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27 Cards in this Set

  • Front
  • Back

Avogadro's Number

6.022 X 10^23

Empirical Formula

Lowest whole number ratio of constituent elements in compound

Molarity (M)

mol solute/volume of solution (L)

Gas Constants

1.) 0.0821 L ATM/ Mol K


2.) 8.314 J/Mol K

1.0 L =

1 dm^3

Torr = ATM = Pa

760 Torr = 1 ATM = 1.01325 Pa

T(K)= T(C)

T(C) +273

pH= log

pH= -log[H3O^1+]

Kw=

at (25C)=1.0E^-14

pOH=log

pOH= -log[OH1-]

Three Classes of Solutions

Strong Electrolytes, Weak Electrolytes, Non-Electrolytes

Strong Electrolytes

Solute fully dissolves into ions


Ionic bonds (NaCl)


Strong acids or bases

Weak Electrolytes

fraction of solute dissolves into ions


weak acids/bases

Non-Electrolytes

solute dissolves as neutral species


Alcohol, Ethylene glycol, sugar, many polymers

Vol Fraction of A (V/V)

Vol A/ total volume


Convenient for liquid mixtures

Mass Fraction of A (m/m or w/w) Mass Fraction of A

Mass A/ Total Mass


Convenient for solid mixtures

Mass %=


PPM=


PPB=

MF * 100


MF * 10^6


MF * 10^9

I

"Van't Hoff Factor" # mols Ions/ mol parent formula units

Non-Electrolytes Van't Hoff Factor

1

V

Specific Frequency

Upsidedown Y

Wavelength

Epsolon Wavelength

measure of extent which a given compound absorbs a given color (wavelength)


"Natural inclination to absorb"

Four types of work

Mechanical, chemical, magnetic, and electrical

w=0

ischoric

+w

E flow into a sytstem

-w

E flow out of a system

heat equation

C*Delta T


(one phase present) m*s*delta T


(one phase present) n*molar heat capacity* Delta T


Delta H