Equilibrium constant

Experiment 4: Kinetics of Nucleophilic Substitutions 1. Determine the effect of varying [OH-] on the rate of the reaction. To do this, you should complete the following table: Experiment [tBuCl]0 (M) [OH-]0 (M) Time (s) Reaction rate (M/s) Rate constant (s-1) 1 0.03 0.003 65 4.89 · 10-5 1.62 · 10-3 2 0.03 0.006 213 3.15 · 10-5 1.05 · 10-3 3 0.03 0.009 362 2.96 · 10-5 9.85 · 10-4 What is the dependence of [OH-] on the rate law? The effect of the increased or…

3.11.2. Effects of pH The pH is a very important parameter which controls the extent of photoassisted degradation. The effects of pH on degradation of CR were investigated using 15.0 mg of LDH; 1x10-5 M CR solution in the pH range of 4.0 to 11.0, adjusted by addition of either 0.1 M HCl or NaOH. The plot of C/C0 vs. irradiation time of aqueous CR is presented in Fig.12(B). The efficiency of photodegradation of aqueous CR was found to be higher in the acidic medium particularly at pH 4 (~99.7%)…

Research Question How does the change in hydrochloric acid concentration affect the rate of reaction between sodium thiosulfate (Na2S2O3(aq)) and hydrochloric acid (HCL(aq))? Background to the Research question Collision Theory Back in 1916, scientists William Lewis and Max Trautz proposed the collision theory, which qualitatively explains how chemical reactions take place and why reaction rates change for various reactions. Chemical reactions involve collisions amongst reactant particles or…

Electrostatic Potential allows for scientists and chemists to calculate the atomic charges of large molecules. LogP is also known as the partition coefficient which is the ratio of concentrations of a compound in a mixture during two phases at equilibrium. LogP can be used to find distributions of chemical compounds in drugs, and how well those drugs can reach and affect their intended targets. Lastly,…

Graph 4 demonstrates the correlation between the transmittance and concentration levels of KMnO4, in how as the levels of concentration increase, the transmittance decreases. The experiment during week 2 was very similar to week 1 except we used potassium phosphate instead of potassium permanganate. Table 3 demonstrates the effect of wavelength on T% and absorbance. The same equation used for Table 2 was used in Table 3 in order, to calculate the absorbance. The highest absorbance level was…

It is essential for pharmacists to be able to predict the theoretical rate kinetics of pharmaceutical products in order to determine its shelf life. As the shelf life is defined by (t90), which is the availability of greater or equal to 90% of the drug, it is important to discover the rate of degradation of a drug to ensure that the patients receive an adequate dose of the drug. In this experiment, the stability of the active ingredient of Aspro Clear is investigated to identify the rate of…

Fizzy drinks can cause some significant damage to your teeth and general heath. There are three main damaging factors: the sugar content, the acidic properties and the staining effect. The ph of a solution is defined as the hydrogen ion, H+, concentration of said solution (ThoughtCo, 2017). The ph scale ranges from 0-14. Ph 7 being a neutral ph, every ph above being classed as alkali and every ph before being classed as acidic. The mouth has a neutral ph that varies slightly from 6.5-7.5. This…

Questions 1. Why are three replicate titrations done for each sample? Three titrations are performed because an error may occur in one of the titrations and getting two extra titrations can help eliminate the wrong answer. It is also a great way to practice accuracy and precision. 2. What other household products could be analyzed by titrations (suggest three)? Some other household items that could be analyzed by titrations are fruit juice, Cola beverages and household ammonia. 3. Why is it…

Bisoprolol fumarate. These may indicate moderate kinetics of complexation between Vildagliptin with Bisoprolol fumarate. The value of stability constant for the drug-drug system at pH 1.0, 3.0 and 6.8 are 1.875 0.7778 and 1.2000 respectively. At pH 1.0 it is found that Vildagliptin form relatively stable complex with Bisoprolol fumarate (stability constant 1.875) is high in comparison to pH 3. From the IR report it…

Marwah Alabbad Qualitative aspects of Equilibrium Post lab 10/7/15 1. Tables in experience 1: A. Test tube 0.5M HNO3 (mL) Drops of Potassium thiocyanate Drops of Ferric nitrate Observation (color) A 0.5 mL 1 1 Light orange B 0.5 mL 1 9 Vibrant orange( medium) C 0.5 mL 5 5 Vibrant red D 0.5 mL 9 1 Dark shade of orange E 0.5 mL 9 9 Dark red B. Removing Fe3+ Test tube 0.5M HNO3 (mL) Drops of Potassium thiocyanate Drops of Ferric nitrate 1% NaOH (mL) Observation F 0.5 mL 5 5 - The color has…