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43 Cards in this Set

  • Front
  • Back
What is temperature measured with in thermal physics?
The Kelvin/absolute temperature scale
What is the unit is temperature measured in in thermal physics?
Kelvin, K
What is absolute zero?
The lowest possible temperature an object can have.
What is the value of absolute zero?
-273°C / 0 K
How much kinetic energy do molecules have at absolute zero?
No kinetic energy
What is a molecule's energy proportional to when using the Kelvin scale?
Its temperature
How do you convert degrees Celsius into Kelvin?
Add 273.

K=C+273




Where:


K is temperature in Kelvin


C is temperature in degrees Celsius

What does Boyle's Law state?
At a constant temperature the pressure p and volume V of a gas are inversely proportional.
What is an ideal gas?

A gas that obey's:




• Boyle's law at all temperatures.


• A gas that obeys Charles' law


• The pressure law

What will the product of p*v always be?
Constant
On a pressure-volume graph in what direction will a higher temperature move the curve?
Further away from the origin
Following Boyle's law, what happens to the volume of a gas if it's pressure doubles?
Volume is halved
What does Charles' law state?
At constant pressure, the volume V of a gas is directly proportional to its absolute temperature T.
What is the volume of a gas at absolute zero?
Zero
Following Charles' law, what happens if the temperature is doubled?
The volume doubles.
If Charles' law is obeyed, what is the volume divided by the temperature?
Constant
What does the pressure law state?
At constant volume, the pressure p of a gas is directly proportional to its absolute temperature T.
Following the pressure law, what happens if the temperature doubles?
Pressure doubles
What is the value for pressure at absolute zero?
Zero

If the pressure law is obeyed, what is the pressure divided by the temperature?

Constant


What is the Avogadro constant?
The number of atoms in exactly 12 g of carbon-12.
What does the Avogadro constant give?
The number of atoms in any volume of substance whose mass, in grams, is the same as its relative atomic mass.
What is the value of Avogadro's constant?
6.02x10^23 mol-¹
What is the symbol for Avogadro's constant?
NA


What is 1 mole of a substance defined as?
A substance that contains NA atoms or molecules, all of which are identical.
What is the molar mass of a substance?
The mass that 1 mole of the substance would have.

What is molar mass usually measured in?

grams
What is molar mass equal to?
A substances relative atomic or relative molecular mass.
What is the number of moles in a substance usually given by?
n
What is the number of moles in a substance usually measured in?
mol
What is the equation for number of molecules in a gas?
N=n*NA



Where:


N is the number of molecules


n is number of moles


NA is Avogadro's constant

What is the molar gas constant, R?
8.31 Jk-¹
How do you derive the ideal gas equation?
• Combine the three laws to get pV/T = constant

• The molar gas constant, R, is used


• The value of pV/T depends on how much gas is present so n is used to represent the number of molecules present


• Putting all this into one equation gives pV/T=nR


• Which can be rearranged to give the ideal gas equation.

What is the ideal gas equation?
pV=nRT



Where:


p is pressure


v is volume


n is number of moles of gas


T is temperature


R is the molar gas constant



What is pressure measured in?
Pa (Pascals)
What is volume measured in?
m³ (meters cubed)
What does the ideal gas law work best for?
Gases with low pressure and fairly high temperatures
What is Boltzmann's constant equivalent to?
R/NA
What is the symbol for Boltzmann's constant?
k
What is the value of Boltzmann's constant?
1.38x10-23 JK-¹
What is the equation of state of an ideal gas?
pV=NkT



Where:


p is pressure


v is volume


N is the number of molecules of gas


T is the temperature


k is the Boltzmann constant

How do you derive the pressure of an ideal gas?
• Imagine a cubic box with sides of length l containing N molecules each of mass m.

• Derive the pressure on one wall of this box in the x direction.


• If molecule Q moves directly towards wall A with velocity u it's momentum approaching the wall is mu.


• If the collisions are perfectly elastic when the molecule strikes wall A, the molecule will rebound in the opposite direction with momentum -mu.


• This makes the change in momentum 2mu.


• Assuming there are no collisions with other mokle

What is Newton's third law of motion?

Every action has an equal and opposite reaction