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79 Cards in this Set

  • Front
  • Back

John Dalton

All matter is made from atoms


Atoms cannot be made or destroyed


All atoms of a certain element are identical


Different elements contain different types of atoms

J.J Thomson

Atoms have subatomic particles called electrons.

Ernest Rutherford

An atom is mostly empty space, with electrons arranged around a central nucleus.

Niels Bohr

Electrons are arranged in shells or fixed orbits.


Proton


(Charge and Mass)

+1


1

Neuron


(Charge and Mass

0


1

Electron


(Charge and Mass)

-1


0.0005

Atomic Number

The number of protons it contains (and electrons)


The bottom number

Mass number

The total number of protons and neutrons


The top number

Isotopes

A variety of an atom with the same atomic number but a different mass number

Element

A substance with only one type of atom

Compound

A substance with more than one type of element that can be chemically broken down

Electronic Structure

2 electrons in the first shell


8 electrons in second and third shell

Ions


(Definition, creation and formulae)

Charged atom


Created by the loss or gain of one or more negatively charged electron


+ or - to show if it's positively or negatively charged

Ionic Bonding

Metal and a non-metal


Usually the metal will lose an outer electron and the non metal will gain one


The metal will become positively charged and the non metal will become negatively charged

Dot and Cross Diagrams

electrons in the metal are dots


electrons in the non metals or crosses


Properties of Sodium Chloride

High Melting Point


Ionic Compound (needs lots of energy to break)


Conduct electricity when molten or dissolved in water (Ions are free to move out of Giant Ionic Lattice)

Properties of magnesium Oxide

High Melting Point


Ionic Compound


Does not dissolve in water


Conduct electricity when molten

Giant Ionic Lattices

Repeated many times, oppositely charged atoms attract to each other, forming ionic bonds

Formulae of ionic compounds

Na+ + Cl- ----> NaCl


Na+ + O2- ------> 2Na+ + O2-

Dobereiner

Triads-elements with similar properties could be arranged into groups of three

Newlands

Octaves-similar elements appeared in the same row and in relative atomic mass

Mendeleev

Increasing atomic mass, left gaps for undiscovered elements and predicted their properties.

Filling in The Gaps

eka-aluminium was discovered as gallium


Iodine and Tellurium

Iodine should have gone first as it has a lower RAM but he swapped it so Iodine was in group 7 with chlorine and bromine.


Iodine was later discovered to a greater Atomic Number then Tellurium so Mendeleev was correct even if he was unaware of it at the time

Groups and Periods

Horizontal rows are periods


Vertical Columns are groups

Electronic Structure and the Periodic Table

The amount of electrons in the outer shell of an electron determines the group it belongs to on the periodic table

Covalent Bonding

A non-metal and a non-metal

Molecule

A particle containing two or more atoms chemically bonded together


Different to a compound because it can have atoms of the same element

Properties of Carbon Dioxide

low melting point


weak intermolecular forces between molecules if carbon and oxygen


Gas at room temperature


Don't conduct electricity (no overall electrical charge)


Properties of Water

Low melting point


Liquid at room temperature


weak intermolecular forces between hydrogen and oxygen molecules


Don't conduct electricity (no overall electrical charge)

Dot and Cross diagrams in Covalent Bonding

Only the outer shell electrons are shown


Shared electrons are shown in a cross over area

Group 1 Elements

All metals


React with water to create alkaline solutions


Called the Alkaline Metals


Reactivity with water increases as you go down the group

Lithium, Sodium and Potassium

Stored under oil because they are too reactive with air and water.

Reactions with Water

Sodium + Water -------> Sodium Hydroxide + Hydrogen


Lithium + Water -------> Lithium Hydroxide + Hydrogen


Potassium + Water -------> Potassium Hydroxide + Hydrogen

Lithium in water

Disappears slowly


Keeps its shape


Doesn't ignite in water

Sodium

Disappears quickly


Forms a silver ball


Doesn't ignite in water

Potassium

Disappears very quickly


Forms a silvery ball


Ignites in water with a lilac flame

General Equation for the Reaction of Group 1 Elements and Water

2M + 2H2O ------> 2MOH + H2

Trends in Alkaline Metals

The easier it is for a group 1 element to lose an electron, the more reactive it is


When an electron has a low level of attraction the the nucleus, it is easier for it to lose that electron

Oxidation General Reaction

M ------> M+ + e-

Flame Test Results


(Lithium, Sodium and Potassium)

Lithium=Red


Sodium=Orange


Potassium=Lilac

Flame Test Method

-A loop of nichrome alloy wire is attached to a metal handle and cleaned in acid


-Dipped in solid sample and placed in bunsen burner flame to test for colour

Group 7 Elements

Halogens (salt formers)


React with metals to make salts


Reduce in reactivity as you go down the group


Gain an electron to become a negative ion when they react

Uses of Chlorine

Sterilises tap and swimming pool water


In the making of PVC Plastics and pesticides and polyvinyl chloride


Uses of Iodine

Antiseptic in sterilising wounds

Colours of Halogens at Room Temperature

Chlorine is a green gas


Iodine is a grey solid (warmed easily to a purple vapour)


Bromine is an orange liquid

Reactions with Metals

React vigorously with alkaline metals


Sodium + Bromine ------> Sodium Bromide

General Equation for the Reaction of a Group 1 (M) Element and a Group 7 (X2) Element

2M + X2 ------> 2MX

Displacement Reactions

Group 7 elements can react with Metal Halides (Group 1 element + Group 7 element)

Displacement Reaction Example

Chlorine + Sodium Bromide ----------> Bromine + Sodium Chloride

Displacements Order in Group 7 Metal Halides

Fluorine displaces Chlorine


Chlorine displaces Bromine


Bromine displaces Iodine


Iodine displaces Astatine

General Equation for Group 7 Displacement Reactions

X2 + 2MY ------> Y2 + 2MX

Reduction Reaction General Equation

X2 + 2e- -----> 2X-

Transition Metals Properties

Malleable


Shiny when cut


Hard


Compounds often used as catalysts

Coloured Compounds

Copper compounds are often blue


Iron (II) compounds are often light green


Iron (III) compounds are often orange-brown

Thermal Decomposition Reaction

One substance breaks down to form two or more other substance when heated.


General Equation for a Decomposition Reaciton

Metal Carbonate + Heat ------------> Metal oxide + Carbonate dioxide

Carbon Dioxide Test

Limewater turns milky in the presence of carbon dioxide

Precipitation Reactions

Two or more solutions react to make an insoluble solid


The solid is called the precipitate and makes the mixture cloudy

Hydroxide Precipitates

When a compound of transition metals dissolve in water, the positively charged metal ions spread out and react with the negatively charged hydroxide ions in water to form coloured hydroxide precipitates.

Colours of Created Hydroxide Precipitates

Copper(II) -----Cu2+ ----- Blue


Iron (II) ----- Fe2+ ---- Grey-Green


Iron (III) ---- Fe3+ ----- Orange-Brown

Symbol Equationfor Copper (II) Ions and Hydroxide Ions

Cu2+ + 2OH- ----- Cu(OH)2

Copper and Iron Uses

Copper is a good conductor of electricity. Used to make brass and electrical wiring.


Iron is used to make steel for cars and bridges.


Metal Properties

Hard


Shiny and Lustrous


Good Conductors of Heat and Electricity


High Tensile Strength (Can't be stretched)


High Melting and Boiling Points


Metals and Ions

Metals have lots of positive metal ions created by the loss of electrons in each atom.


The free electrons form a "Sea" of delocolised electrons. Metallic bonding is the force between the delocolised electrons and the metal ions.


The force is strong, giving them high melting and boiling point.


Metal Crystals

Contain delocalised electrons


Particles in solid metals are arranged so that they are packed closely and repeated many times. The repetiiton produces crystals

Electrical Resistance

When the delocalised electrons cross paths with the poistive metal ions, electrical resistance happens.


Resistance creates waste heat energy

Superconductors

Materials that have little or no resistance to the flow of electricity


Metals at low temperatures sometimes become superconductors

Superconductors Uses

Powerful Electromagnets


MRI Scanners


Superconductors could be used for....

Super fast electronic circuits


Quicker carrying of electricity in metal cables to homes, factories and offices.


Co

Cons of Superconductors

Only work at very low temperatures (below -200 degrees Celsius)


Water Sources

Reservoirs


Lakes


Underground Reservoirs


97% of the Earth's water is salt water, so fresh water needs to be preserved

Water uses

A solvent


A coolant


A cheap raw material

Pollutants in Water

Nitrates from fertilisers


Lead compounds from old led pipes


Pesticides from crops sprayed in it

Purifying Water

Sedimentation-Removes large suspended particles (sand and soil (etc) settle at the bottom after time)


Filtration-Removes smaller suspended particles


Chlorination-Kills microbes (prevents disease)


Distillation

Creates very pure water from sea water.


Needs a lot of energy though, it's expensive.

Testing for Sulfate Ions

Barium chloride is added to water and if it creates a white precipitate of barium sulfate then sulfate ions are present


Sodium Sulfate + Barium Chloride ----> Sodium Chloride + Barium Sulfate


Na2SO4 + BaCl2 ---> 2NaCl2 + BaSO4

Testing for Dissolved Halide Ions with Silver Nitrate

Chloride ions = A white precipitate


NaCl2 + AgNO3 ----> NaNO3 + AgCl


Bromide ions = A cream precipitate


Iodide ions = A pale yellow precipitate