozonalysis Internal
Use of acetylide ion as a nucleophile
Use of acetylide ion as a nucleophile
Acidity of Terminal Alkynes
Acidity of Terminal Alkynes
Acidity of term alkyne
Acidity of term alkyne