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64 Cards in this Set

  • Front
  • Back
Anthropogenic Source
Pollution from human activity

Smoke stack emissions, tailpipe emissions, airplanes, etc.
Natural Source
Pollution from natural source

Methane from farms, dust from sand dunes, volcanoes, etc.
Smokestack Plume -- Stable Air
No vertical motion, stagnant or horizontal fanning
Smokestack Plume -- Low-alt unstable air
Spreads out below the inversion layer (fumigation)
Smokestack Plume -- Unstable Air
Pollution can go wherever, often looping due to waves in the air
Urban Heat Island
Urban area is warmer than surrounding country.

Rising air causes an inward breeze

Out of town factories pollute city

Pollution is trapped under inversion top
London Smog (sulferous)
SO2, Sooty Particles
Recognized Centuries Ago
Cool temperature
High humidity
Early morning is peak polltuion
Dark & Foggy
Radiation Inversion
LA Smog (photochemical)
Organic pollutants, NOx
Ozone
Warm temperature
Bright Sunlight
Afternoon is peak of pollution
subsidence inversion
Acid-Base Scale
0-14 pH scale
7 = Regular Water
< 7 -- Acidic (more protons)
> 7 -- Basic (fewer protons)
Acid Rain
pH of 4-5
Big contributors: sulfuric acid and nitric acid

Secondary pollutants from sulfur dioxide and nitrogen dioxide.
Net Effect of Acid Rain on Acidity
pH of rain is rising!!
So, the clean air act is working.

Acid Rain is strongest in Northeast (Ohio, Pennsylvania) Still below pH of 5 here
Yucky Effects of Acid Rain
Changes acidity of soil
Soil nutrients can be leached away
Fish eggs will not hatch
Biodiversity is reduced
Kills off some insect life
Soil microbes can die out
Increased oxidation of iron
Reacts with calcium in stone
Air Pollution Researchers (fun, exciting job)
Take measurements of air quality

Do a lot of meteorology
- Back trajectories tell pollutant source
- Forward trajectories tell pollutant destination

Do climate studies
- Longterm influences of air pollution and long term trends in pollution levels
What is Ozone?
three oxygen atoms bonded together

O3
Where is Ozone
Troposphere (BAD)
Stratsophere (GOOD)
What does Ozone do?
Absorbs harmful UV sunlight but is bad for our delicate lungs.
Ozone Loss vs. Latitude
Most of the downward trend in ozone content is occurring at high latitudes.
- 50% loss over Antarctica since 1970

Biggest loss in spring, then a recovery
Ozone Hole
Lasts for a few months each year in Polar Spring (sept. - nov.)

Overall downward trend of 2% a decade
Chemical Destroyer Mechanisms
Atoms/Molecules that react easily with ozone

Chlorine (biggest source is CFCs), Nitric Oxide, Hydroxyl
Catalytic Cycle
CDMs consume ozone but are not destroyed. One atom/molecule can destroy thousands of O3 molecules.
Why Springtime at the Poles?
Release of destroyer chemicals from stable forms need two things: UV sunlight and a sruface.

UV light is in the stratosphere

Surface = Polar Stratospheric Clouds (PSCs).
Polar Stratospheric Clouds (PSCs).
Requires very cold temperatures.

Only happen without sunlight in polar winter over Antarctica!
Koppen climate Classification system
Grouped the world into 5 major climate types
Koppen Group A
Tropical moist climates
Average temp. > 64F
Koppen Group B
Dry climates

Evaporation and transpiration exceed precipitation
Koppen Group C
Moist mid-latitude climates with mild winters

Average temp of coldest month between 27 and 64 F
Koppen Group D
Moist mid-latitude climates with severe winters.

Warmest month exceeds 50F and coldest month below 27F
Koppen Group E
Polar Climates

Warmest month has avg temperature below 50F
Global Temperatures
Largely controlled by latitude with slight modifications due to ocean currents and mountains
Global Precipitation
Global circulation patterm creates overall pattern with modifications from ocean currents and mountain ranges
Some evidence of climate change
Tree rings, glacial ice cores, ocean sediments, radiocarbon dates of organic material, pollen samples, sedimentary rock records, historical records of crops, droughts, and floods

big one: isotope ratios
The Faint Young Sun Paradox
Sun was not always as bright as it is now.
-- Maybe 70% of its value at formation

Earth's equilibrium temperature should be below freezing.

We avoided this "snowball earth" because of the Greenhouse effect and the presence of CO2 in the atmosphere.
History of the Atmosphere
Lots of CO2 in the air. How?

--Atmospheric Source: volcanism (release of CO2)

-Atmospheric sink: weathering (reabsorption into the rock)

Increased plant life then converted this to oxygen.
Plate Tectonics
CONTINENTS ON THE MOVE!

Evidence? Volcanism history, mountain range ages, subduction zones, magnetism of rocks
Dinosaur Extinction Theories
Asteriod hit Earth creating a haze layer causing intense but brief climate change.
Huge volcanic eruptions caused intense but brief climate change
Small mammals ate the dinosaur eggs
Earth's orbit changed, ice caps formed, ocean levels dropped
Methane release from deep sea algae deposits
Over-foraging led to mass starvation
Nearby supernova bathed earth in deadly radiation
Temperatures and CO2 Levels
Correlation is extremely high - every peak and valley matches up.
Milankovitch Theory
Climate varies because of orbital changes
- Amount of sunlight reaching earth is different
- Distribution and timing of sunlight is different
Eccentricity
Non-circular orbit varies in its non-circularity by a tiny a bit.
Axial Tilt
The present 23 degree tilt of Earth's rotation axis is not a constant
Cycles every 41,000 years or so from 21.5 to 24.5
Precession of Perihelion
Whole ellipse is wobbling like a hula hoop around sun.

Timing of seasons relative to eccentricity reverses every 23,000 yrs
Younger Dryas Period
Cold period of 1000 yrs as Earth was emerging from last ice age.

Caused by fresh water ice melt shutting off the North Atlantic current system.

Fast change

Named after arctic flower when it was found south of usual location.
27 day Solar Rotation Cycle
sun's rotation about its axis...sunspots coming in and out of view
154 Day Cycle
Seen in solar data but no obvious climate connection
10-11 Year Sunspot cycle
Small but definite climate signal - sometimes positive, sometimes negative
80-90 Year Cycle
Envelope of sunspot peak values - shows up a little bit in some climate data
Maunder Minimum
1650 - 1700

Very few sunspots

Slightly less sunlight

Slight dip in temperature
Features of the last 2000 yrs
Grand maximum around 1000 AD
Little Ice AGE around 1600 AD

Solar causes? Maybe. They correspond to carbon isotope solar proxies.
Temperature and Volcanoes
Massive, equatorial erupitons cause aerosol haze to form in the stratosphere (dust/ash sulfur dioxide haze). Reduced global temperatures for 1-2 years by 0.5-2 degrees C

Miniscule CO2 released by volcanoes but it adds up
Cloud Feedback
A warmer planet leads to more evaporation and a more active water cycle, hence more/thicker clouds!

Net cooling effect since shortwave radiation forcing (reflection) is larger than the longwave radiation forcing (trapping).
Air Pollution and its Effect on Climate
Air pollution is declining since the EPA creation in 1970

Aerosols play a significant role in counteracting GHG warming.
Positive Feedback Loop
Once perturbed, a system will continue to shift in that direction.

Counteracted by negative feedback loops.
CO2 in the Atmosphere
Annual variation and an overall upward trend.

Decay in plant life leads to an increase in C02 in the fall/winter while photosynthesis decreases it in spring/summer

Upward trend is due to man made emissions =(
Full Terrestrial Carbon Cycle
\\/// dont know \\\//
1000 Yrs of Carbon Dioxide
Flat for a looooong time and growing now due to human activity
Temperature Modeling: Natural forcing
Overpredicted an early 1900s rise and missed late 1900s rise
Temperature Modeling: Anthropogenic forcing
No rise at all until after 1950 then a lot
Temperature Modeling: Natural forcing and Anthropogenic forcing combined result
Matches the observations quite well, including the dip around 1950 and the recent fast rise.
Climate Predictions: 2100
Probable temperature increase of 3C - >5C if we do nothing!

Greater increase in the Northern hemisphere (4C) and North Polar Region about 6C

Sea Level: Probable increase of 80 cm....utoh. North Atlantic current decrease of 10-20%!
Sources of GHGs
Carbon dioxide and fossil fuel emissions --> 56.6%

Energy supply and transportation industries
CO2: USA vs. the WORLD!
US emissions per capita up 25% over 50 years

Global emissions per capital up 75% over 50 years

US is world leader in per capitaa emissions

China just passed USA in total output
Air Pollution
Airborne "bad thing" with adverse health effects to humans, plants, buildings, environment
Sunspots
Huge magnetic storms on the sun that show up as cooler (darker) regions on the Sun's surface. They occur in cycles, with the number and size reaching a maximum approximately every 11 years
Pleistocene epoch
Continental glaciers alternately advanced and retreated over large portions of North America and Europe.
CFCs
• They are chemically inert so they can survive their journey into the troposphere and make it to the stratosphere
• They then mix to all latitudes and sunlight and PSCs break them down and release CL!
Natural CL sources don’t survive tropospheric chemistry; the stratospheric CL is dominated by CFCs.