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12 Cards in this Set
- Front
- Back
london-type smog
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pollution from coal and smoke in foggy places or temperature inversions. Invention is steam engine.
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photochemical
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secondary pollutants forming in sunlight, strong temperature inversion, more automobiles=invention
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photostationary state reactions for ozone
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NO + O3 --> NO2 + O2
NO2 + LIGHT --> NO + O O+ O2 --> O3 |
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importance of OH
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breaks down all organics and most inorganics in the air
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CO reactions
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doesn't make much because it breaks down slowly
CO + OH --> CO2 + H H + O2 --> HO2 NO + HO2 --> NO2 + OH NO2 + LIGHT --> NO + O O + O2 --> O3 |
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methane reactions
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CH4 + OH --> CH3 + H2O
CH3 + O2 --> CH3O2 NO + CH3O2 --> NO2 + CH3O NO2 + LIGHT --> NO + O O + O2 --> O3 |
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ethane reactions
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C2H6 + OH --> C2H5 + H2O
C2H5 + O2 --> C2H5O2 NO + C2H5O2 ---> NO2 + C2H5O NO2 + LIGHT --> NO + O O + O2 --> O3 |
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formaldehyde reactions
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HCHO + LIGHT --> HCO + H
HCHO + LIGHT --> CO + H2 HCHO + OH --> HCO + H2O HCO + O2 --> CO + HO2 H + O2 --> HO2 (then back to CO equations) |
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most important organics for pollution
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most important: aromatics, alkenes, aldehydes
Alkanes and CO react slowly but are emitted in greater abundance fastest to slowest: alkene > aldehyde > aromatic > alcohol > alkane |
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what breaks down ROG's
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OH, HO2, O, O3, NO3
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ozone isoplethe chart (ROG limited, NOx limited)
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when ROG's are high and NOx is low, reduce NOx. When NOx is high and ROG's are low, reduce ROG's. If they're both super high, reduce either.
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RO: NOx ratios in LA and Atlanta
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LA: ROG limited (cars produce NOx)
Atlanta: NOx limited |