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144 Cards in this Set

  • Front
  • Back

What is a compound?

A substance made of multiple atoms chemically bonded together

Elements react to form compounds in two ways - what are they?

By sharing, or by losing/gaining electrons.

Ions are formed when ___________ are transferred

Electrons

Ionic compounds are held together by strong forces between the oppositely charged ions. This is called...

Ionic bonding

The structure of an ionic compound is known as a...

Lattice (giant structure)

The structure of NaCl is a ________ lattice

Cubic

All __________ compounds are neutrally charged

Ionic

The formula of an ionic compound shows the ________ of ions present in the compound

Ratio

A covalent bond is formed when two atoms ____________ a pair of electrons

Share

Atoms of non-metals always need to _________ electrons to achieve stable electronic structures

Gain

Substances that are made of covalently bonded atoms are called...

Molecules

How many covalent bonds do each group form and why?

Group 1 forms a single bond as it only needs one more electron for a stable outer shell. Group 2 forms a double bond as it needs two electrons for a stable outer shell, etc.

One covalent bond only acts between two atoms, so many covalent substances are...

Small/simple

Some atoms such as _________ can form several bonds, so form giant structures

Carbon

Giant covalent structures are known as...

Macromolecules

Explain how a metallic bond works.

When metal atoms are packed together, the electrons with the highest energy level "delocalise" (come free) and begin to move freely through the substance. This causes a lattice of positive ions in a "sea" of moving electrons. The negative, delocalised electrons strongly attract the positive ions, holding the giant structure together.

The atoms in metals are __________ packed together and are arranged in ___________ layers

Closely, regular

Strong ______________ forces hold giant ionic structures together

Electrostatic

Because of strong electrostatic forces, ionic bonds are hard to...

Break

Because it is hard to break ionic bonds, ionic lattices have high __________ and ___________ points

Melting and boiling

Why are ionic compounds able to carry a charge when they are melted?

When They are solid, the ions vibrate around fixed positions so they cannot move. As a liquid, the ions move so are free to carry an electrical charge.

Some ionic compounds can also carry a charge when they are dissolved in...

Water

____________ bonds in a molecule only act between atoms within the molecule, so simple molecules have _________ _________________ forces.

Covalent, weak, intermolecular

Because simple molecular substances have weak intermolecular forces, they have low...

Melting and boiling points

Why can't simple molecular substances carry an electrical charge?

Because molecules have no overall charge

The __________ the molecules in a simple molecular structure, the ____________ the intermolecular forces

Larger, stronger

Substances with large molecules have stronger intermolecular forces, so are more likely to be _________ at room temperature

Liquids

Some elements can form several covalent bonds, so they can join together in...

Giant covalent structures

What are giant covalent structures referred to as?

Macromolecules

Describe a giant covalent structure.

Every atoms is joined to several other atoms by strong covalent bonds

What are some characteristics of macromolecules?

They have extremely high melting and boiling points

Describe the structure of diamond.

Diamond is a form of carbon with a regular 3-D structure. Each carbon atom is covalently bonded to three other carbon atoms, making diamond hard and transparent.

Describe the structure of graphite.

Graphite is a form of carbon which is arranged in giant hexagonal 2-D layers. Each carbon atom is covalently bonded to three others. Each layer is not bonded, so they slide over each other. As a result graphite is slippery and grey.

Why is graphite able to conduct electricity?

As only three carbons are bonded to each carbon in graphite, one electron from each carbon atom is left delocalised, so it is free to carry an electric charge.

What are fullerenes?

Giant molecules formed from hexagonal rings of carbon atoms, some being nano-sized.

What are some applications that fullerenes are being developed for?

Drug delivery into the body, lubricants, catalysts, and reinforcing materials

Why can metals bend?

Metal atoms are arranged in layers. when a bending force is applied, these layers slide over each other without breaking.

Why are alloys harder than pure metals?

Because different metals have different-sized atoms, when they are mixed the regular layers of each metal is distorted. This means the layer cannot slide over each other as easily.

What is a shape memory alloy and what can it be used for?

Shape memory alloys are metal alloys which can return to their original shape after being bent, by heating. They are used in dental braces.

Why are metals good conductors?

They have delocalised electrons, which are free to move throughout the metal and can transfer energy quickly.

What two things influence the properties of polymers?

The monomers used to make them, and the reaction conditions under which they were made.

What properties of polymers can be changed?

Density, softening temperature, melting temperture

Describe the structure of a thermosoftening polymer, and its properties.

Thermosoftening polymers are made of polymer chains which are tangled together.

What is nanoscience?

The study of small particles that are between 1 and 100 nanometres in size.

A nanometre is one ____________ of a metre

Billionth

Nanoparticles have different _______________ to the bulk materials they are made from

Properties

What are some uses of nanoparticles?

Highly selective sensors, super efficient catalysts, construction material enhancements, coatings, cosmetics

What is a danger of using nanoparticles?

As they are used more and more, the risk of them entering our bodies will increase, which could have dangerous effects on us

What is the relative mass of protons and neutrons?

1

The total number of protons and neutrons in an atoms is called the...

Mass number

The atomic number represents...

The number of protons and electrons in an atom

Atoms of the same element always have the same atomic number, but the ______ ____________ can vary

Mass number

Why can the mass number vary in atoms from the same element?

Atoms of the same element can have different number of neutrons

What are isotopes?

Atoms of the same element with different numbers of neutrons

How is the amount of neutrons calculated?

Mass number - atomic number

What is the relative atomic mass?

An average value for the isotopes of an element

What is the relative formula mass?

The relative atomic masses of all the atoms in a formula added up

What is a mole?

The relative formula mass in grams

What is the unit used for moles?

g/mol

What is the symbol for relative atomic mass?

Ar

What is the symbol for relative formula mass?

Mr

How can the percentage of an element in an compound be calculated?

(Relative atomic mass/relative formula mass) x 100

What is the empirical formula?

The simplest ratio of atoms in a compound

How can the empirical formula be calculated?

1) Divide the mass of 100g of the element of the compound by the relative atomic mass (Ar) - this gives the ratio




2) Divide each number by the smallest part of the ratio - this gives the simplest ratio

_______________ symbol equations can be used to calculate the masses of reactants and products in a reaction

Balanced

What is the yield of a reaction?

How much product is made

What is the percentage yield?

The percentage of product made out of the maximum amount that could have been made

How is percentage yield calculated?

(Amount of product made/Maximum amount possible) x 100

Why is it important to get maximum yield?

To conserve resources

What is a reversible reaction?

When the products of a reaction can react together to form the original reactants.

What is an example of a reversible reaction?

The heating of ammonium chloride 

The heating of ammonium chloride

Substances added to food are called...

Food additives

Additives in food can be checked by....

Chemical analysis

Why are two methods of chemical analysis?

Paper chromatography and mass spectrometry

How does paper chromatography work?

A droplet (e.g. food colouring) is added to paper, and a solvent (e.g. water) is allowed to travel through it. different colours move different distances depending on their solubility, separating and revealing them.

Compounds in a mixture can be separated using...

Gas chromatography

How does a GC-MS analysis work?

The mixture is carried through a column by a gas. the column is full of solid particles. Each compound travels through the column at different speeds, so when they come out they are separate and can be identified by a mass spectrometer. They can also be recognised by analysing their retention times.

What is retention time?

The time it takes for a compound to travel through the column of a gas chromatography machine

What two things have to be measured to find the rate of a reaction?

The amount of a reactant used over a certain time, or the amount of product made over a certain time

The rate of reaction can be found from the _____________ a of line on a graph

Gradient

What is collision theory?

A theory that states that reactions can only happen if particles collide with enough energy to form new substances.

Particles need a minimum amount of energy when they collide to for new substances - what is this energy called?

Activation energy

The rate of reaction can be increased by two things - increasing the chance of ______________ , and increasing the _____________ of the particles.

Collisions, energy

What are five ways of increasing the rate of reaction?

Increasing the:




- Surface area


- Temperature


- Concentration


- Pressure




Or by adding a catalyst.

Why does increasing surface area increase the rate of reaction?

Breaking down a solid exposes new surfaces, creating more surface area. More surface means collisions can happen more frequently. Thus, the reaction rate increases.

How does a catalyst increase the rate of reaction?

It lowers the activation energy

Why does increasing temperature increase the rate of reaction?

Increasing the temperature gives the particles more speed and energy. More speed means they collide more often, and more energy means more particles are above the activation energy - Both of these increase the rate of reaction.

Why does increasing the concentration and pressure increase the rate of reaction?

Increasing the concentration/pressure means that there are more particles in the same volume. this means they are closer together. Because they are closer together, they collide more often - this increases the reaction rate. Increasing the pressure

A catalyst is not _______ ___ during a chemical reaction

Used up

To make a catalyst as effective as possible, its _____________ _________ can be increased

Surface area

Why are catalysts used in industry?

They reduce costs/the impact on the environment

Many traditional catalysts are ______________ metals

Transition

What are two modern catalysts being developed?

Nano particles and enzymes

A reaction that transfers energy from the reactants to its surroundings is called...

Exothermic

A reaction which takes energy from its surroundings into the reactants is called...

Endothermic

If a reversible reaction is exothermic in one direction, then it is...

Endothermic in the other direction

The a reversible reaction, the amount of energy released in one direction is _________ to the amount of energy taken in in the other direction

Equal

What are two applications of exothermic and endothermic reactions?

Exothermic reactions can be used in hand warmers




Endothermic reactions can be used in instant cold packs for injuries

Pure water has a pH value of...

7

A liquid with a pH value of 7 is known as...

Neutral

What is an acid?

A substance that produces hydrogen ions, H+(aq) when added to water

When a substance is dissolved in water, it makes an...

Aqueous solution

Hydrogen ions make a solution...

Acidic

What is an acidic solution?

A solution with a pH value of less than 7

_______ react with acids and neutralise them

Bases

What is an alkali?

A base that produces hydroxide ions, OH-(aq), when added to water.

When dissolved in water, alkalis create a solution with a pH value ____________ than 7.

Greater

What is the range of the pH scale?

0-14

_____________ _____________ can be used to test the pH of a solution

Universal Indicators

How does a universal indicator tell us the pH of a solution?

It has different colours at different pH values

Acids will react with metals that are above _____________ in the reactivity series.

Hydrogen

When an acid reacts with a base, a ______________ reaction occurs

Neutralisation

What two things are produced in a neutralisation reaction?

A salt and water

What two things are produced when an acid reacts with a metal?

A salt and hydrogen gas

How can a salt be crystallized?

By evaporating off the water in the solution

Metal _________ and _____________ are bases

Oxides and hydroxides

What can be used to tell when a neutralisation reaction is complete?

An indicator

_____________ salts can be produced by reacting two solutions to form a ______________ .

Insoluble, Precipitate

What are three types of salts?

Chlorides, nitrates, and sulphates

Some pollutants such as __________ ______ can be removed from industrial waste water by ______________ .

Metal ions, precipitation

___________________ splits up substances using electricity

Electrolysis

What must be done to an ionic compound before it can be electrolysed?

It must be made molten or dissolved in a solution

Why must an ionic compound be dissolved or molten for electrolysis?

So the ions are free to move

The substance being broken down in electrolysis is called the...

Electrolyte

The electrodes used in electrolysis are made of substances which will not react with the electrolyte - this is called being...

Inert

Positive ions move to the negative electrode and form either __________ or _____________ .

Metals or hydrogen

Negative ions move to the negative electrode to form a __________________ element.

Non-metallic

When positive ions get to the negative electrode they _______ an electron to become neutral atoms.

Gain

Gaining electrons is called...

Reduction

Losing electrons is called...

Oxidation

When an aqueous solution is electrolysed, __________ gas is produced at the negative electrode, unless the solution contains the ions of a metal that is more reactive than ___________ .

Hydrogen

Aluminium can only be extracted from its ore by electrolysis because it is more reactive than...

Carbon

_______________ __________ is electrolysed to produce aluminium

Aluminium oxide

Aluminium is mixed with molten cryolite for electrolysis - why?

melting pure aluminium would require to much energy and would be too expensive. The aluminium oxide - cryolite mixture has a lower melting point, making the process much more cost efficient.

What two products are formed during the electrolysis of aluminium oxide, and at which electrodes?

Aluminium is formed at the negative electrode, Oxygen is formed at the positive electrode

Why are the carbon electrodes regularly replaced in the electrolysis of aluminium oxide?

They react with the oxygen and gradually burn away

What is brine?

A solution of sodium chloride in water

What four ions does brine contain?

Sodium ions, chloride ions, hydrogen ions, and hydroxide ions

What is produced at the negative electrode when brine is electrolysed?

Hydrogen gas

What is produced at the positive electrode when brine is electrolysed?

Chlorine gas

What solution is left over from the electrolysis of brine?

Sodium hydroxide solution

What is electroplating?

Using electrolysis to coat an object in a thin layer of metal

What are some purposes of electroplating?

- To make an object look more attractive


- To protect a metal from corroding


- To increase the hardness of a surface


- To reduce costs by using a thin layer of metal instead os a pure metal.

How does electroplating work?

The object to be plated is made the negative electrode. the plating metal is made the positive electrode. the solution contains ions of the plating metal. At the positive electrode, the plating metal atoms lose an electron to become ions and go into the solution. these ions go to the negative electrode where they gain an electron to become atoms, and are deposited.