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80 Cards in this Set
- Front
- Back
element
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substances that cannot be broken down into simpler substances by ordinary chemical reactions
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oxygen
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O
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carbon
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C
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hydrogen
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H
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nitrogen
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N
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calcium
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Ca
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Phosphorus
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P
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potassium
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K
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Sulfur
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S
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sodium
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Na
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magnesium
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Mg
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Chlorine
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Cl
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iron
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Fe
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matter
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anything that has mass and takes up space
-components of atoms -dont work with chemical properties |
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electron
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a particle that carries a unit of negative charge
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proton
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a particle that carries a unit of positive charge
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neutron
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an uncharged particle
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atomic nucleus
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composed of protons and neutrons
-electrons exist outside of this |
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atomic number
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the fixed number of protons in an elements atomic nucleus
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atomic mass unit (amu)
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unit of measure for the mass of subatomic particles
1 x = 1 proton or 1 neutron 1/1800 x = 1 electron |
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atomic mass
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a number that indicates how much matter an atom of an element contains
*left postscript |
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isotopes
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atoms which consist of a mixture of atoms with different numbers of neutrons and therefore have different masses
-of the same element have the same numbers of protons and electrons, on the number of neutrons varies ex: carbon 14 is a _____ of carbon? |
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radioisotopes
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isotopes which are unstable and tend to break down or decay to a more stable isotope, usually becoming a different element
-emit radiation as they decay |
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autoradiography
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a way of detecting radioactive decay in which radiation causes the appearance of dark silver grains in photographic film
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orbitals
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3d space in which electrons move
-each of these contains a maximum of 2 electrons -these are depicted as electron clouds because it is impossible to know where an electron will be at any moment -energy of an electron depends on which one of these it occupies |
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electron shell
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electrons in orbitals with similar energies
-greater distance from the nucleus = greater energy -smaller distance from the nucleus = smaller energy |
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valence electrons
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the most energetic electrons that occupy the outermost orbital
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valence shell
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the outermost concentric ring in a bohr model
-houses the most energetic electrons -the play a key role in chemical reactions -electrons can move to different orbitals by gaining or losing electrons |
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the chemical behavior of an atom is determined primarily by the number and arrangement of its valence electrons
-valence shell of H or He is full with 2 electrons, any other atom is full with 8 electrons -when the valence shell is not full the atom tends to gain, lose, or share electrons to achieve a full valence shell - the valence shells of all isotopes of an element are identical, in this way they have similar chemical properties and can be substituted for one another in chemical reactions |
info on valence electrons:
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chemical compound
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consists of atoms of 2 or more different elements combined in a fixed ratio
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molecular mass
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this is found by determining the sum of the atomic masses of the component atoms of a single molecule
-measured in amu or grams |
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mole (mol)
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the amount of an element or compound whose mass in grams is equivalent to its atomic or molecular mass
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6.022 x 10^23
- the number of units in 1 mol |
what is avogadros number?
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dynamic equilibrium
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when the rates of forward and reverse reactions are equal
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bond energy
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the energy necessary to break a chemical bond
-valence electrons dictate how many bonds an atom can form |
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covalent bonds
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involve the sharing of electrons between atoms in a way that results in each atom having a filled valence shell
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covalent compound
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unlike atoms linked by covalent bonds to form molecules
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single covalent bond
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when one pair of electrons is shared between 2 atoms
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double covalent bond
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when 2 pairs of electrons are shared between 2 atoms
- in molecular oxygen, 2 O atoms share 2 pairs of electrons, forming this |
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orbital hybridization
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when an atom forms covalent bonds with other atoms, the orbitals in the valence shells may become rearranged, thereby affecting the shape of the molecule...what this process called?
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electronegativity
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a measure of an atoms attraction for shared electrons in chemical bonds
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nonpolar covalent bond
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when covalently bonded atoms have similar electronegativities and the electrons are shared equally
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polar covalent bonds
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a covalent bond between atoms that differ in electronegativity
-such a bond has 2 dissimilar ends, one with a partial positive charge and the other with a partial negative charge |
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ion
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a particle with one or more units of electrical charge
- an atom becomes this if it gains or loses one of more electrons - an atom with 1, 2, or 3 electrons in its valence shell has a tendency to lose electrons to other atoms. such an atom then becomes positively charged because its nucleus has more protons than the electron cloud posses in electrons |
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cations
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positively charged ions
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anions
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negatively charged ions
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ionic bond
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forms as a consequence of the attraction between the positive charge of a cation and the negative charge of an anion
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ionic compound
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a substance consisting of anions and cations bonded by their opposing charges
-compounds joined by ionic bonds have a tendency to separate into their individual ions when placed in water -in solid form, very strong |
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solvent
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as a liquid, ti is capable of dissolving many substances, particularly those that are polar or ionic
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solute
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a dissolved substance
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hydration
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in solution, when each cation and anion of the ionic compound is surrounded by oppositely charged ends of the water molecules
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hydrogen bond
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when H combines with O or with another relatively electronegative atom, it acquires a partial positive charge because its electron spends more time closer to the electronegative atom
-these bonds tend to form between an atom with a partial negative charge and a H atom that is covalently bonded to O or N -these bonds are readily formed and broken -although individually weak, these bonds are collectively strong when present in large numbers |
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van der waal interactions
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the attractive forces, that operate over very short distances and are weaker and less specific that covalent bonds or ionic bonds
-they are most important when they occur in large numbers and when they can permit close conduct between atoms -ind. weak, collectively strong |
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oxidation
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a chemical process in which an atom, ion, or molecule loses electrons
-always occurs with reduction |
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reduction
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a chemical process in which an atom, ion or molecule gains electrons
-always occurs with oxidation |
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cohesion
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the ability to stick to one another
-helps water molecules stick together and move together |
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adhesion
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the ability to stick to many other kinds of substances
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capillary action
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a combination of adhesive and cohesive forces
-this is a tendency of water to move in narrow tubes, even against the force of gravity |
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surface tension
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cohesion of its molecules, which have a much greater attraction for another than for molecules in the air
-water molecules are polar, one end of each molecule bears a partial positive charge and the other a partial negative charge |
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hydrophilic
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water-loving, substances that interact readily with water
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hydrophobic
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water-fearing, substances that dont readily interact with water
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hydrophobic reactions
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occur between groups of nonpolar molecules. such molecules are insoluble in water and tend to cluster together
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kinetic energy
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the energy of motion
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heat
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refers to the total amount of kinetic energy in a sample of a substance
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temperature
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a measure of the average kinetic energy of the particles in a substance
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heat of vaporization
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the amount of heat energy required to change 1g of a substance from the liquid phase to the vapor phase, expressed in the unit of calories
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calorie
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the amount of heat energy required to raise the temperature of 1g of water to 1*C
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evaporative cooling
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when faster moving molecules escape the liquid phase and move to the vapor, taking heat with them in the process
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ionize
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tendency in water molecules to dissociate into H ions (H+) and hydroxide ions (OH-)
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acid
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a substance that dissociates in solution to yield H ions (H+) and anions
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base
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substance that dissociates to yield hydroxide ions (OH-) and a cation when dissolved in water
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pH
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Defined as the negative logarithm of the H ion concentration
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neutral solution
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pH = 7, has equal concentrations of H ions and hydroxide ions
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acidic solution
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pH - less than 7, has more H+ than OH- ions
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basic solution
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pH = greater than 7, has more OH- than H+ ions
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buffer
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a substance or combination of substances that resists change in pH when an acid or base is added
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dynamic equilibrium
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when the ratio of the forward and reverse reactions are equal and the relative concentrations of the components are not changing
-the equilibrium can be shifted and a subsequent new one is formed if outside stress is placed on the system |
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salt
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a compound in which the H ion of an acid is replaced by some other cation
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electrolytes
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when a salt, acid, or base is dissolved in water, it dissociated ions can conduct electric current, these ions are called what?
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non-electrolytes
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other substances that are dissolved in water and do not form ions and dont conduct electric current
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