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16 Cards in this Set

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Define a buffer solution

A system which minimises pH changes when small amounts of acid/bases are added

What are the components of a buffer solution

A weak acid and it's conjugate Base (HA and A-)

What are the two methods for preparing buffer solutions

1) Mixing a weak acid with its salt


2) Partially neutralising a weak acid

Equilibria Equation to explain the lack of pH change when an acid is added

HA < - - > H+ + A-

For when an alkali is added:

H+ + OH- < - - > H2O

Typically what are the operating pH's of a buffer if it's pKa is 3

2-4

Equation for the concentration of H+ in a buffer solution

Ka (HA/A-) = H+

Name one common buffer used in the blood

H2CO3

What is the healthy pH and the range for blood (and name the conditions of high acid/alkali blood)

7.4, 7.35-7.45 (acidosis and alkalosis)

What are the symptoms of acidosis and alkalosis

1) Fatigue, shortness of breath, shock/death


2) muscle spasms, light headedness and nausea

Method to use a pH meter

Measure a volume of acid into a conical flask


Place electrode of pH meter in flask


Using a burette, add aqueous alkali, swirling the flask


Record pH changes

Describe the 3 stages of a pH titration curve (acid to alkali)

1) There is an excess of acid. The pH increases very slowly as Base is added.


2) Acid and base concentrations are similar. pH increases rapidly when small amounts of Base added in the vertical section.


3) There is an excess of Base. Once again pH increases slowly as Base is added

What is the equivalence point and how can you find it on a graph

The point when the volume of one solution that reacts exactly with the volume of another solution.


It is the centre of the vertical section.

Define the end point of a titration

When the indicator contains equal concentrations of HA and A-

What are indicators

A weak acid which has a different colour to its conjugate Base

How do you choose an end point

The pH range of an indicator should contain the pKa of the acid