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19 Cards in this Set
- Front
- Back
oxidation
oxidizing agent |
lose eletrons
oxidizing agent accept electrons and become reduced |
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reduction and reducing agents
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gain electrons
reducing agents: donate electrons and become oxidized |
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NAD
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carrier e-s
two forms: NAD+ and NADH + H+ (reduced_ |
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glycolysis operates without O2 T/F
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false
glycolysis works in presence or absense of O2 |
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functions of glycolysis
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1. almost universl central pathway of glucose catabolism (ex: bacteria, plants, ppl all same)
2. >er form C in pathway: most common degrad of C 3. some cells glucose only source metab E via glycolysis (for brain) 4. one of 1st meta pathwys evolved, is conserved 5. major diff involve pyruvic acid and methods regulation of pathway 7. finished in 1940 |
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food glucose C-C -->
NAD (___) --> |
food glucose C-C --> more oxi
NAD (oxi'd) --> NADH reduced series of red oxi rxns --> VALUABLE ATP |
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1st couple of rxns of glycolysis ___
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couple of rxns of glycolysis E consuming, glucose gets more E than before
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[S] level phorylation
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make ATP on spot, glycolysis
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net E calculation: glycolysis
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2 ATP in ------------= -2 ATP
2 NADH made-------= +4ATP 2 ATP made--------= +4ATP = 6 ATP/gycolysis turn every NADH --> 2 ATPs for NADH to be used --> mitochondria |
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glycolysis process
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glucose (atp -> ADP)--- glucose 6 Pi---frutcose 6 phosphate (atp -> ADP)---fructose 1,6 biPi
-----dihydroxyacetone phosphate or -----3 phosphoglyceraldehyde ----2 of the rest: ----3 phosphoglyceraldehyde (NAD+ --> NADH)----1,3 biPiglyceric Acid (ADP -> atp)----3 Phosphoglyceric glyceric Acid---2 Pi glyceric Acid---phosphoenolpyruvate (ATP -> adp)-----pyruvic acid |
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% E efficiency
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6 ATP * 8,000 cal
--------------------- X 100 686,000 cal/mol 7% efficiency made available thru glycolysis what happened to other 93%? NOT IN GLYCOLYSIS |
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phosphoenolpyruvate PEP
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unstable!
adp --> ATP |
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after fructose 1,6 biphosphate splits into 2,
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after fructose 1,6 biphosphate splits into 2,
rest of them are 2 molecules dihydroxyacetone phosphate 3 - phosphoglyceraldehyde |
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number in front
ex: 3 phosphoglyceraldehyde |
= +ed C @ beta C (first carbon)
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glucose
//////// _________ |
====glucose====
//////// ====pyruvate==== ////////////////// no O2-------- O2 ////---------//////// ethanol---acetyl CoA or lactic----//////// acid--------Krebs cycle |
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pyruvate process
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pyruvate -- oxidation decaboxylation -- CoA -- pulls off carboxyl group (CO2) -- NAD -- NADH -- Acetyl CoA -- Ctiric acid cycle
-->es 6 ATP 40% efficiency 0=--> O2 makes HUGE difference |
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1 Kreb cycle = ___ ATPs
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1 Kreb cycle = _12 ATPs
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complete oxidation of glucose = __ ATP
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complete oxidation of glucose = 36 ATP
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pyruvate oxidation occurs in the ___ of the cell
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pyruvate oxidation occurs in the mitochondria of the cell
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