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23 Cards in this Set

  • Front
  • Back

Ferritin

1.

Vanadium bromoperoxidase


1. oxidizes halogens(bromide never touches vanadium)


2. Vanadium


3. Four oxygens and histidine



Vitamin B-12 (cobalamin)_stinson

1.  important cofactor in methyl transferases

2. cobalt (+1)  (CN=6)
3. Corrin ring with two axial ligands

1. important cofactor in methyl transferases


2. cobalt (+1) (CN=6)


3. Corrin ring with two axial ligands



Tecnetium Exametazime (ceretec)_hecimovich

1. It's a nuclear dye for human spectroscopy
2. Tc (Technitium) (+1) (CN:5)
2. kindal like a heme or corrin, with an oxo on the TC

1. It's a nuclear dye for human spectroscopy


2. Tc (Technitium) (+1) (CN:5)


2. kindal like a heme or corrin, with an oxo on the TC



Arginase_schreiber

1. converts arginie to ornithine plus urea
2. 2 Manganese (MN2+) ions (CN=5)
3. Asp and his everywher, with a water in the middle

1. converts arginie to ornithine plus urea


2. 2 Manganese (MN2+) ions (CN=5)


3. Asp and his everywher, with a water in the middle





NiFe hydrogenase_thao

1. metabolizes hydrogen gas

2. Iron (CN=6) and Nickel(CN=5)
3. cysteines mostly

1. metabolizes hydrogen gas


2. Iron (CN=6) and Nickel(CN=5)


3. cysteines mostly



Cytochrome C_lomeli

1. hemeprotein which is electron carrier in ETC.
2. FeIII (CN=6)
3. heme with an open axial postion

1. hemeprotein which is electron carrier in ETC.


2. FeIII (CN=6)


3. heme with an open axial postion



Zinc finger _krismer

1. artifiical RE with zinc-finger and nuclease domains stiched together
2. Zn2+
3. zinc hinger (2cys2his)

1. artifiical RE with zinc-finger and nuclease domains stiched together


2. Zn2+


3. zinc hinger (2cys2his)



Nitrous oxide reductase_feist

1. creates N2 from N20
2. there are two copper (II) ions
3. 2 his 2 cys

1. creates N2 from N20


2. there are two copper (II) ions


3. 2 his 2 cys


Cis-platin

1. cancer drug
2. platinum in it
3.

1. cancer drug


2. platinum in it


3.

mycrosin_waniger

1. gold drug for RA
2. a polymer of gold and sulfur (gold-sulfer backbone)
3.

1. gold drug for RA


2. a polymer of gold and sulfur (gold-sulfer backbone)


3.

ferritin_schultz

1. Iron transport protein
2. Fe(III) all over the place, like 12 per protein
3.

1. Iron transport protein


2. Fe(III) all over the place, like 12 per protein


3.

Gd MRI contrast agents_everson

1. Galladiume 3+ mri contrast agent
2. Gd3+ with NINE CN (8 ligands and a water on the ninth site)
3.

1. Galladiume 3+ mri contrast agent


2. Gd3+ with NINE CN (8 ligands and a water on the ninth site)


3.

chlorophyll_colby

1. Magnesium heme thing inside of chloroplasts they all stack up
2. Mg2+ CN=4 square planar
3.

1. Magnesium heme thing inside of chloroplasts they all stack up


2. Mg2+ CN=4 square planar


3.

oxygen evolving comples (OEC)_reffke

1. site of water oxidation
2. Four Manganese ions (+3 to +4) (CN=8)
3.

1. site of water oxidation


2. Four Manganese ions (+3 to +4) (CN=8)


3.

Yttrium-90_edmond

1. beta emitter for localized chemotherapy
2.  It's actually a monoclonal antibody with yttrium in a tetradentate macrocycle (CN=4) (+3)
3. 

1. beta emitter for localized chemotherapy


2. It's actually a monoclonal antibody with yttrium in a tetradentate macrocycle (CN=4) (+3)


3.

Fe-superoxide dismutatse_bilman

1. 202- + 2H+ ----> h202 +02 (disproportionation of superoxide
2. Fe3+ (his and oxygens)
3. 

1. 202- + 2H+ ----> h202 +02 (disproportionation of superoxide


2. Fe3+ (his and oxygens)


3.

Cobalt 57 cyanocobalamin_waksman

1. B12 replacement
2. Co(I) with a corrin ring
3. 

1. B12 replacement


2. Co(I) with a corrin ring


3.

Liver alcohol dehydrogenase_vircks

1. Turns alcohol into acetyaldehyde
2. Zn(II) CN=4
3.

1. Turns alcohol into acetyaldehyde


2. Zn(II) CN=4


3.

BMOV_hawkinson

1.  Insulin mimetic
2. Vandium (IV) CN=5
3. 

1. Insulin mimetic


2. Vandium (IV) CN=5


3.

Zn/Cu SOD_oster

1. SOD (02- to o2 and h202)
2. Cu(II) and Zn(II)

1. SOD (02- to o2 and h202)


2. Cu(II) and Zn(II)





Nitrogenase_ley

1. N2 --> NH3 (nitrogen fixer)
2. 7 Fe, 1Mo, 9 sulfides, 1 his, 1 cys and 1 homocitrate
3.

1. N2 --> NH3 (nitrogen fixer)


2. 7 Fe, 1Mo, 9 sulfides, 1 his, 1 cys and 1 homocitrate


3.

Sulfite reductatse_bluem

1. converts sulfite into hydrogen sulfide
6h+ + 6e- + HSO3 -> 3H2O and HS-
2. four irons in a cubane shape, plus a heme iron.

1. converts sulfite into hydrogen sulfide


6h+ + 6e- + HSO3 -> 3H2O and HS-


2. four irons in a cubane shape, plus a heme iron.