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104 Cards in this Set

  • Front
  • Back
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___ occupies space at any given time and has a mass.
Matter
Capacity to do work (puts matter to work).
Energy
Substances that cannot be split into simpler substances by ordinary chemical means.
Chemical elements
Units of matter of all chemical elements.
Atom
What subatomic particles can be found in an atom and what are their charges?
An atom is made up of a nucleus that contains protons (+) and neutrons (neutral). Surrounding the nucleus are electrons (-).
What are the main chemical elements in the body?
Carbon, Hydrogen, Oxygen, Nitrogen, Phosphorus
CHONP
The # of electrons in an atom always equals the # of ___.
Protons
The # of protons in the nucleus is called ___.
Atomic number
The sum of an atom's protons and neutrons is called ___.
Mass number
Atoms of an element with the same # of protons but different # of neutrons are called ___.
Isotopes
Isotopes who are unstable and have nuclei that decay into a stable configuration are said to be ___.
Radioactive isotopes
Time required for half of the radioactive atoms in an isotope sample to decay into a more stable form.
Half-life
On the periodic table, is a group horizontal or vertical? What is similar in a group?
Vertical. A group has the same charge and the same configuration in the valence shell.
On the periodic table, is a period horizontal or vertical? What is similar in a period?
Horizontal. A period has the same # of shells.
Describe the octet rule.
Electron shells follow the 2-8-8 pattern.
Standard unit for measuring mass of atoms and subatomic particles.
Dalton
The average mass of all of an element's naturally occurring isotopes is called ___. It is typically close to the mass number of its most abundant isotope.
Atomic mass (or weight)
An atom with a (+) or (-) charge because it has an unequal # of protons and electrons.
Ion
Process of giving up or gaining electrons.
Ionization
Atoms sharing electrons are called ___.
Molecules
Substance that contains 2 or more atoms of different elements.
Compound
Electrically charged atom or group of atoms with an unpaired electron in its outermost shell. Unstable and highly reactive. Can become stable by giving or gaining an electron.
Free radical
What substances in the body can inactivate oxygen-derived free radicals?
Antioxidants such as selenium, zinc, beta-carotene, and vitamins C and E.
Atoms of a molecule are held together by forces of attraction called ___.
Chemical bonds
The likelihood that an atom will form a chemical bond with another atom depends on ___.
The # of electrons in an atom's valence shell.
What type of bond holds ions together and why? Is energy needed to make or break the bond?
Ionic bond. Positively and negatively charged ions are attracted to one another. Energy is NOT needed to make but needed to break.
Positively charged ions are called ___.
Cations
Negatively charged ions are called ___.
Anions
An ionic compound that breaks apart into ions in solution is called ___.
Electrolyte
What type of bond is formed by atoms sharing 1, 2 or 3 pairs of their valence electrons? Is energy needed to make or break the bond?
Covalent bond. Energy is needed to make but not needed to break.
What is the different between polar and nonpolar covalent bonds?
In a nonpolar bond, atoms share electrons equally. In a polar bond there in unequal sharing of electrons.
What element usually creates a polar covalent bond?
Hydrogen
What is a hydrogen bond and how is it different from ionic and covalent bonds? Is it weaker or stronger? What 2 elements is hydrogen most often attracted to?
A hydrogen bond is formed when a hydrogen atom with a partial positive charge attracts the partial negative charge of another atom. It occurs in MOLECULES that are already polar covalently bonded where as ionic /covalent bonds occur between ATOMS. Hydrogen bonds are weak links compared to ionic/covalent bonds. Hydrogen is most attracted to oxygen and nitrogen.
HON
A ___ occurs when a new bonds form and old bonds break.
Chemical reaction
Starting substances in a reaction.
Reactants
Ending substances in a reaction.
Products
The sum of all chemical reactions occurring in the body.
Metabolism
The # of ___ is the same before and after a chemical reaction.
Atoms
The principle ___ states the total amount of energy at the beginning and end of a reaction is the same. Although energy can neither be created/destroyed, it can be converted from one form to another.
Law of conservation of energy
Energy associated with motion.
Kinetic energy
Energy stored by matter due to its position.
Potential energy
Collision energy needed to break the chemical bonds of the reactants is called ___.
Activation energy
Name 3 factors that can cause a chemical reaction.
Concentration, temperature, catalysts.
Club scenario - wingman
Chemical compounds that lower activation energy and speed up chemical reactions.
Catalysts (enzymes)
A ___ reaction is where 2 or more atoms/ions/molecules combine to form new and larger molecules. Is it anabolism/catabolism? Endergonic/exergonic?
Synthesis reaction. Anabolism. Endergonic.
A ___ reaction splits up large molecules into smaller atoms/ions/molecules. Is it anabolism/catabolism? Endergonic/exergonic?
Decomposition reaction. Catabolism. Exergonic.
A ___ reaction consists of both synthesis and decomposition reactions.
Exchange reaction
A ___ reaction is where the products can revert to the original reaction.
Reversible reaction
Do inorganic compounds contain carbon? Are they complex/simple? Give 4 examples.
Inorganic compounds do not contain carbon and are structurally simple. Examples are acids, bases, salts, H2O.
Do organic compounds contain carbon? Are they complex/simple? Give 5 examples.
Organic compounds always contain carbon (called carbon skeleton) and are complex and always have covalent bonds. Examples are carbs, lipids, protein, nucleic acid and ATP.
What is water's most important property?
Its polarity, the uneven sharing of valence electrons.
What causes water to have a high heat capacity? How does thermoregulation affect the body?
The large amount of hydrogen bonds are hard to break. Water prevents the denaturization of proteins.
Give 5 reasons why water is important to the body.
1) Water is a good solvent. 2) It participates in hydrolysis/dehydration synthesis reactions. 3) Lubricant 4) High surface tension (lungs) 5) High heat capacity (thermoregulation)
Type of mixture where the solvent dissolves a solute and is transparent.
Solution
Type of mixture where particles are large enough to scatter light (opaque).
Colloid
Type of mixture where material may mix with liquid for some time but will eventually settle out (layers).
Suspension
Name 2 ways concentration can be measured.
1) Mass / volume % 2) Moles / liter
A ___ disassociates into hydrogen ions and anions. It is referred to as a proton ___.
Acid. Proton donor.
A ___ removes hydrogen ions from a solution and is referred to as a proton ___.
Base. Proton acceptor.
When dissolved in water, a ___ disassociates into cations and anions, neither of which is H+ or OH-. It is formed by acids and bases reacting.
Salt
The pH scale is based on the concentration of ___. A pH of 7 is considered ___. Blood has a pH of ___ and is slightly alkaline/acidic.
The pH scale is based on the concentration of H+ in moles per liter. A pH of 7 is considered alkaline. Blood has a pH of 7.4 and is slightly alkaline.
___ convert strong acids/bases into weak acids/bases.
Buffers (buffer systems)
An important buffer system in the body.
Carbonic acid-bicarbonate buffer system
Chain of carbon atoms in an organic molecule is called ___. Many carbons are bonded to hydrogen atoms, yielding a ___. Also attached are ___.
Carbon skeleton. Hydrocarbon. Functional groups.
___ have the same molecular formula but different structures.
Isomers
A ___ is a large molecule formed by the covalent bonds of smaller building block molecules called ___.
Polymer. Monomer.
Which macromolecule provides most of the energy needed for life? Name 3 groups and give 2-3 examples for each.
Carbohydrates. Monosaccharides (glucose, fructose, deoxyribose). Disaccharides (sucrose, lactose). Polysaccharides (glycogen, starch, cellulose).
A disaccharide consists of 2 monosaccharides that have been combined by what type of chemical reaction?
Dehydration synthesis
What is the principle polysaccharide in the human body and name 2 storage areas in the body.
Glycogen is stored in the liver and skeletal muscles.
Macromolecule represents 2-3% of your total body mass.
Carbohydrates
Macromolecule makes up 18-25% body mass in lean adults.
Lipids
What is the ratio of hydrogen to oxygen atoms in carbohydrates?
2:1
Lipids have few polar covalent bonds and are hydrophobic. How do they become soluble in blood plasma?
Lipids join with hydrophilic protein molecules called lipoproteins. These are soluble because the proteins are on the outside and lipids are on the inside.
Name the 5 types of lipids in the body.
Fatty acids, triglycerides, phospholipids, steroids, eicosanoids
Which lipid is used to synthesize triglycerides, phospholipids or is catabolized to generate ATP?
Fatty acids
What is the difference between a saturated fatty acid and an unsaturated fatty acid (can be mono or poly)?
A saturated fatty acid contains single covalent bonds between carbons and hydrocarbon chain. An unsaturated fatty acid contains one or more double covalent bonds between carbons and hydrocarbon chain.
Which lipid is the most plentiful in the body and provides protection, insulation and energy? What are the 4 building blocks of this lipid?
Triglycerides are built from one glycerol and 3 fatty acids.
Does the oxygen in the water molecule removed during hydration synthesis come from glycerol or from a fatty acid?
Fatty acid
A triglyceride that is solid at room temperature is a ___. If it is liquid it is a ___.
Fat. Oil.
Which lipid is said to be amphipathic and an important part of the cell membrane? Which portion is hydrophilic (polar) and hydrophobic (nonpolar)?
Phospholipids have a hydrophilic head and hydrophobic tail.
What is the chemical structure of a phospholipid?
Polar head contains glycerol and phosphate group. Nonpolar tail contains 2 fatty acids.
Which lipid has 4 rings of carbon atoms?
Steroids
What is synthesized in the liver and is the starting material for other steroids in the body?
Cholesterol
Which lipids are derived from arachidonic acid and modify hormone responses, contribute to inflammation, dilate airways and thermoregulation?
Eicosanoids
What are the monomers used to build proteins and how many types are there?
There are 20 different amino acids.
A ___ is formed by 2 amino acids joined by a covalent bond called a ___.
A dipeptide is formed by 2 amino acids joined by a covalent bond called a peptide bond.
A chain of 10-2000 amino acids is called a ___.
Polypeptide
What 4 parts make up a body protein?
H atom, amino group, carboxyl group, side chain
Name and describe the 4 levels of structural organization in a protein.
Primary - amino acid sequence. Secondary - twisting/folding of neighboring amino acids (alpha helix or beta pleated sheets). Tertiary - 3D shape. Quaternary - arrangement of 2 or more polypeptides in relation to eachother.
Do all proteins have a quaternary structure?
No, proteins with a single polypeptide chain do not.
___ of a protein by a hostile environment causes loss of its characteristic shape and function.
Denaturization
Which macromolecule gives body structure, regulate processes, provide protection, muscle contraction, transport substances, enzymes.
Protein
Catalysts in living cells are called ___.
Enzymes
What are 3 characteristics of enzymes?
1) Enzymes are highly specific (2) Efficient - speed up chemical reactions by lowering activation energy (3) Are subject to a variety of cellular controls (genes)
What are the 3 phases in the enzyme-substrate process?
1) Enzyme and substrate join at active site, forming enzyme-substrate complex (2) Enzyme catalyzes RXN and transforms products (3) When RXN complete, enzyme is unchanged and is free to catalyze RXN with new substrate
___ are huge organic molecules that contain carbon, hydrogen, oxygen, nitrogen and phosphorus (CHONP)
Nucleic acids
___ forms the genetic code in each cell and regulates most activities in cells.
Deoxyribonucleic acid (DNA)
___ relays instructions from cell's genes to guide each cell's assembly of amino acids into proteins by ribosomes.
Ribonucleic acids (RNA)
What are the 4 nitrogenous bases found in a DNA nucleotide? How do they pair? Which is purine/pyrimidines?
Adenine, Guanine (purine). Thymine, Cytosine (pyrimidine). Pairs: AT, GC
AGTC = All good things come, ATGC
Describe 3 differences between DNA and RNA.
RNA is single strand and DNA is double strand. RNA consists of ribose sugar and DNA consists of deoxyribose sugar. RNA's nitrogenous base is uracil and replaces DNA's thymine.
What are the 3 types of RNA?
Messenger RNA, ribosomal RNA, transfer RNA
Energy currency of living cells
Adenosine triphosphate (ATP)
What is the reaction catalyzed by ATPase? Is it exergonic/endergonic?
ATP + H2O --> ADP + Phosphate Group + Energy. Exergonic.
What is the reaction catalyzed by ATP synthase? Is it exergonic/endergonic?
ADP + Phosphate Group + Energy --> ATP + H2O. Endergonic.