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59 Cards in this Set

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How is an atom placed in the periodic table?

An atom is placed in the periodic table according to its number of protons

How did Mendeleev use his table to predict the existence and properties of other elements?

By using the gaps between already discovered elements

The mass number is...

The number of protons added to the number of neutrons - the bigger number

Why do atoms bond together to form compounds?

So that they have full outer shells so they are more stable

What is an ion?

Ions are electrically charged particles, formed from atoms by the addition or removal of e-

Which ions are attracted to each other?

Positive cations are attracted to negatively charged anions

How do metals become ions?

Metals lose e- to become metal cations

How do non-metals become ions?

Non-metals gain e- to become non-metal anions

Define an ionic bond

The electrostatic attraction between oppositely charged metal cations and non-metal anions

Compounds ending with "ide" contain...

Two elements

Compounds ending with "ate" contain...

Both named elements and oxgyen

e.g. Calcium carbonate

What charge do ionic compounds have?

Ionic compounds are neutral

Describe the electron configuration and ion formed of an alkali metal

All have 1 e- in their outer shell, therefore forming a metal cation with a charge of 1+

Describe the electron configuration and ion formed of an alkaline Earth metal

All have 2 e- in their outer shell, so they all form metal cations with 2+ charge

Describe the charge of the following ions:


- Cu(i)


- Cu(ii)


- Fe(ii)


- Fe(iii)


- Zn(ii)


- Cu(i) = Cu +


- Cu(ii) = Cu +


- Fe(ii) = Fe 2+


- Fe(iii) = Fe 3+


- Zn(ii) = Zn 2+

Name the compounds:


- CO3


- SO4


- NO3


- OH

- CO3 = Carbonate (2-)


- SO4 = Sulphate (2-)


- NO3 = Nitrate (-)


- OH = Hydroxide (-)

Sheet C2.6e Ionic compounds

Define lattice

A regular arrangement of billions of ions in a 3D structure

Give one example of a giant ionic lattice

NaCl

Do ionic solids conduct electricity and why?

Ionic solids don't conduct electricity as the ions cannot move

How can one enable ionic compounds to conduct electricity?

If ionic compounds are dissolved in water (aqueous) or melted (molten) then they can conduct electricity

Why can molten or aqueous ionic compounds conduct electricity?

As in both the ions can move so the flow of charged particles (current) occurs

Define a precipitate

An insoluble solid formed from the reaction between two soluble substances

Define a covalent bond

A single covalent bond is a shared pair of e- between two non-metals. A double covalent bond would be two shared pairs of e- between 2 non-metals

In a covalent bond, how is the number of shared e- determined?

By the number of e- in the outer shell of the element

Name the two main types of covalent bonds

- Simple molecular covalent substance


- Giant molecular covalent substance

Do covalent substances conduct electricity?

No, bar graphite, as they have no charged particles

Simple molecular covalents are usually...

Gases at room temperature

low melting and boiling points

Simple molecular covalents exist as...

Discrete molecules (e.g. CO2, O2, CO, NH3)

Weak inter-molecular forces, strong intra-molecular forces

Define electronegativity

The property which mans something draws e- to it

Water

Giant molecular covalent substances are...

Solids at room temperature

High melting and boiling points

Give three examples of giant molecular covalents

Diamond, graphite (both allatropes of carbon) and sand (SiO2)

Why doesn't diamond conduct electricity?

As there are no free e- as each carbon atom is bonded to 4 other carbon atoms ---> no free e-

Why does graphite conduct electricty?

As each carbon is bonded to 3 other carbon atoms so there is 1 delocalized e-, meaning they are free to move between layers when p.d. is applied

Give a use of graphite

Lubricant as layers slide over eachother

Give a use of diamond

Drill as extremely strong and durable

Soluble substances are usually...

ionic substances, bar sucrose, which is a covalent

Why are ionic substances usually soluble?

As water possesses hydrogen bonding so there is a polarity - a slight positive charge on the hydrogen and a slight negative charge on the oxygen

Is ethanol attracted to water?

Yes

Why?

Because ethanol contains O, H and C atoms so there is delta charge and will be attracted to water

Is oil immiscible or miscible?

Immiscible

Why?

As it doesn't have oxygen so it's neutral

What is the energy change when bonds are formed?

Energy is released into the surroundings from the system (exothermic)

Name 5 ways which can be used to separate mixtures

-Fractional distillation


-Centrifuge


-Filtering


-Evaporating


-Chromotography

What is distillation?

When a solution is evaporated and then condensed so miscible substances are separated

What is a separating funnel used for?

Separating immiscible mixtures

How can distillation be used to separate ethanol and water?

The mixture is evaporated then condensed. The temp. must be between the boiling point of two of the liquids - ethanol will evaporate, water won't. Ethanol gas condenses in Leiberg condenser, comes out in beaker

Why does the round-bottomed flask have bump granules?

So that SA is increased for bubbles to form

How can a separating funnel be used to separate oil and water?

Densities of two are different - denser of two will sink to bottom, so it can be let out

Name the flame colors for potassium, calcium, sodium and copper

K - lilac


Ca - red


Na - yellow


Cu - blue/green

How does one test for a halide ion?

Add nitric acid and silver nitrate to solution. If halide ions are present the silver halide will precipitate

What are the colours of the possible silver halide precipitates formed?

AgCl - white precipitate


AgBr - cream precipitate


AgI - yellow precipitate

What is the test for sulfate ions?

Add sulfate ions to barium chloride and HCl. If sulfate ions present, barium sulfate will precipitate

How would one tell if barium sulfate is present?

It is a white precipitate

Describe the test for carbonate ions

Acid is added to carbonate, if carbonate is present CO2 released in effervescence, which turns lime water cloudy when bubbled through

What is the use of chromatography?

Separating out different compounds in a mixture

Where must the water level be in order for chromatography to work?

The water level must be below the test samples and pencil line

What will affect how far the samples move?

The particle size/mass and the solubility

How is the Rf value found?

distance moved by compound


---------------------------------------------


distance moved by solvent