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80 Cards in this Set

  • Front
  • Back
element
substances that cannot be broken down into simpler substances by ordinary chemical reactions
oxygen
O
carbon
C
hydrogen
H
nitrogen
N
calcium
Ca
Phosphorus
P
potassium
K
Sulfur
S
sodium
Na
magnesium
Mg
Chlorine
Cl
iron
Fe
matter
anything that has mass and takes up space

-components of atoms
-dont work with chemical properties
electron
a particle that carries a unit of negative charge
proton
a particle that carries a unit of positive charge
neutron
an uncharged particle
atomic nucleus
composed of protons and neutrons

-electrons exist outside of this
atomic number
the fixed number of protons in an elements atomic nucleus
atomic mass unit (amu)
unit of measure for the mass of subatomic particles

1 x = 1 proton or 1 neutron
1/1800 x = 1 electron
atomic mass
a number that indicates how much matter an atom of an element contains

*left postscript
isotopes
atoms which consist of a mixture of atoms with different numbers of neutrons and therefore have different masses

-of the same element have the same numbers of protons and electrons, on the number of neutrons varies

ex: carbon 14 is a _____ of carbon?
radioisotopes
isotopes which are unstable and tend to break down or decay to a more stable isotope, usually becoming a different element

-emit radiation as they decay
autoradiography
a way of detecting radioactive decay in which radiation causes the appearance of dark silver grains in photographic film
orbitals
3d space in which electrons move

-each of these contains a maximum of 2 electrons

-these are depicted as electron clouds because it is impossible to know where an electron will be at any moment

-energy of an electron depends on which one of these it occupies
electron shell
electrons in orbitals with similar energies

-greater distance from the nucleus = greater energy

-smaller distance from the nucleus = smaller energy
valence electrons
the most energetic electrons that occupy the outermost orbital
valence shell
the outermost concentric ring in a bohr model

-houses the most energetic electrons

-the play a key role in chemical reactions

-electrons can move to different orbitals by gaining or losing electrons
the chemical behavior of an atom is determined primarily by the number and arrangement of its valence electrons

-valence shell of H or He is full with 2 electrons, any other atom is full with 8 electrons

-when the valence shell is not full the atom tends to gain, lose, or share electrons to achieve a full valence shell

- the valence shells of all isotopes of an element are identical, in this way they have similar chemical properties and can be substituted for one another in chemical reactions
info on valence electrons:
chemical compound
consists of atoms of 2 or more different elements combined in a fixed ratio
molecular mass
this is found by determining the sum of the atomic masses of the component atoms of a single molecule

-measured in amu or grams
mole (mol)
the amount of an element or compound whose mass in grams is equivalent to its atomic or molecular mass
6.022 x 10^23

- the number of units in 1 mol
what is avogadros number?
dynamic equilibrium
when the rates of forward and reverse reactions are equal
bond energy
the energy necessary to break a chemical bond

-valence electrons dictate how many bonds an atom can form
covalent bonds
involve the sharing of electrons between atoms in a way that results in each atom having a filled valence shell
covalent compound
unlike atoms linked by covalent bonds to form molecules
single covalent bond
when one pair of electrons is shared between 2 atoms
double covalent bond
when 2 pairs of electrons are shared between 2 atoms

- in molecular oxygen, 2 O atoms share 2 pairs of electrons, forming this
orbital hybridization
when an atom forms covalent bonds with other atoms, the orbitals in the valence shells may become rearranged, thereby affecting the shape of the molecule...what this process called?
electronegativity
a measure of an atoms attraction for shared electrons in chemical bonds
nonpolar covalent bond
when covalently bonded atoms have similar electronegativities and the electrons are shared equally
polar covalent bonds
a covalent bond between atoms that differ in electronegativity

-such a bond has 2 dissimilar ends, one with a partial positive charge and the other with a partial negative charge
ion
a particle with one or more units of electrical charge

- an atom becomes this if it gains or loses one of more electrons

- an atom with 1, 2, or 3 electrons in its valence shell has a tendency to lose electrons to other atoms. such an atom then becomes positively charged because its nucleus has more protons than the electron cloud posses in electrons
cations
positively charged ions
anions
negatively charged ions
ionic bond
forms as a consequence of the attraction between the positive charge of a cation and the negative charge of an anion
ionic compound
a substance consisting of anions and cations bonded by their opposing charges

-compounds joined by ionic bonds have a tendency to separate into their individual ions when placed in water

-in solid form, very strong
solvent
as a liquid, ti is capable of dissolving many substances, particularly those that are polar or ionic
solute
a dissolved substance
hydration
in solution, when each cation and anion of the ionic compound is surrounded by oppositely charged ends of the water molecules
hydrogen bond
when H combines with O or with another relatively electronegative atom, it acquires a partial positive charge because its electron spends more time closer to the electronegative atom

-these bonds tend to form between an atom with a partial negative charge and a H atom that is covalently bonded to O or N

-these bonds are readily formed and broken

-although individually weak, these bonds are collectively strong when present in large numbers
van der waal interactions
the attractive forces, that operate over very short distances and are weaker and less specific that covalent bonds or ionic bonds

-they are most important when they occur in large numbers and when they can permit close conduct between atoms

-ind. weak, collectively strong
oxidation
a chemical process in which an atom, ion, or molecule loses electrons

-always occurs with reduction
reduction
a chemical process in which an atom, ion or molecule gains electrons

-always occurs with oxidation
cohesion
the ability to stick to one another

-helps water molecules stick together and move together
adhesion
the ability to stick to many other kinds of substances
capillary action
a combination of adhesive and cohesive forces

-this is a tendency of water to move in narrow tubes, even against the force of gravity
surface tension
cohesion of its molecules, which have a much greater attraction for another than for molecules in the air

-water molecules are polar, one end of each molecule bears a partial positive charge and the other a partial negative charge
hydrophilic
water-loving, substances that interact readily with water
hydrophobic
water-fearing, substances that dont readily interact with water
hydrophobic reactions
occur between groups of nonpolar molecules. such molecules are insoluble in water and tend to cluster together
kinetic energy
the energy of motion
heat
refers to the total amount of kinetic energy in a sample of a substance
temperature
a measure of the average kinetic energy of the particles in a substance
heat of vaporization
the amount of heat energy required to change 1g of a substance from the liquid phase to the vapor phase, expressed in the unit of calories
calorie
the amount of heat energy required to raise the temperature of 1g of water to 1*C
evaporative cooling
when faster moving molecules escape the liquid phase and move to the vapor, taking heat with them in the process
ionize
tendency in water molecules to dissociate into H ions (H+) and hydroxide ions (OH-)
acid
a substance that dissociates in solution to yield H ions (H+) and anions
base
substance that dissociates to yield hydroxide ions (OH-) and a cation when dissolved in water
pH
Defined as the negative logarithm of the H ion concentration
neutral solution
pH = 7, has equal concentrations of H ions and hydroxide ions
acidic solution
pH - less than 7, has more H+ than OH- ions
basic solution
pH = greater than 7, has more OH- than H+ ions
buffer
a substance or combination of substances that resists change in pH when an acid or base is added
dynamic equilibrium
when the ratio of the forward and reverse reactions are equal and the relative concentrations of the components are not changing

-the equilibrium can be shifted and a subsequent new one is formed if outside stress is placed on the system
salt
a compound in which the H ion of an acid is replaced by some other cation
electrolytes
when a salt, acid, or base is dissolved in water, it dissociated ions can conduct electric current, these ions are called what?
non-electrolytes
other substances that are dissolved in water and do not form ions and dont conduct electric current