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Spontaneous Process

A process that does occur under a specific set of conditions.

A reaction that results in a Decrease in the energy of a system often is spontaneous.

Nonspontaneous

A process that does not occur under a specific set of conditions

Delta S system.

The difference in entropy of the final State and the entropy of the initial state.

Standard Entropy

The absolute entropy of a substance at 1 atm. Temp must be specified.

Trends in Entropy

Delta S rxn

Increase in Entropy

Several Processes that lead to an increase in entropy are.


Melting, Vaporization or Sublimation, Temperature increase, Reaction resulting in a greater number of gas molecules.

Second Law of Thermodynamics

States that for a process to be spontaneous Delta S universe must be positive.

Example: Second Law of Thermodynamics

Third Law of Thermodynamics

States that the entropy of a perfect crystalline substance is zero at absolute serotonin.

Entropy Increases in a substance as temperature increases from absolute zero.

Gibbs Free Energy