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9 Cards in this Set
- Front
- Back
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Catalytic Hydrogentation
1. Pt, Pd, or Ni 2. Raney Ni 3. Partially deactivated Pd. |
1. Alkane
2. Aldehyde/Ketone 3. Acyl Chloride-Chloride Leaves |
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Reduction of Alkynes to Alkenes
1. H2 Lindlar catalyst 2. Na or Li or NH3 |
1. Cis
2. Trans |
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Reduction of Carbonyl Carbons
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NaBH4 + H3O
Esters, CA Amides (H20) |
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Oxidation of Alcohols
1. H2CrO4 2. PCC 3. SO(CH3)2, C2Cl2O2; triethylamine |
1. CA
2. Aldehyde 3. Aldehyde |
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Oxidation of Aldehydes & Ketones
1. H2CrO4 2. Ag2O, NH3 3. CO3H Baeyer-Villiger oxidation |
1. CA
2. CA 3. Aldehyde CA 4. Ketone Ester |
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Migration Tendencies
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H>tert-alkyl>sec-alkyl>primary alcohol>methyl
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Oxidation of Alkenes
1. O3 Zn H2O 2. O3 H2O2 3. KMnO4 OH+ H2O cold; HIO4 or OxO4, HIO4 4. CO3H |
1. Aldehyde
2. CA & Aldehyde 3. di Alcohol; oxidative cleavage, ketone & aldehyde 4. Epoxide |
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Oxidation of 1,2 Diols
HIO4 |
aldehyde & Ketone
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Alkynes p. 931
1. KMnO4, -OH 2. O3, H2O |
2a. Terminal alkyne = CO2
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