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33 Cards in this Set

  • Front
  • Back
thermodynamics
the branch of chemistry concerned with energy changes
energy
the capacity to do work
kinetic energy
the energy of motion
potential energy
stored energy
oxidation
process where atom or element loses an electron
reduction
process where atom or element gains an electron
redox reactions
reactions in which in which oxidation and reduction take place.
first law of thermodynamics
energy cannot be created or destroyed, it can only change from one form to another
heat
measure of the random motion of moledules
second law of thermodynamics
entropy is continuously increasing
entropy
disorder in the universe
free energy
energy available to do work in any system
enthalpy
energy contained in a molecules chmical bonds
endergonic
reaction that requires input of energy
exergonic
reaction that release excess free energy as heat
activation energy
the extra energy neeeded to destabilize existing chemical bonds and initiate a chemical reaction
catalysis
the process of influencing chemical bonds in a way that lowers the activation energy needed to initaiate a reaction
ATP
a nucleotide consisting of adenine, ribose sugar, and three phosphated groups; energy currency of cellualr metabolism in all organisms
substrates
the molecules that will undergo the reaction
active sites
the pockets or clefts in enzymes
enzyme substrate complex
when substrates bind to the enzyme at these active sites
inhibitor
a substance that binds to an ezyme that decreases its activity
competitive inhibitors
compete with the substrate for the same active site, occupying the active site preventing substrates from binding
noncompetitive inhibitorys
bind to the enzyme in a location other than active site, changing the shape of the enzyme and making it unable to bind to the substrate
allosteric enzymes
can exist in either an active or inactive conformation
allosteric site
portion of enzyme that most noncompetitive inhibitors bind to
allosteric inhibitor
a stubstance that binds to an allosteric site and sreduces enzyme activity
allosteric activator
binds to allosteric sites to keep an enxyme in its active configurations, thereby increasing enzyme activity
cofactors
additional chemical components that are in enzyme function
metabolism
the total of all chemcial reactions carried out by an organism
anabolism
chemcial reactions that expend energy to make or transform chemcial bonds
catabolism
reactions that harvest energy when chemical bonds are broken
biochemical pathways
sequences in whcih the product of one reaction becomes the substrate for the next;organizational units for metabolism