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15 Cards in this Set

  • Front
  • Back

the formation of ammonia from nitrogen and hydrogen gas is a reversible reaction



( reaction can go backward and forward at the same time )

-

ammonia is made up if nitrogen and hydrogen gas

f

H : N is 3:1 by volume

s

nitrogen is obtained from fractional distillation if liquid air

hydrogen is obtain from cracking of petroleum

a

for nitrogen and hydrogen to form ammonia , a high pressure and a relatively high temperature is needed

plus , iron has to be present as catalyst to speed up the reaction

c

some ammonia formed may decompose and convert back to nitrogen and hydrogen

f

to achieve maximum yield of ammonia at min cost , the pressure a and temperature has to be carefully controlled

s

high pressure increases yield of ammonia and speed if reaction

however maintaining high pressure is expensive

hence there us a limited amount of pressure that should be applied

f

the lower the temperature the higher the yield of ammonia

this is because the decomposition of ammonia is reduced

however reaction is slower

s

despite pressure and temperature , haber process reaction is still slow hence a catalyst is used

s

what are the optimal conditions in the haber process

pressure : 250 atm
temperature : 450 degrees
presence of iron catalyst

v

reaction is exothermic

x

only about 10 to 15 percent of nitrogen and hydrogen Is converted to ammonia , the rest are recycled and pumped back to converter

x

ammonia can also be obtained by displacement of ammonia from its salt

react it with alkaline or bases

s

calcium hydroxide should not be added to soil at the same time as nitrogenous fertiliser as ammonia gas will form and nitrogen will evaporate with it

w