Supramolecular chemistry

CORROSION STUDIES WITH ANTIGONON LEPTOPUS IN 1M HCl S.Aejitha 1, P P.K.Kasthuri 2andGeethamani 3 1 Department of Chemistry, Asian College of Engineering & Technology, Coimbatore- 641110, India 2 Department of Chemistry, L.R.G.Government Arts College for Women, Tirupur- 638604, India 3 Department of Chemistry, Sriguru Engineering College of Technology, Tamil Nadu, Coimbatore -641110, India Correspondence should be addressed to S.Aejitha ,aejitha_subbaian@yahoo.co.in ABSTRACT The inhibition…

Kwong equations are mainly used as they are simple and a temperature-dependent correction is used for EOS constant A. van der Waals Equation van der Waals proposed the first cubic EOS in 1873. The van der Waals EOS gives a simple, qualitatively accurate relation between pressure, temperature, and molar volume. P=RT/(V-b)-a/V^2 where a is “attraction” parameter, b is “repulsion” parameter, and R is universal gas constant. Comparing this equation with the ideal gas law,P= zRT/v, we see that the…

4. Why PdO/TiON NP powders are chosen as photocatalyst? There are many reasons why PdO/TiON NP powders are chosen as a photocatalyst for MTBE mineralization under visible light. These reasons are listed and discussed as follows: 1- The synergistic effect. 2- The ease of synthesis. 3- The memory effect. 4.1 The synergistic effect Nowadays, modified TiO2 by metal and nitrogen is considered as one of the most promising TiO2 based materials for photocatalytic applications, which is able to…

So as to guarantee conscious and safe transportation of HUM, Etihad Cargo asks for that all HUM are hermetically fixed in an internal lead or zinc box, set in a wooden coffin, to keep any harm. The coffin must be secured by a proper canvas, not to make the substance promptly obvious. Urns must be secured by padded external pack and joined by a testament from the crematorium. • Marks and marks utilized on bundles containing pine boxes must be the same as those utilized for general cargo •…

Diels-Alder Reaction Objective: The objective of this lab was to do a diels-alder reaction using anthracene, maleic anhydride, and xylene to create 9,10-dihydroanthracene, 10-, -succinic acid anhydride. Experimental: Anthracene (1.00g, 5.61x 10-3 mol), maleic anhydride (0.75g, 7.61x 10-3 mol), xylene (5mL, 4.71x 10-2 mol), and a stir rod were added into a round-bottomed flask. The round-bottom flask was then moved to the hood where the it was attached to a distillation column, placed on…

INTRODUCTION Conformational isomerism is a type of stereoisomerism whereby the isomers are interconverted by rotations about the single bonds. There be terms used below such as eclipsed conformation, staggered conformation,dihedral angle and a few more. Eclipsed conformation is the conformation whereby the C-H bonds on one carbon is directly aligned with the C-H bonds of the adjacent carbon. When the C-H bond of one carbon bisects the H-C-H bond on the adjacent carbon, it is known as staggered…

Since suitable crystals for X-ray single crystal analysis was not obtained, to have reliable structural information, HR-TEM analysis of the product was carried out. The average size of the assembly calculated from HR-TEM measurement is found to be 2.8 nm which is in good agreement with the size of the previously reported Pd6L8 assembly where L is the non N-methylated (2.5nm, Fig. 2).9 As first step, to explore the catalytic activity of 1 in copper and phosphine free Sonogashira coupling reaction…

6.3. A. Microemulsions (135-143) Microemulsions are clear, stable, isotropic mixtures of oil, water, and surfactant, frequently in combination with a cosurfactant 135-137. Microemulsions have several advantages such as enhanced drug solubility, good thermodynamic stability, and higher transdermal permeability over conventional formulations 138,139. Many studies reported the use of microemulsions as topical drug delivery vehicles showed their ability to improve transdermal and dermal delivery…

Discussion: Based off the results from this lab the student was able to determine whether the model cell and cell environment each represent a hypertonic, hypotonic or isotonic solution. The first solution cell and environment the student had, was water and sodium chloride. In this instance water was the model cell (what was in the dialysis tubing) and Sodium chloride was the surround environment (plastic cup). The initial weight of the model cell was 13.2g, but after sitting in the sodium…

New method of synthesis of oligoetherols with carbazole ring Renata Lubczak Abstract: The new method of synthesis of multifuntional oligoetherols with carbazole ring suitable for obtaining the polyurethane foams of enhanced thermal resistance was presented. At the first step of the synthesis the carbazole was reacted with excess glycidol to obtain the product of (n +1) functionality, where n is number of equivalents of glycidol reacted with carbazole. Carbazole reacts with glycidol without…