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23 Cards in this Set

  • Front
  • Back

4 element theory 400BC

People who followed Aristotle believed all matter was a combination of:


Air, Earth, Fire, and Water

Democritus 460-370 BC

World is made up of empty space and tiny particles called atoms. (Didn’t believe 4 element theory)

Law of Conservation of Mass

Lavoisier concludes matter is neither created nor destroyed, only changed.

The Law of Definite Proportion

A compound contains exactly the same elements in exactly the same proportions by mass regardless of the size.

The Law of Multiple Proportions

Atoms of 2+ elements may combine in different ratios to produce more than one compound.

J. J. Thomson 1897

Discovered the electron

J. J Thomson 1897

Atoms contain negatively charged particles from conducting the cathode ray experiment. Atoms must also have a positive change since atoms are know to be neutral.

Robert Millikan 1909

An American physicist who determined the charge of an electron via the oil drop experiment.

Ernest Rutherford 1909

Gold foil experiment: directed alpha particles at a thin sheet of gold foil and observed the path of deflection of the particles.

Ernest Rutherford 1911

Concluded that atoms have a dense, positively charged core (nucleus) which is surrounded mainly by emptyspace where electrons are found

Thomson’s model vs. Rutherford’s model

Thomson’s model didn’t have a distinct positively charged nucleus, only positive charge


Thomson’s model didn’t have an atom with mostly empty space

Niels Bohr 1913

Planetary model of the atom


Proposed that electrons could move around in the nucleus only in certain allowed circular orbits.

Quantum Mechanical Model 1935ish

Used today


Electrons have particles and waves.


Shows probable location of an electron


Probability distribution: more dots=areas with higher prob. of finding an electron

Sir James Chadwick 1932

Discovered NUETRONS: a particle with the same mass as protons but with no electrical charge in the nucleus

S sublevel shape

Sphere

P sublevel shape

Dumbell

D and F sublevel shape

Very complicated

Orbital

Region of space around the nucleus where there is a high probability of finding an electron.

Aufbau Principle

Electrons are added one at a time to the lowest energy orbitals first

Pauli Exclusion Principle

There’s a maximum of 2 electrons per orbital and they must have opposite spins.

Hund’s Principle

Electrons don’t pair up until they are forced to.

Degenerate orbitals

Orbitals of equal energy (2px, 2py, 2pz)

Heisenberg Uncertainty Principle

It is impossible to determine both the position and momentum of a particle simultaneously