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63 Cards in this Set
- Front
- Back
What is an aldose |
Carbonyl at end of carbon chain In aldehyde group |
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What is a ketose |
Carbonyl not at the end of carbon chain In ketone group |
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What are isomers |
mirror images around chiral carbons |
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What is the most common isomer form in CHO's in living organisms |
D isomer |
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When does a CHO exist in a cyclical not straight chain structure |
more than 5 C |
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Alpha anomer |
-OH of anomeric (carbonyl) C is down |
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Beta anomer |
-OH of anomeric (carbonyl) C is up |
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What is a CHO derivative |
Hydroxyl group replaced with: another substituent carbon is oxidized hydroxyl is phosphorylated |
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What are the 4 main CHO derivatives |
1. Amino Sugars = -OH to -NH2
2. Deoxy Sugars = -OH to -H
3. Acidic sugars = -CH2OH to -COO-
4. Sugar phosphates = -OH to -OPO3-2- |
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4 main classifications of CHO's |
1. Monosaccharides = simple sugar
2. Disaccharides = 2 monosacchrides
3. Oligosaccharides = 3~9 monosaccharides
4. Polysaccharides = 10+ monosaccharides |
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What determines the name of the glycosidic bond between two monosaccharides |
1. Position of C involved
2. Anomeric configuration of those C's (alpha "u" shaped, beta "s" shaped) |
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3 important disaccharides and their linkage |
1. Maltose - glc(alpha1 to 4)glc
2. Lactose - gal(beta1 to 4)glc
3. Cellobiose - glc(beta1 to 4)glc |
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2 important starches and their likage |
1. Amylose - glc(alpha1 to 4)glc - linear
2. Amylopectin - glc(alpha1 to 6)glc - branches (24-30 residues) |
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How does glycogen structure differ from amylopectin |
Similar structure but more frequent branching (8-12 residues) |
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Structure of cellulose, hemicellulose and pectin |
Cellulose = glc(beta1 to 4)glc
Hemicellulose = heteropolysaccharide
Pectin = heteropolysaccharide |
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What is lignin |
NOT a CHO
part of cell wall
complex polymer of aromatic alcohols |
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2 main places CHO's found |
1. Endosperm
2. Plant cell wall |
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3 main components of cell wall and their function |
1. Cellulose = individual chains form microfibrils
2. Hemicellulose & Pectin = cross link cellulose microfibrils
3. Lignin = bonded to cellulose and hemicellulose, like concreted surrounding steel rods (cellulose) |
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4 main functions of CHO's |
1. Not essential
2. Provide source of energy
3. Starch and glycogen = energy storage
4. Plant cell wall |
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Where does most CHO digestion occur |
Small intestine |
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Origin, Substrate, Action, and End products of: Pancreatic amylase |
Origin = pancreas
Substrate = Starch
Action = dextrins
End Products = Maltose, isomaltose, glucose |
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Origin, Substrate, Action, and End products of: Maltase and Isomaltase |
Origin = Sm Intestine
Substrate = Maltose, isomaltose
End products = glucose |
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Origin, Substrate, Action, and End products of: Lactase |
Origin = Sm Intestine
Substrate = lactose
End products = glucose and galactose |
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Origin, Substrate, Action, and End products of: Sucrase |
Origin = Sm Intestine
Substrate = sucrose
End products = glucose and fructose |
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_______ breaks alpha(1-4) bonds in amylose and amylopectin and yields ___, ____, and _____ |
Alpha-amylase breaks alpha(1-4) bonds in amylose and amylopectin and yields maltose, maltotriose and limit dextrins |
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______ cleaves ______ bonds as well as alpha(1-4) bonds at non-reducing ends of amylose/amylopectin and yields ________ |
Amyloglucosidase cleaves alpha(1-6) bonds as well as alpha(1-4) bonds at non-reducing ends of amylose/amylopectin and yields glucose |
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_______ cleaves alpha(1-4) bonds of maltose and yields ______ |
Maltase cleaves alpha(1-4) bonds of maltose and yields glucose |
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Where is the most absorption of CHO's |
duodenum and ileum |
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What is the active transporter of Glucose |
Sodium-glucose linked transoprter |
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What is the passive transporter of Glucose |
Glucose transporter |
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What is the beginning and end products of Glycolysis and what is net products |
Glucose to Pyruvate
2 ATP, 2 Pyruvate, 2 NADH |
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The conversion of _________ to _________ is the intermediate step between glycolysis and citric acid cycle and it yields _________ |
pyruvate to acetyl-CoA
yields 2 NADH/glucose or 1 NADH/pyruvate |
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What is the beginning and end products of the Citric Acid Cycle and what is net products |
Acetyl-CoA to Co2
Yields: 4 CO2, 2 ATP, 6 NADH, 2 FADH2 |
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What is the beginning and end products of Oxidative Phosphorylation and what is net products |
NADH/FADH2 to ATP
Yields: 2.5 ATP/NADH or 1.5 ATP/FADH2 |
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Which is a higher energy carrier, NADH or FADH2 |
NADH |
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In __________ pyruvate is converted to glucose |
Gluconeogenesis |
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How does gluconeogenesis differ from glycolysis |
glycolysis in reverse
requires 6 ATP equivalents
Oxaloacetate is and intermediate
Other enzymes differ |
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Another word for glycogen degradation is |
glycogenolysis |
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What are the steps of glycogenolysis and what is yielded |
1. Glycogen phosphorylase breaks alpha(1-4) bonds 2. Debranching enzyme breaks alpha(1-6) bonds
Yield: 1 glucose-1-P and conserves 1 ATP |
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What is another word for glycogen synthesis |
Glycogenesis |
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What are the steps of glycogenesis |
1. Glycogen synthase elongates alpha(1-4) chains of UDP-glucose 2. Glycogen branching enzyme forms alpha(1-6) branches
requires 2 ATP equivalents |
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What is the main point of glycogenesis |
makes more non-reducing ends to increase sites for synthesis and degredation |
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What happens in the pentose phosphate pathway |
1. Pentoses converted to corresponding sugar phosphates
2. Sugar phosphates then fed into glycolysis (EMP) |
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What is the total ATP yield from 1 molecule of Glucose |
Total = 32 Glycolysis = 2 ATP, 2 NADH (5 ATP) = 7 ATP A. CoA = 0 ATP, 2 NADH (5 ATP) = 5 ATP C.A.C. = 2 ATP, 6 NADH (15 ATP), 2 FADH2 (3 ATP) = 20 ATP |
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______ secreted by ________ in response to high blood glucose |
Insulin is secreted by pancreas in response to high blood glucose |
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________ secreted by ________ in response to low blood glucose |
Glucagon is secreted by the pancreas in response to low blood gluose |
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5 effects of Insulin |
1. increase glucose uptake 2. increase glycogen synthesis 3. decrease glycogen degredation 4. increase lipogenesis 5. decrease lipolysis |
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4 effects of Glucagon |
1. decrease glucose uptake 2. increase glycogen degradation 3. increase glucoeogenesis 4. increase lipolysis |
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Approximately ______ percent of bacteria attached to feed particles |
70 % |
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Are protozoa associated or attached |
associated |
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What are the two steps to plant cell wall breakdown by gut microbes |
1. Cellulolytics break down cellulose and hemicellulose into solubilized oligo and polysaccharides
2. Other species ferment to acetate, butyrate, methane and propionate |
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What are the 2 limits to hydrolysis by gut microbes |
1. Rate - dependent upon surface area
2. Extent - dependent upon lignin |
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What are the steps to fermentation of CHO's by gut microbes and what is the ATP yield |
1. Glucose to pyruvate
2. Pyruvate to SCFA, CO2, H2, and Methane
Yields 2-4 mol ATP per mol of glucose, plus extra for methane |
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What are the 4 most common abnormalities of CHO digestion |
1. Malabsorption of of sucrose and lactose
2. Diabetes mellitus
3. Acute Acidosis
4. Chronic Acidosis or SARA (sub acute rumen acidosis) |
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What are the 3 types of diabetes |
Type 1 = don't produce insulin, childhood diabetes
Type 2 = don't sense insulin
Gestational = don't sense insulin during pregnancy, most common in animals |
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What causes acute acidosis |
abrupt transition from forage to grain, lactate accumulates and pH drops below 5.2
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What microbes cause acute acidosis
What microbes alleviate it |
Cause = streptococcus bovis
Alleviate = Megasphaera elsdenii |
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What causes chronic acidosis |
After adaptation to high grain, chronic episodes of low pH b/w 5.2 and 5.6
no accumulation of lactate
poor rumination = poor salivation = poor liquid dilution rate = less VFA washed out = low pH |
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What is the way to tell if a cow has chronic acidosis |
milk fat depression |
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What are the main 4 effects of chronic acidosis |
1. Milk fat depression
2. Ulceration and scarring ofrumen wall
3. Migration of fusobacterium necrophorum from ruminal ulcers to liver
4. formation of liver abscesses |
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How can you treat chronic acidosis |
increase fiber to stimulate rumination and increase pH |
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Most concentrates are high in _________ |
starch |
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Most forages are high in ________, ________ and ___________ |
cellulose, lignin and other cell wall components |