Hydrogen storage

Paragraph 1 This report aims to study the symmetrical distinctions, crystal structures and chemistry of α‐FePO4 and β‐FePO4 as well as any alteration to FeO4 and PO4 when there are modifications to temperature. It also seeks to justify the tilting of the tetrahedral. The article by Haines shows that he had studied the iron phosphate, FePO4, at temperatures from 294 K to 1073 K and had found that the turning point between the 2 phases is at 980 K, where FePO4 takes on the alpha phase at…

Chitin is the second most abundant natural polysaccharide consisting of β(1→ 4)-linked N-acetyl-D-glucosamine (GlcNAc) units in a linear form. Chitin is insoluble in water and mainly exists in two crystalline (α- and β-) forms. The α-chitin consists of sheets of tightly packed alternating parallel and antiparallel chains (1) and is abundant in the exoskeleton of arthropods, insects, fungi, and yeast cell walls. The chains are arranged in parallel orientation in β-chitin (2), which occurs less…

Abstract: A one dimensional variable range hopping type conduction is observed in Poly (3,4-ethylenedioxythiophene): polystyrenesulfonate (PEDOT : PSS) films and the mechanism behind enhancement in conductivity in 3% dimethyle sulfoxide (DMSO) doped PEDOT:PSS film is due to the phase segregation of PSS on the surface and reduction of energy barrier between the conducting grains. Enhanced conductivity of PEDOT:PSS films and transparency more than 80% in the visible region makes PEDOT:PSS films…

hChemical kinetics deals with the rates of chemical processes. Any chemical process is considered to consist of number of one or more single-step step which are known as elementary reactions elementary processes or elementary steps. Elementary reactions may involve dissociation or isomerisation of a single reactant molecule, which is referred as unimolecular step. Also there may be a single collision between two molecules, which is referred as a bimolecular step. It should be noted that…

The kinetics of the reaction between peroxomonosulphate with Lactic acid was studied in the presence of Mn(II) at alkaline pH. The reaction followed first order with respect to peroxomonosulphate. The rate of the reaction was studied under pseudo first order condition and found to increases with the [Mn(II)] and lactic acid. Thermodynamic parameters were calculated and reported. Based on the results a rate equation, kinetic scheme and a most probable mechanism has been predicted. Keywords: Alpha…

2.7 Styrene Butadiene Rubber Styrene Butadiene Rubber (SBR) belongs to the synthetic rubbers families that are derived from Styrene and Butadiene.[53] SBR is an aqueous dispersion of (25%) Styrene (CH2=CHC6H5) and (75%) Butadiene (CH2=CH-CH=CH2) copolymer as shown in Figure (2-1). The copolymerization of these two polymers may done by different ways. Mostly they copolymerized in an emulsion process, by dispersing a soap like surface acting agent where the materials are in water solution.[54]…

Bismuth is the 83rd chemical in the periodic table. It is found as a natural metal on the surface of the earth. Bi has a ground state electronic configuration of [Xe]4f145d106s26p3 and trivalent and pentavalent Bi, Bi(III) and Bi(V), respectively, are the two predominant oxidation states. [27] It was discovered over a thousand years ago but was often confused with tin and lead. It is a prevalent post transition metal, which chemically resembles arsenic or antimony. Bismuth is the most naturally…

1. INTRODUCTION Thiosemicarbazone is a derivative of imine which is formed when an aldehyde/ketone reacts with a thiosemicarbzide through a condensation reaction. The presence of the hetero atoms like Sulphur and Nitrogen makes these derivatives biologically active. Lately, great emphasis is laid on the synthesis and development of these derivatives reason being the wide variety of pharmacological activities exhibited by them. So far, thiosemicarbazones have been shown to exhibit analgesic and…

Research Question How does the change in hydrochloric acid concentration affect the rate of reaction between sodium thiosulfate (Na2S2O3(aq)) and hydrochloric acid (HCL(aq))? Background to the Research question Collision Theory Back in 1916, scientists William Lewis and Max Trautz proposed the collision theory, which qualitatively explains how chemical reactions take place and why reaction rates change for various reactions. Chemical reactions involve collisions amongst reactant particles or…

Figure 1 shows the relation between density ρ and molar volume Mv as a function of copper oxide. From this figure, can be observed that the ρ and Mv decreased with the increased of copper oxide content replacement the lead oxide. The decrease of density due to the molecular weight of CuO is lower than the molecular weight of Pb3O4. The decrease of the molar volume due to the decrease the number of oxygen and may be the ionic radius of copper ions less than the ionic radius of lead ions. The…