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10 Cards in this Set
- Front
- Back
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Mercuration/Demercuration (Alkane to alcohol w/o carbon chain rearrangement) |
Hg(OAc)2 + THF NaBH4 OH- |
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Hydroboration/Oxidation (Alkene to alcohol anti Markovnikov) |
BH3 + THF H2O2 OH- |
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Acid Catalyzed Oxidation (Alkene to alcohol, prone to carbon frame rearrangement) |
Acid, water |
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Double bond cleavage without converting H to OH |
Ozone, CH2Cl2, cold, Zn/HOAc |
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Double bond cleavage that converts H to OH |
KMnO4 Heat OH- |
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Glycerization (always syn) |
KMnO4, heat, OH- OR OsO4, pyrimidine, NaSO3 |
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Forming Alkyne |
Dihalogenated alkane + excess NaNH2 |
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Alkyne to Alkene (trans) |
Li EtNH2, Cold NH4Cl |
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Alkyne to Alkane |
Pt, Hydrogen |
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Alkyne to alkene (cis) |
Lindlar's Catalyst |
